Refrigerant Blend Composition for Low-GWP R-410A Replacement

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Solution Overview

Problem

There is a need for a refrigerant that can replace R-410A in heat exchange systems, offering excellent heat transfer properties, chemical stability, non-flammability, lubricant miscibility, and low Global Warming Potential (GWP) without requiring significant modifications to existing systems, as R-410A has a high GWP and is not a drop-in replacement for R-22.

Innovation Solution

A refrigerant composition comprising between 38% and 48% difluoromethane (HFC-32), 6% to 12% pentafluoroethane (HFC-125), 33% to 41% trifluoroiodomethane (CF3I), and 2% to 16% 2,3,3,3-tetrafluoropropene (HFO-1234yf), with specific weight ratios to achieve non-flammability and reduced GWP, ensuring compatibility with R-410A systems.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If R-410A is used as a refrigerant, then heat transfer efficiency is improved, but Global Warming Potential increases significantly

Engineering Contradiction:
Improveheat transfer efficiencyVSAvoidGlobal Warming Potential
Core Design Contradiction:
Use of energy by moving objectVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the refrigerant by blending HFC-32, HFC-125, and HFO-1234yf in specific proportions (38-48%, 6-12%, and 2-16% respectively) to achieve a GWP of less than 750 while maintaining heat transfer efficiency comparable to R-410A

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite refrigerant composition by combining multiple refrigerant components (HFC-32, HFC-125, HFO-1234yf) with specific weight ratios to achieve desired thermodynamic properties and environmental performance that individual components cannot provide alone

Inventive Principle:
Principle #40Composite materials

2Object-generated harmful factors

If a replacement refrigerant is developed, then environmental acceptability is improved, but system compatibility and heat transfer properties become difficult to achieve

Engineering Contradiction:
Improveenvironmental acceptabilityVSAvoidsystem compatibility
Core Design Contradiction:
Object-generated harmful factorsVSAdaptability or versatility

Solution Approach 1:

The patent optimizes multiple composition parameters simultaneously (proportions of HFC-32, HFC-125, HFO-1234yf) to achieve a balance between environmental performance (GWP < 750) and system compatibility (non-flammability, lubricant miscibility, heat transfer properties)

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops a refrigerant composition that serves multiple functions: it provides acceptable environmental performance, maintains non-flammability, ensures lubricant compatibility, and delivers adequate heat transfer properties, making it a versatile replacement for R-410A in existing systems

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Object-affected harmful factors

If non-flammable compounds are used, then safety is improved, but heat transfer properties and lubricant compatibility become harder to achieve

Engineering Contradiction:
Improvenon-flammabilityVSAvoidheat transfer properties
Core Design Contradiction:
Object-affected harmful factorsVSAdaptability or versatility

Solution Approach 1:

The patent adjusts the composition parameters by selecting specific ratios of non-flammable HFC and HFO components that maintain non-flammability (meeting ASHRAE Standard 34) while preserving adequate heat transfer properties through the synergistic effect of the blended components

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS11905454B2Heat transfer methods, systems and compositions
Publication Date: 2024.02.20 SOLSTICE ADVANCED MATERIALS US INC

AI summary

Disclosed are refrigerants comprising at least about 97% by weight of a blend of three compounds, said blend consisting of:from about 38% by weight to about 48% by weight difluoromethane (HFC-32),from about 6% by weight to about 12% by weight pentafluoroethane (HFC-125),from about 33% by weight to about 41% by weight trifluoroiodomethane (CF3I) andfrom about 2% by weight to about 16% by weight 2,3,3,3-tetrafluoropropene (HFO-1234yf)wherein the percentages are based on the total weight of the three compounds in the blend, and methods and systems which use same.