Self-Healing Cement Sheath via Hydrocarbon Swelling

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Solution Overview

Problem

Current well cements fail to restore zonal isolation once cracks, gaps, or microannuli form, especially in environments with high concentrations of gaseous hydrocarbons, which compromise the integrity and safety of subterranean wells.

Innovation Solution

Incorporating a composition of settable materials, such as Portland cement or geopolymers, with thermoplastic block copolymers and asphaltite mineral particles that form a pumpable slurry, allowing the particles to swell and self-repair the cement sheath upon exposure to hydrocarbons, thereby maintaining hydraulic isolation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional cement formulations are used, then the cement sheath provides initial zonal isolation, but it fails to restore isolation once cracks or microannuli form

Engineering Contradiction:
Improvezonal isolation restorationVSAvoidresponse to downhole fluids
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The cement formulation contains dormant swelling particles that automatically activate upon exposure to downhole hydrocarbons through self-healing mechanisms. The particles swell in response to hydrocarbon contact, sealing cracks and microannuli without external intervention, thereby restoring zonal isolation autonomously.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The swelling particles undergo parameter changes in their physical state when exposed to hydrocarbons. The particles transition from a dormant state to an activated swollen state, changing their volume and physical properties to seal defects in the cement sheath, enabling adaptive response to environmental conditions.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If the cement formulation includes swelling particles activated by hydrocarbons, then self-healing capability is achieved, but the formulation must remain pumpable during placement

Engineering Contradiction:
Improveself-healing capabilityVSAvoidpumpability during placement
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The swelling particles are pre-incorporated into the cement formulation in a dormant state during manufacturing, allowing the cement to maintain pumpability during placement. The particles are designed to remain inactive during pumping and setting, then activate only after the cement has set and hydrocarbons penetrate the cement sheath.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The formulation exhibits dynamic behavior where the swelling particles transition from a non-reactive state during placement to an active swelling state upon hydrocarbon exposure. This dynamic characteristic allows the cement to maintain pumpability during installation while acquiring self-healing capabilities afterward.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The self-healing cement composition effectively restores and maintains zonal isolation in subterranean wells, even under high gaseous hydrocarbon concentrations, enhancing the integrity and safety of the well by sealing cracks and defects.

Implementation Method 1

the particles will swell and enable the cement sheath to self-repair

Methodology Applied
Scientific EffectSwelling:

Data Source

PatentUS9222011B2Self-adaptive cements
Publication Date: 2015.12.29 SCHLUMBERGER TECH CORP
  • US9222011B2 patent drawing
  • US9222011B2 patent drawing

AI summary

A self-adaptive cement formulation includes cement, water, block copolymer and asphaltite-mineral particles. The set cement demonstrates self-healing properties when exposed to methane, and is particularly suited for well-cementing applications. After placement and curing, the self-healing properties help maintain zonal isolation should bonding be disrupted between the set cement and the formation or a casing string, should cracks or defects appear in the set-cement matrix, or both.