Silicone Surface Protection Composition for Water and Oil Repellency

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current non-fluoropolymer technologies face challenges in achieving efficient water and oily soil repellency on surfaces while being cost-effective and environmentally friendly, with existing compositions often requiring significant sacrifices in stability and performance.

Innovation Solution

A surface treatment composition comprising an aqueous polyorganosiloxane fluid-silicone resin mixture, with specific molecular formulations and ratios, along with a protonating agent and optional emulsifier, applied in various forms such as laundry sprays or hard surface cleaners, to provide water and oil repellency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If fluoropolymers are used to provide water and oil repellency, then stain protection efficiency is improved, but environmental and health safety concerns arise due to potential persistent bioaccumulation and toxicity

Engineering Contradiction:
Improvestain protection efficiencyVSAvoidenvironmental and health safety
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent removes fluoropolymer components from the composition entirely, extracting the harmful substance while retaining the desired water and oil repellency function through alternative polyorganosiloxane and silicone resin components

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent employs conventional polyorganosiloxane and silicone resin materials that are environmentally benign and do not persist in the environment like fluoropolymers, effectively using shorter-lived, safer materials to replace persistent harmful ones

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Object-affected harmful factors

If non-fluoropolymer compositions are used to avoid environmental concerns, then environmental safety is improved, but water and oily soil repellency efficiency deteriorates

Engineering Contradiction:
Improveenvironmental safetyVSAvoidwater and oily soil repellency
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent creates a composite system combining polyorganosiloxane fluids with silicone resins in specific ratios, where the synergistic interaction between these components achieves superior water and oil repellency that neither component could achieve alone, matching or exceeding fluoropolymer performance

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes specific parameters including the ratio of polyorganosiloxane to silicone resin (2:98 to 95:5), molecular weight ranges, and viscosity specifications to maximize repellency efficiency while maintaining environmental safety

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If non-fluoropolymer compositions are developed to provide stain protection, then environmental friendliness is improved, but product stability and performance characteristics deteriorate

Engineering Contradiction:
Improveenvironmental friendlinessVSAvoidproduct stability
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent specifies precise parameter ranges including pH (2-8), viscosity (1-100,000 cP), and compositional ratios to ensure product stability during storage and application, preventing phase separation and maintaining consistent performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs emulsifiers as intermediary substances to stabilize the mixture of polyorganosiloxane and silicone resin, preventing phase separation and ensuring homogeneous distribution of active ingredients throughout the composition

Inventive Principle:
Principle #24Intermediary (Mediator)

4Object-affected harmful factors

If conventional non-fluoropolymer treatments are applied to achieve water repellency, then environmental safety is improved, but cost-effectiveness and convenience deteriorate

Engineering Contradiction:
Improveenvironmental safetyVSAvoidcost-effectiveness
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

The patent uses commercially available, inexpensive polyorganosiloxane and silicone resin materials that are readily produced at scale, making the treatment cost-effective compared to specialized fluoropolymer alternatives while providing sufficient durability

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively reduces the propensity of surfaces to stain from water or oil-based soils, offering high efficiency and stability in a convenient and affordable format, suitable for diverse substrates including textiles and hard surfaces.

Implementation Method 1

provide protection of surfaces by repelling water and oil based soils from the surface

Methodology Applied
Scientific EffectHydrophobic effect: Hydrophobe

Implementation Method 2

aqueous polyorganosiloxane fluid-silicone resin mixture

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Data Source

PatentEP2619271B1Non-fluoropolymer surface protection composition
Publication Date: 2018.05.16 PROCTER & GAMBLE CO
  • EP2619271B1 patent drawing
  • EP2619271B1 patent drawing
  • EP2619271B1 patent drawing

AI summary

The present invention encompasses a surface treatment composition which comprises a polyorganosiloxane fluid-silicone resin mixture and a carrier. The polyorganosiloxane fluid-silicone resin mixture comprises about 2% to about 95%, by weight of the mixture, of one or more polyorganosiloxane fluid compounds; from about 1% to about 10%, by weight of the mixture, of one or more silicone resin, a protonation agent, at least about 5%, by weight of the mixture; of water; and optionally, less than about 5%, by weight of the mixture, of an emulsifier.