QLED Electron Transport Layer Cleaning for Impurity Removal

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Solution Overview

Problem

Current QLED manufacturing methods introduce impurities into the electron transport layer, affecting the luminous efficiency and service life of QLED devices.

Innovation Solution

A QLED manufacturing method involving a solution with a main solvent and a solute of higher polarity, which does not dissolve the electron transport material, is used to infiltrate and dry the electron transport layer, adsorbing and removing impurities through a heating operation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional QLED manufacturing methods are used to form the electron transport layer, then the layer can be successfully formed, but impurities are introduced into the layer which affect luminous efficiency and service life

Engineering Contradiction:
Improveservice lifeVSAvoidimpurities in electron transport layer
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent applies preliminary action by performing a pre-treatment step on the substrate before depositing the electron transport layer. The substrate undergoes cleaning and activation treatments to remove contaminants and create a clean surface, preventing impurity introduction at the source rather than attempting to remove them afterward. This preliminary preparation ensures the electron transport layer is formed on a contaminant-free surface, thereby improving service life without compromising layer formation.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent converts the potentially harmful effect of common manufacturing impurities into a benefit by using a selective cleaning approach. The cleaning process is designed to remove specific organic contaminants and moisture that cause degradation, while preserving the functional morphology of the electron transport layer. By selectively eliminating harmful impurities through controlled thermal treatment and solvent vapor exposure, the method transforms the manufacturing challenge into an opportunity to enhance both luminous efficiency and device reliability.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Object-affected harmful factors

If a solution with high polarity solute is used to infiltrate the electron transport layer for impurity removal, then impurities can be effectively removed, but the electron transport material must not be dissolved

Engineering Contradiction:
Improveimpurities in electron transport layerVSAvoidintegrity of electron transport material
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent applies local quality by using a solution with specific local chemical properties - high polarity solutes that selectively interact with impurity molecules rather than the electron transport material. The solution's polarity is locally optimized to match the impurity characteristics while being incompatible with the electron transport material's solubility requirements. This selective local interaction allows impurity removal through differential solubility, where the high polarity solute binds to and extracts polar impurities while leaving the non-polar or less polar electron transport material intact and undissolved.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent applies parameter changes by carefully controlling the polarity parameter of the cleaning solution. The solution uses solutes with polarity values specifically selected to be higher than the electron transport material's polarity threshold, creating a polarity gradient that favors impurity extraction. By adjusting the solution's polarity parameters (through solvent selection and concentration control), the method achieves optimal impurity removal while maintaining the structural integrity of the electron transport layer, as the material's solubility is not reached at the controlled solution parameters.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method improves the luminous efficiency and service life of QLED devices by effectively removing impurities from the electron transport layer without dissolving the electron transport material.

Implementation Method 1

depositing a solution on a surface of the electron transport layer, standing until the electron transport layer is infiltrated by the solution

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 2

the solution comprises a main solvent and a solute dissolved in the main solvent, a polarity of the solute is greater than a polarity of the main solvent

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 3

performing a drying operation

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS11889745B2QLED manufacturing method
Publication Date: 2024.01.30 TCL TECHNOLOGY GROUP CORPORATION
  • US11889745B2 patent drawing

AI summary

The present application discloses a QLED manufacturing method including: providing a substrate provided with an electron transport layer; depositing a solution on a surface of the electron transport layer, standing until the electron transport layer is infiltrated, and then performing a drying operation, wherein the solution includes a main solvent and a solute dissolved in the main solvent, a polarity of the solute is greater than a polarity of the main solvent, and the solution is not able to dissolve the electron transport material in the electron transport layer; preparing other film layers on the electron transport layer processed by the mixed solvent to prepare the QLED, such that the QLED at least includes: an anode and a cathode arranged oppositely, a quantum dot light emitting layer arranged between the anode and the cathode, and the electron transport layer between the quantum dot light emitting layer and the cathode.