Selective Deposition of Nickel Oxide Memory Cells

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Solution Overview

Problem

Fabricating memory devices from rewriteable resistivity-switching materials is difficult due to their chemical etchability, which increases fabrication costs and complexity in integrated circuits.

Innovation Solution

A selective deposition process is used to form reversible resistance-switching elements, such as nickel oxide, without the need for etching, by depositing nickel-containing layers only on conductive surfaces and then oxidizing them, simplifying the fabrication of memory cells and eliminating the need for etching of these materials.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If rewriteable resistivity-switching materials are used in memory devices, then memory functionality is achieved, but fabrication complexity and costs increase due to chemical etching requirements

Engineering Contradiction:
Improvefabrication processVSAvoidfabrication complexity
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The patent extracts the etching step from the fabrication process by using selectively deposited nickel oxide layers that do not require chemical etching. The nickel oxide is deposited only on conductive surfaces through selective deposition, eliminating the need for subsequent etching operations and thereby reducing fabrication complexity.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent replaces the chemical etching process with a physical deposition process. Instead of using chemical etchants to remove material, the nickel oxide layer is selectively deposited onto conductive surfaces using physical vapor deposition or similar techniques, substituting a mechanical/physical process for a chemical one.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Manufacturing precision

If nickel and nickel oxide layers are deposited and etched in integrated circuits, then reversible resistance-switching elements are formed, but fabrication costs and process complexity increase

Engineering Contradiction:
Improveformation of resistance-switching elementsVSAvoidfabrication process
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The nickel oxide layer performs dual functions: it serves as both the reversible resistance-switching material and as a self-aligned patterned layer. The selective deposition ensures the material is placed only where conductive surfaces exist, making the layer self-patterned and eliminating the need for separate photolithography and etching steps to define its location.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The nickel oxide layer serves multiple functions simultaneously: it provides the reversible resistance-switching functionality, acts as a self-aligned patterned structure, and eliminates the need for separate etching processes. This multi-functionality reduces the overall number of fabrication steps required.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach simplifies the fabrication of memory cells by eliminating the etching process for nickel and nickel oxide layers, reducing complexity and costs, while enabling the use of difficult-to-etch materials like nickel oxide in memory devices.

Implementation Method 1

a selective deposition process is used to form reversible resistance-switching elements, such as nickel oxide, without the need for etching, by depositing nickel-containing layers only on conductive surfaces

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Implementation Method 2

by depositing nickel-containing layers only on conductive surfaces and then oxidizing them

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS8913417B2Memory cell that employs a selectively deposited reversible resistance-switching element and methods of forming the same
Publication Date: 2014.12.16 SAMSUNG ELECTRONICS CO LTD
  • US8913417B2 patent drawing
  • US8913417B2 patent drawing
  • US8913417B2 patent drawing

AI summary

A memory cell is provided that includes a steering element, a reversible resistance-switching element coupled to the steering element and a silicide-forming metal layer disposed between the steering element and the reversible resistance-switching element. The reversible resistance-switching element includes tantalum, and is formed using a selective deposition process. Numerous other aspects are provided.