Rubber Composition with Epoxy Dipolar Compound

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Solution Overview

Problem

Rubber compositions reinforced with silica or carbon black face a trade-off between improved dispersion, which reduces cured rigidity, and the need for limited plasticizer addition, limiting tire performance variability.

Innovation Solution

Incorporating a 1,3-dipolar compound with an epoxy group into the rubber composition, which enhances filler dispersion while maintaining a balance between cured rigidity and hysteresis, allowing for improved reinforcement and performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If the dispersion of silica or carbon black is improved in the rubber composition, then the reinforcing properties are enhanced, but the cured rigidity decreases

Engineering Contradiction:
Improvereinforcing propertiesVSAvoidcured rigidity
Core Design Contradiction:
StrengthVSStress or pressure

Solution Approach 1:

The invention changes the chemical composition parameters of the rubber compound by introducing a 1,3-dipolar compound with epoxy group. This compound modifies the interaction between filler particles and rubber matrix, enabling improved dispersion while maintaining rigidity through chemical bonding mechanisms rather than physical mixing alone.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite system combining diene elastomer, silica or carbon black filler, and 1,3-dipolar compound with epoxy group. This multi-component composite achieves synergistic effects where the dipolar compound acts as a coupling agent between filler and rubber, simultaneously improving dispersion and preserving mechanical properties.

Inventive Principle:
Principle #40Composite materials

2Stress or pressure

If the amount of plasticizer added to the rubber composition is limited to maintain cured rigidity, then the reinforcing properties are preserved, but the flexibility in tire performance formulation is reduced

Engineering Contradiction:
Improvecured rigidityVSAvoidformulation flexibility
Core Design Contradiction:
Stress or pressureVSAdaptability or versatility

Solution Approach 1:

The invention changes the formulation approach by replacing plasticizer-based rigidity adjustment with a chemical coupling mechanism. The 1,3-dipolar compound with epoxy group provides rigidity through chemical bonding, freeing up plasticizer usage for other performance optimizations and restoring formulation flexibility.

Inventive Principle:
Principle #35Parameter changes

3Strength

If a 1,3-dipolar compound with epoxy group is added to improve filler dispersion, then the reinforcing properties are enhanced while cured rigidity is maintained, but the formulation complexity increases

Engineering Contradiction:
Improvereinforcing propertiesVSAvoidformulation complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The 1,3-dipolar compound with epoxy group serves multiple functions simultaneously: it acts as a dispersing agent for filler particles, a coupling agent between filler and rubber matrix, and a reinforcement promoter. This multi-functionality reduces the need for multiple separate additives, actually simplifying the overall formulation despite the specialized nature of the compound.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of a 1,3-dipolar compound with an epoxy group in rubber compositions reinforced with silica or carbon black improves filler dispersion, maintaining rigidity and hysteresis properties, thus enhancing tire performance and flexibility in formulation.

Implementation Method 1

a 1,3-dipolar compound comprising an epoxy group

Methodology Applied
Scientific Effect1,3-dipolar compound interaction: Chemical Bonding

Implementation Method 2

a vulcanization system

Methodology Applied
Scientific EffectVulcanization: Chemical Bonding

Data Source

PatentEP3713773B1Rubber composition
Publication Date: 2022.03.23 MICHELIN & CO (CIE GEN DES ESTAB MICHELIN)
  • EP3713773B1 patent drawing
  • EP3713773B1 patent drawing
  • EP3713773B1 patent drawing

AI summary

The present invention relates to a rubber composition based on at least one diene elastomer, a 1,3-dipolar compound comprising an epoxide group, a reinforcing filler comprising a silica or a carbon black and a vulcanization system. A rubber composition of this kind exhibits improved dispersion of the silica or the carbon black as well as a good compromise in terms of the properties consisting of the rigidity in the cured state, the hysteresis and the reinforcement.