Quantum Dot Lighting Sealed Chamber Humidity Control

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Solution Overview

Problem

Silica-coated quantum dots in lighting devices experience instability and degradation due to the absence of water in hermetically sealed environments, leading to reduced quantum efficiency and color point stability over time.

Innovation Solution

Incorporating a controlled amount of water with a relative humidity of at least 1% but less than 100% in the filling gas, such as helium, hydrogen, or nitrogen, within the sealed chamber of the lighting device to maintain optimal performance and stability of quantum dots.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If quantum dots are hermetically sealed in a dry environment, then protection from chemical interactions is improved, but quantum efficiency stability and color point stability deteriorate

Engineering Contradiction:
Improveprotection from chemical interactionsVSAvoidquantum efficiency stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The invention changes the environmental parameter from completely dry (0% humidity) to controlled humidity (1-50% relative humidity). This parameter modification resolves the contradiction by providing the necessary water molecules for maintaining quantum efficiency stability while still protecting from harmful chemical interactions through the hermetic seal.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses an inert or controlled atmosphere inside the hermetic seal, specifically introducing water vapor at controlled humidity levels. This creates an optimized environment that protects quantum dots from degradation while maintaining their optical properties, resolving the contradiction between protection and stability.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

2Reliability

If quantum dots are hermetically sealed in a dry environment, then protection from chemical interactions is improved, but color point stability deteriorates

Engineering Contradiction:
Improveprotection from chemical interactionsVSAvoidcolor point stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The invention modifies the humidity parameter from 0% to 1-50% relative humidity within the hermetic seal. This change ensures color point stability by preventing the degradation mechanisms that occur in completely dry environments, while the hermetic seal continues to provide protection from external chemical interactions.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If silica coating is applied to quantum dots, then stability against photo-oxidation is improved, but quantum efficiency stability in sealed environments deteriorates

Engineering Contradiction:
Improvestability against photo-oxidationVSAvoidquantum efficiency stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The invention changes the environmental parameters inside the hermetic seal (humidity and oxygen levels) to be compatible with silica-coated quantum dots. By controlling the atmosphere to 1-50% relative humidity and potentially reducing oxygen content, the invention maintains both the photo-oxidation protection from silica coating and the quantum efficiency stability required in sealed environments.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite protective system combining silica coating on quantum dots with a controlled humidity atmosphere inside the hermetic seal. This composite approach leverages both the photo-oxidation resistance of silica and the stability provided by controlled environmental parameters, resolving the contradiction between these two protective mechanisms.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly reduces initial quenching and photo brightening effects, ensuring more stable color points and prolonged quantum efficiency in quantum dot-based lighting devices.

Implementation Method 1

the chamber comprises a filling gas, especially comprising one or more of helium gas, hydrogen gas (H2), nitrogen gas (N2) and oxygen gas (O2), and having a relative humidity (RH) at 19° C. of at least 1%

Methodology Applied
Scientific EffectHumidity control:

Implementation Method 2

the chamber further encloses a wavelength converter configured to convert at least part of the light source radiation into wavelength converter light, wherein the wavelength converter comprises luminescent quantum dots which upon excitation with at least part of the light source radiation generate at least part of said wavelength converter light

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Data Source

PatentUS10156325B2Quantum dots in enclosed environment
Publication Date: 2018.12.18 LUMILEDS SINGAPORE PTE LTD
  • US10156325B2 patent drawing
  • US10156325B2 patent drawing
  • US10156325B2 patent drawing

AI summary

The invention provides a lighting device for providing light, the lighting device comprising a closed chamber with a light transmissive window and a light source configured to provide light source radiation into the chamber, wherein the chamber further encloses a wavelength converter configured to convert at least part of the light source radiation into wavelength converter light, wherein the light transmissive window is transmissive for the wavelength converter light, wherein the wavelength converter comprises luminescent quantum dots which upon excitation with at least part of the light source radiation generate at least part of the wavelength converter light, and wherein the closed chamber comprises a filling gas comprising one or more of helium gas, hydrogen gas, nitrogen gas or oxygen gas, the filling gas having a relative humidity at 19° C. of at least 5%.