Rolled FeCoNiCrRn/Al-2024Al Composite Panel for Strength and Ductility

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Solution Overview

Problem

Traditional particle-reinforced aluminum matrix composites (AMCs) exhibit low ductility and local instantaneous breakability, limiting their application range, while also facing challenges in forming effective interfaces with aluminum matrices, which affects their mechanical properties.

Innovation Solution

A rolled (FeCoNiCrRn/Al)-2024Al composite panel is fabricated by adding FeCoNiCrRn medium-entropy alloy particles as a reinforcing phase to a 2024 aluminum alloy matrix, utilizing hot-roll bonding and microwave sintering to create a stable interface with a FeCoNiCrAl FCC structure, enhancing both strength and toughness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If traditional non-metallic particle reinforcement is used in aluminum matrix composite, then high strength and abrasion resistance are achieved, but effective interface formation with aluminum matrix becomes difficult and brittleness increases

Engineering Contradiction:
ImprovestrengthVSAvoidinterface stability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent uses medium-entropy alloy particles (FeCoNiCrAl) as reinforcement instead of traditional non-metallic particles. This composite reinforcement phase combines multiple metallic elements in specific atomic ratios to achieve both high strength and good interfacial compatibility with the aluminum matrix, resolving the contradiction between strength and interface stability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the atomic ratios of Fe, Co, Ni, Cr, and Al elements in the medium-entropy alloy particles, controlling them within specific ranges (e.g., Al: 30-50 at%, Fe: 10-20 at%). This parameter optimization ensures the reinforcement phase achieves high strength while maintaining good wettability and stability with the aluminum matrix.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If medium-entropy alloy particles are used as reinforcement, then excellent interface wettability and stable interface are formed, but the sintering temperature and inherent brittleness of metal-based reinforcing phase are limited

Engineering Contradiction:
Improveinterface stabilityVSAvoidsintering temperature
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent optimizes the composition parameters of the medium-entropy alloy, specifically controlling the Al content at 30-50 at% and adding small amounts of Y (0.1-5 at%) and R (0.1-5 at%). This compositional parameter optimization lowers the sintering temperature requirement while maintaining interface stability and preventing excessive brittleness.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces Y and R elements in small amounts to specifically improve the interfacial properties and reduce brittleness of the medium-entropy alloy particles. These local compositional adjustments address the brittleness issue without compromising the overall interface stability achieved by the medium-entropy alloy structure.

Inventive Principle:
Principle #3Local quality

3Strength

If traditional particle-reinforced AMC is used, then high strength is achieved, but low ductility and local instantaneous breakability severely limit application range

Engineering Contradiction:
ImprovestrengthVSAvoidductility
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The patent uses medium-entropy alloy particles with a specific multi-element composition (FeCoNiCrAl system) as reinforcement. This composite reinforcement phase provides both high strength and improved ductility compared to traditional non-metallic particles, as the metallic nature of the reinforcement allows for better plastic deformation and energy absorption.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the atomic ratios of the medium-entropy alloy elements, particularly controlling the balance between strengthening elements (Fe, Co, Ni) and ductility-enhancing elements (Al, Y, R). This parameter optimization ensures the composite achieves both high strength and improved ductility, expanding its application range.

Inventive Principle:
Principle #35Parameter changes

4Strength

If FeCoNiCrRn medium-entropy alloy particles are added to aluminum matrix, then high strength and toughness are achieved, but the complexity of controlling multiple element ratios increases

Engineering Contradiction:
ImprovestrengthVSAvoidcomposition control complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent defines specific atomic ratio ranges for each element in the medium-entropy alloy (Al: 30-50 at%, Fe: 10-20 at%, Co: 10-20 at%, Ni: 10-20 at%, Cr: 5-15 at%, Y: 0.1-5 at%, R: 0.1-5 at%). These parameter specifications simplify the composition control by providing clear ranges rather than requiring precise single-value control, thus reducing complexity while maintaining high strength and toughness.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite panel achieves improved mechanical properties, including high strength, toughness, and fatigue crack growth resistance, while maintaining light weight and low cost, addressing the limitations of traditional AMCs by combining the benefits of medium-entropy alloys and 2024 aluminum alloys.

Implementation Method 1

the excellent interface wettability between a metal-based reinforcement and an aluminum alloy matrix makes a stable and effective interface formed between the reinforcement particles and the aluminum matrix

Methodology Applied
Scientific EffectInterface wettability: Wetting

Implementation Method 2

subjecting a 2024Al aluminum alloy plate and the FeCoNiCrRn/Al aluminum matrix composite as raw materials to hot-roll bonding to obtain the rolled (FeCoNiCrRn/Al)-2024Al composite panel

Methodology Applied
Scientific EffectHot-roll bonding: Welding

Data Source

PatentUS11731178B2Rolled (FeCoNiCrRn/Al)-2024Al composite panel and fabrication method thereof
Publication Date: 2023.08.22 JIANGSU UNIV
  • US11731178B2 patent drawing

AI summary

Disclosed are a rolled (FeCoNiCrRn/Al)-2024Al composite panel and a preparation method therefor. The preparation method involves taking pure aluminum as a matrix, adding an FeCoNiCrRn medium-entropy alloy with a high strength and toughness as an reinforcing phase to prepare an FeCoNiCrRn/Al composite material, then laminating the FeCoNiCrRn/Al composite material with aluminum alloy 2024, and preparing the (FeCoNiCrRn/Al)-2024Al composite board by means of hot-rolling recombination, which solves the problem that high-strength aluminum matrix composites (AMCs) are prone to instantaneous breakability and low ductility, thereby improving the overall performance of the material. The present disclosure adopts microwave sintering (MWS) to fabricate a medium-entropy alloy-reinforced AMC, and adopts hot-roll bonding to fabricate the (FeCoNiCrRn/Al)-2024Al metal composite panel. The composite panel fabricated by the present disclosure has excellent comprehensive mechanical properties, and has high application values for promoting the application of modern lightweight and high-efficiency industrial materials in aerospace, new energy vehicles, and the like.