Electrochemical Sensor Housing Surface Coating for Electrolyte Positioning

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Solution Overview

Problem

Electrochemical sensors face inefficiency and electrolyte leakage due to the electrolyte drying out or receding from the active region, which affects their operation over time.

Innovation Solution

The use of hydrophobic and hydrophilic materials arranged within the sensor housing to encourage the electrolyte to remain positioned over the active region, preventing drying out and leakage by repelling or attracting the electrolyte through specific patterns and configurations.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If the electrolyte is exposed to the natural environment through holes or pores in the housing, then gas sensing function is enabled, but the electrolyte dries out or recedes from the active region over time

Engineering Contradiction:
Improvegas sensing functionVSAvoidelectrolyte position stability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The housing interior is divided into regions with different surface properties: hydrophobic regions (repelling the electrolyte) and hydrophilic regions (attracting the electrolyte). The hydrophobic material is applied to specific areas such as the ceiling and upper walls of the housing, while the bottom region near the electrodes remains hydrophilic or untreated. This local differentiation creates a gradient that guides the electrolyte to remain in the active region without complete sealing, thus maintaining both gas sensing function and electrolyte position stability.

Inventive Principle:
Principle #3Local quality

2Reliability

If hydrophobic or hydrophilic materials are applied to the housing interior, then the electrolyte is encouraged to remain in the active region, but the device complexity increases

Engineering Contradiction:
Improveelectrolyte position stabilityVSAvoidhousing structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention changes the surface energy parameters of the housing materials by applying hydrophobic or hydrophilic coatings. Instead of modifying the physical structure of the housing, the solution alters the chemical surface properties of existing surfaces. This allows electrolyte position control through material property modification rather than structural complexity, reducing device complexity while maintaining reliability.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If the electrolyte is allowed to move freely in the housing, then manufacturing is simpler, but the electrolyte may escape or dry out affecting sensor efficiency

Engineering Contradiction:
Improveelectrolyte filling processVSAvoidsensor efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The hydrophobic and hydrophilic materials are applied to the housing interior before the electrolyte is introduced. This preliminary action creates the surface energy gradient that will subsequently guide and confine the electrolyte in the desired active region. The electrolyte filling process remains simple and unrestricted, but the pre-applied surface treatments ensure the electrolyte self-organizes into the correct position, maintaining both ease of manufacture and sensor efficiency.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution ensures the electrolyte remains correctly positioned, maintaining sensor efficiency and stability throughout its lifetime by keeping the active region wet and preventing electrolyte escape.

Implementation Method 1

The inner walls, base and ceiling of the housing are coated in either hydrophobic or hydrophilic materials, or both, so as to encourage the electrolyte to take a position over the active region

Methodology Applied
Scientific EffectHydrophobic effect: Hydrophobe

Implementation Method 2

The inner walls, base and ceiling of the housing are coated in either hydrophobic or hydrophilic materials, or both, so as to encourage the electrolyte to take a position over the active region

Methodology Applied
Scientific EffectHydrophilic effect: Hydrophile

Implementation Method 3

the hydrophobic and/or hydrophilic material may be patterned in a way so as to cause movement of the electrolyte to be repelled away from the hydrophobic material and attracted towards the hydrophilic material

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Data Source

PatentUS11536680B2Electrochemical sensor and method of forming thereof
Publication Date: 2022.12.27 ANALOG DEVICES INT UNLTD CO
  • US11536680B2 patent drawing
  • US11536680B2 patent drawing
  • US11536680B2 patent drawing

AI summary

Electrochemical sensors include a housing within which an electrolyte is provided over the electrodes. The housing includes an active region, which is the area around the electrodes in which the electrolyte must be positioned to ensure correct operation of the device. The inner walls, base and ceiling of the housing are coated in either hydrophobic or hydrophilic materials, or both, so as to encourage the electrolyte to take a position over the active region, which is defined by the position of the electrodes. In some electrochemical sensors, a combination of hydrophobic and hydrophilic materials is used and the materials can be arranged in a pattern, which encourages the electrolyte to take a position over the active region.