Silane Curable Composition with Non-Tin Fast Curing Catalysts

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing curable compositions containing organic polymers with bifunctional dialkoxysilyl groups and non-tin catalysts suffer from insufficient curing rates.

Innovation Solution

A curable composition using a combination of an amidine compound and a titanium compound as the curing catalyst, along with a silane condensate having a specific structure, to enhance curing speed.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If an organic polymer having a bifunctional dialkoxysilyl group is used as the reactive silicon group to obtain a cured product having high elongation and flexibility, then the mechanical properties of the cured product are improved, but the hydrolyzability of the organic polymer is low resulting in insufficient curing rate

Engineering Contradiction:
Improvemechanical properties of cured productVSAvoidcuring rate
Core Design Contradiction:
StrengthVSProductivity

Solution Approach 1:

The patent changes the chemical parameters of the catalyst system by selecting specific metal compounds (titanium, zirconium, hafnium alkoxides) and organic bases (amidine, guanidine, carbodiimide compounds) to optimize the hydrolysis and condensation reaction rates of the bifunctional dialkoxysilyl groups, thereby achieving both high mechanical properties and fast curing rate

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite catalyst system combining metal compounds (providing Lewis acid catalysis) and organic base compounds (providing nucleophilic catalysis) to synergistically enhance the hydrolyzability of the low-hydrolyzability organic polymer having bifunctional dialkoxysilyl groups, resolving the contradiction between maintaining mechanical properties and improving curing rate

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If a non-tin catalyst is used to reduce toxicity, then the safety of the curable composition is improved, but the curing rate becomes insufficient

Engineering Contradiction:
ImprovetoxicityVSAvoidcuring rate
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent introduces metal compounds (titanium, zirconium, hafnium alkoxides) as intermediary catalysts that mediate the hydrolysis and condensation reactions of silane groups. These metal compounds provide efficient catalytic activity comparable to or exceeding organotin compounds while being less toxic, and they work synergistically with organic base compounds to achieve fast curing rates without the toxicity problems of traditional tin catalysts

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the catalytic parameters by selecting metal compounds with specific properties (Lewis acidity, alkoxide groups) that enhance their catalytic efficiency for silane hydrolysis and condensation. This parameter optimization allows non-tin catalysts to achieve curing rates that were previously only attainable with toxic organotin compounds

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves fast curability and effective crosslinking of organic polymers with bifunctional dialkoxysilyl groups, providing improved adhesion and stability.

Implementation Method 1

The organic polymer having at least one reactive silicon group in the molecule can be crosslinked by a hydrolysis reaction of silyl groups, due to moisture even at room temperature, etc. accompanied by siloxane bond formation.

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 2

crosslinked by a hydrolysis reaction of silyl groups... accompanied by siloxane bond formation

Methodology Applied
Scientific EffectCondensation reaction:

Implementation Method 3

The curable composition containing an organic polymer having a reactive silicon group is usually cured using a silanol condensation catalyst such as an organotin compound having a carbon-tin bond typified by dibutyltin bis(acetylacetonato). The silanol condensation catalyst is also referred to as a curing catalyst.

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentEP4692247A1Curable composition
Publication Date: 2026.02.11 KANEKA CORP
  • EP4692247A1 patent drawing
  • EP4692247A1 patent drawing
  • EP4692247A1 patent drawing

AI summary

The present invention provides a curable composition that contains a silane compound, a non-tin-based curing catalyst, and an organic polymer having a bifunctional dialkoxysilyl group as a reactive silicon group, and that exhibits quick curability. Provided is a curable composition that contains a silane compound, a non-tin-based curing catalyst, and an organic polymer having a bifunctional dialkoxysilyl group as a reactive silicon group, wherein an amidine compound and a titanium compound are used in combination as the curing catalyst, and a silane condensate having a specific structure is used as the silane compound.