Silver-Reinforced 316L Composite for Fuel Cell Bipolar Plates

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Solution Overview

Problem

316L stainless steel alone cannot meet the high requirements for corrosion-resistance and electrical conductivity needed for proton exchange membrane fuel cell bipolar plates, and traditional composite technologies face issues like poor bonding, segregation, complexity, and high cost.

Innovation Solution

A micron silver particle-reinforced 316L stainless steel matrix composite is created using selective laser melting (SLM) technology, where silver particles are uniformly distributed in the 316L stainless steel matrix, improving corrosion-resistance and electrical conductivity, with a preparation method involving mechanical ball milling and SLM forming.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional composite methods are used to add reinforcement particles to 316L stainless steel, then the corrosion-resistance and electrical conductivity can be improved, but the bonding between reinforcement and matrix deteriorates

Engineering Contradiction:
Improvecorrosion-resistanceVSAvoidbonding strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent utilizes selective laser melting (SLM) technology to melt the powder mixture and form the composite. The laser heating causes phase transition from solid powder to molten state, enabling complete fusion between silver particles and 316L stainless steel matrix, thereby achieving strong bonding and eliminating the bonding issues of traditional composite methods

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The patent creates a composite material system combining silver particles (1-5 wt%) with 316L stainless steel matrix. This composite structure leverages the high electrical conductivity and corrosion-resistance of silver while maintaining the mechanical strength and formability of stainless steel, achieving synergistic performance improvement

Inventive Principle:
Principle #40Composite materials

2Reliability

If traditional composite methods are used to add reinforcement particles, then the corrosion-resistance and electrical conductivity can be improved, but the reinforcement phase segregates

Engineering Contradiction:
Improveelectrical conductivityVSAvoiduniformity of reinforcement distribution
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent performs preliminary mechanical ball milling to mix the silver powder and 316L stainless steel powder before SLM processing. This pre-mixing action ensures homogeneous distribution of reinforcement particles in the powder blend, preventing segregation during subsequent laser melting and achieving uniform microstructure in the final composite

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent replaces traditional mechanical composite methods (such as stir-casting or powder metallurgy compaction) with selective laser melting technology. The laser field enables precise local melting and rapid solidification, which locks in the uniform particle distribution achieved during pre-mixing and prevents segregation that occurs in conventional mechanical processing

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Reliability

If traditional composite technologies are used, then the reinforcement can be added, but the process becomes complicated and cost increases

Engineering Contradiction:
Improvecorrosion-resistanceVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines multiple functions into a single SLM processing step: powder mixing (through pre-milling), heating, melting, solidification, and densification all occur in one integrated process. This eliminates the need for separate steps for particle addition, bonding, and microstructure control that characterize traditional composite methods, thereby simplifying the overall manufacturing process

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent utilizes controllable laser parameters (power, scanning speed, hatch distance) and processing atmosphere (inert gas protection) to optimize the SLM process. By adjusting these parameters, the process achieves complete melting, uniform particle distribution, and high-density microstructure in a single step, simplifying the process while maintaining high corrosion-resistance

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite achieves excellent electrical conductivity and corrosion-resistance, simplifying the process, reducing costs, and expanding the application of 316L stainless steel in fuel-cell bipolar plates and other fields with high requirements.

Implementation Method 1

selective laser melting (SLM) technology has attracted people's attention due to its advantages of high melting-concreting speed, tiny formed material structures

Methodology Applied
Scientific EffectSelective Laser Melting: Laser Beam Welding

Implementation Method 2

mixing raw materials of a spherical silver powder and a spherical 316L stainless steel powder and subjecting a resulting mixture to mechanical ball milling

Methodology Applied
Scientific EffectMechanical Ball Milling: Mechanical Force

Data Source

PatentUS11946122B2Micron silver particle-reinforced 316L stainless steel matrix composite and preparation method thereof
Publication Date: 2024.04.02 NANJING UNIV OF AERONAUTICS & ASTRONAUTICS
  • US11946122B2 patent drawing
  • US11946122B2 patent drawing
  • US11946122B2 patent drawing

AI summary

The present disclosure relates to a micron silver particle-reinforced 316L stainless steel matrix composite, including a 316L stainless steel matrix and silver particles uniformly distributed in the 316L stainless steel matrix. The silver particles have a weight 1% to 5% of the total weight of the composite; and the composite has a density of 7.9 g/cm3 to 8.2 g/cm3 and a relative density of more than 98%. The composite is prepared by the following method: mixing raw materials of a spherical silver powder and a spherical 316L stainless steel powder; subjecting a resulting mixture to mechanical ball milling to obtain a mixed powder; sieving the mixed powder and adding a resulting powder to a powder cylinder of an SLM forming machine; and charging an inert protective gas for printing to obtain the composite.