Printable Electronics Adhesive Layer for Low-Temperature Circuit Fusing

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Solution Overview

Problem

Current printed electronics face challenges in creating low-cost, highly conductive circuits and ensuring strong adhesion to various substrates without compromising electrical and thermal performance, particularly due to limitations in temperature and adhesion issues with flexible materials.

Innovation Solution

A method involving the application of an adhesive layer followed by a conductive metal layer, where the conductive metal particles fuse and the adhesive cures at temperatures below 200°C, allowing for strong adhesion and high conductivity without incorporating adhesives into the bulk structure, using a circuit-printing device with separate heads for each layer and optional curing agents.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If metal inks are used to create conductive circuits, then electrical conductivity is improved, but processing temperature must be increased to 300°C for 30-60 min to fuse metal particles

Engineering Contradiction:
Improveelectrical conductivityVSAvoidprocessing temperature
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent changes the processing temperature parameter from 300°C to below 200°C by using a two-layer system where an adhesive layer is applied first, then a conductive metal layer is applied over it. The adhesive layer acts as a flux that enables metal particle fusion at lower temperatures, thus improving electrical conductivity while reducing processing temperature requirements.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The adhesive layer serves as an intermediary substance between the substrate and the conductive metal layer. This intermediary enables the metal particles to fuse at lower temperatures by providing a chemical environment that facilitates bonding, thereby resolving the contradiction between achieving high conductivity and maintaining low processing temperature.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Strength

If adhesive layers are incorporated into the bulk structure to improve adhesion, then adhesion strength is improved, but electrical and thermal performance deteriorates

Engineering Contradiction:
Improveadhesion strengthVSAvoidelectrical and thermal performance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent segments the adhesive function from the bulk conductive structure by creating a thin adhesive layer at the interface between the substrate and the conductive metal layer. This segmentation allows the adhesive to provide strong bonding while the bulk metal layer maintains its electrical and thermal performance, as the adhesive is confined to a thin interfacial region rather than being distributed throughout the conductive path.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The adhesive is placed locally at the interface region where adhesion is needed, rather than being incorporated into the bulk conductive structure. This local placement ensures that the adhesive's bonding function is fulfilled while minimizing its impact on the electrical and thermal properties of the conductive circuit.

Inventive Principle:
Principle #3Local quality

3Reliability

If high-temperature processing is used to fuse metal particles, then electrical conductivity is improved, but substrate deformation increases

Engineering Contradiction:
Improveelectrical conductivityVSAvoidsubstrate deformation
Core Design Contradiction:
ReliabilityVSShape

Solution Approach 1:

The patent changes the processing temperature parameter from high temperature (300°C) to low temperature (below 200°C) by using the adhesive layer as a flux. This temperature reduction enables metal particle fusion and circuit formation while preventing substrate deformation, thus resolving the contradiction between achieving good electrical conductivity and maintaining substrate shape integrity.

Inventive Principle:
Principle #35Parameter changes

4Ease of manufacture

If conventional printing processes are used to create circuits, then manufacturing cost is reduced, but resolution and throughput are limited

Engineering Contradiction:
Improvemanufacturing costVSAvoidresolution
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent uses a composite material system consisting of an adhesive layer and a conductive metal layer. This composite approach enables the use of conventional printing processes at low cost while achieving high resolution, because the adhesive layer provides a forgiving matrix that allows for precise metal particle placement and fusion even with standard printing techniques.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the creation of highly conductive circuits with strong adhesion to a wide range of substrates, maintaining near-bulk material performance and flexibility, while avoiding the need for high-temperature processing and reducing substrate deformation.

Implementation Method 1

exposing the first layer and the second layer to a temperature for a duration of time to (1) fuse the particles of the conductive metal together

Methodology Applied
Scientific EffectSintering: Sintering

Implementation Method 2

cure the adhesive of the second layer

Methodology Applied
Scientific EffectCuring: Photopolymerisation

Data Source

PatentUS10919281B2Nanoparticle application with adhesives for printable electronics
Publication Date: 2021.02.16 LOCKHEED MARTIN CORP
  • US10919281B2 patent drawing
  • US10919281B2 patent drawing
  • US10919281B2 patent drawing

AI summary

A circuit assembly can be made by adhering a conductive element to a substrate with an adhesive. A first layer including an adhesive can be applied over at least a portion of a surface of the substrate. A second layer including a conductive metal can be applied over at least a portion of the first layer. The first layer and the second layer can be exposed to a temperature for a duration of time to (1) fuse the conductive metal together in at least a portion of the first layer and (2) cure the adhesive of the second layer. The fusing can be substantially complete before the curing is substantially complete to enhance bonding of the adhesive to the fused conductive metal.