Negative-Working Photosensitive Siloxane Composition Without Post-Exposure Baking

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Solution Overview

Problem

Conventional negative-working photosensitive siloxane compositions require a post-exposure baking step for complete curing, which is energy-intensive and inefficient, and they lack high sensitivity and resolution in forming optical or physical characteristics for advanced display technologies.

Innovation Solution

A negative-working photosensitive siloxane composition comprising polysiloxane, a silicon-containing compound with an ureido bond, and a photo-polymerization initiator, which allows for light exposure and development without the need for post-exposure baking, achieving high sensitivity and resolution with excellent transparency, heat resistance, and chemical resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a conventional negative-working photosensitive siloxane composition is used, then the composition can be coated and exposed to light, but it requires a post-exposure baking step for complete curing which consumes energy and reduces production efficiency

Engineering Contradiction:
Improveproduction efficiencyVSAvoidenergy consumption for heating
Core Design Contradiction:
ProductivityVSUse of energy by stationary object

Solution Approach 1:

The patent modifies the chemical composition parameters of the photosensitive system by selecting specific photo-polymerization initiators and silane compounds that enable complete curing through light exposure alone, eliminating the need for post-exposure baking and thereby reducing energy consumption while maintaining productivity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent extracts and removes the post-exposure baking step from the manufacturing process by designing a photosensitive composition that achieves complete curing during the light exposure step itself, eliminating this energy-intensive intermediate step and improving production efficiency

Inventive Principle:
Principle #2Taking out (Extraction)

2Manufacturing precision

If a conventional negative-working photosensitive siloxane composition is used, then the composition can form a cured film, but it lacks high sensitivity and resolution for advanced display technologies

Engineering Contradiction:
ImproveresolutionVSAvoidsensitivity
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent employs a composite photosensitive composition containing specifically selected photo-polymerization initiators, silane compounds, and additives that work synergistically to achieve both high sensitivity for reliable exposure and high resolution for advanced display applications, overcoming the limitations of conventional single-component systems

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition forms a cured film that is superior in optical and physical characteristics, eliminating the need for post-exposure baking, enhancing production efficiency, and providing excellent performance in display technologies and semiconductor applications.

Implementation Method 1

a photo-polymerization initiator

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Data Source

PatentUS9684240B2Negative-working photosensitive siloxane composition
Publication Date: 2017.06.20 MERCK PATENT GMBH
  • US9684240B2 patent drawing
  • US9684240B2 patent drawing
  • US9684240B2 patent drawing

AI summary

To provide a negative-working photosensitive siloxane composition developable inorganically, and also to provide a cured film-manufacturing method employing that. The present invention provides a negative-working photosensitive siloxane composition comprising a polysiloxane, a silicon-containing compound having an ureido bond, a polymerization initiator, and a solvent. This composition is coat on a substrate, exposed to light, and developed, so that a cured film can be obtained without carrying out post-exposure baking.