Quantum Dot Microcavity Light Extraction

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Solution Overview

Problem

The luminous efficiency of quantum dot emission layers in electronic devices is limited by low light extraction efficiency, making it difficult to achieve advanced electronic devices with improved performance.

Innovation Solution

The electronic device includes a configuration with specific layers such as a reflective layer, a charge auxiliary layer, an emission layer with quantum dots, and an optical functional layer, where the distance between the reflective layer and the emission layer is optimized, and the refractive indices of the layers are carefully managed to enhance light extraction efficiency and color purity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If quantum dots are used in the emission layer, then color purity and wavelength control are improved, but light extraction efficiency remains low

Engineering Contradiction:
Improvecolor purityVSAvoidlight extraction efficiency
Core Design Contradiction:
Illumination intensityVSLoss of energy

Solution Approach 1:

The device is segmented into multiple functional layers including charge auxiliary layers (with hole transport and hole injection sub-layers), emission layer with quantum dots, and optical functional layers. This segmentation allows optimization of charge carrier balance in specific layers while managing light extraction in others, resolving the contradiction between color purity and light extraction efficiency.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent introduces a microcavity structure by controlling the distance between the reflective layer and emission layer (100-160 nm for blue quantum dots), adding an optical dimension to enhance light extraction. This dimensional control creates constructive interference for extracted light while maintaining quantum dot color purity.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Loss of energy

If the distance between reflective layer and emission layer is optimized for blue quantum dots, then light extraction efficiency is improved, but the same distance may not be optimal for red quantum dots

Engineering Contradiction:
Improvelight extraction efficiencyVSAvoidwavelength region adaptability
Core Design Contradiction:
Loss of energyVSAdaptability or versatility

Solution Approach 1:

The patent makes the device adaptable to different wavelength regions by dynamically adjusting the distance between the reflective layer and emission layer based on quantum dot emission wavelength. For blue quantum dots (450-480 nm), the distance is 100-160 nm, while for red quantum dots (600-680 nm), the distance is adjusted to 230-280 nm, optimizing light extraction for each wavelength region.

Inventive Principle:
Principle #15Dynamics

3Productivity

If charge auxiliary layers are added to improve charge carrier balance, then luminous efficiency is improved, but device complexity increases

Engineering Contradiction:
Improveluminous efficiencyVSAvoidlayer structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The charge auxiliary layers serve multiple functions: they balance charge carriers (improving luminous efficiency), provide hole injection, and contribute to the overall optical cavity structure. This multi-functionality reduces the need for separate dedicated layers, managing device complexity while improving luminous efficiency.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration significantly improves the luminous efficiency and color reproducibility of the electronic device, achieving higher external quantum efficiency and light extraction efficiency, resulting in better performance and image quality in display devices.

Implementation Method 1

a first electrode including a reflective layer

Methodology Applied
Scientific EffectReflection: Reflection

Implementation Method 2

Quantum dots emit light while the excited electrons are transited from a conduction band to a valence band

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 3

an optical functional layer on the second electrode

Methodology Applied
Scientific EffectRefraction: Refraction

Data Source

PatentUS11594698B2Electric device and display device comprising quantum dots with improved luminous efficiency
Publication Date: 2023.02.28 SAMSUNG ELECTRONICS CO LTD
  • US11594698B2 patent drawing
  • US11594698B2 patent drawing
  • US11594698B2 patent drawing

AI summary

An electronic device includes a first electrode and a second electrode facing each other, an emission layer comprising a plurality of quantum dots, wherein the emission layer is disposed between the first electrode and the second electrode; a first charge auxiliary layer disposed between the first electrode and the emission layer; and an optical functional layer disposed on the second electrode on a side opposite the emission layer, wherein the first electrode includes a reflecting electrode, wherein the second electrode is a light-transmitting electrode, wherein a region between the optical functional layer and the first electrode comprises a microcavity structure, and a refractive index of the optical functional layer is greater than or equal to a refractive index of the second electrode.