Multilayer Single-Crystal Copper Lamination for Scalable High Conductivity

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Solution Overview

Problem

Current commercialized single-crystal copper materials are expensive and limited in area, making them unsuitable for large-scale applications in microelectronic industry and traditional power transmission.

Innovation Solution

A method involving the lamination of multiple layers of single-crystal copper foils, followed by pressurizing and annealing, or direct hot rolling, to produce an ultrahigh-conductivity multilayer single-crystal laminated copper material.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If bulk crystal growth or thin film deposition is used to prepare single-crystal copper, then single-crystal structure is achieved, but the material is expensive and limited in area

Engineering Contradiction:
Improvesingle-crystal structure qualityVSAvoidproduction cost and scalability
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The invention divides the single-crystal copper material into multiple thin foil layers that are laminated together. Each foil layer maintains its single-crystal structure, and through hot rolling or pressurizing-annealing treatment, they form a multilayer single-crystal laminated structure that preserves the electrical properties of single-crystal copper while enabling large-scale production through conventional foil manufacturing techniques

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention creates a composite structure by laminating multiple single-crystal copper foils together to form a multilayer single-crystal laminated copper material. This composite approach combines the advantages of single-crystal copper (high conductivity) with the manufacturability of foil-based materials, achieving both excellent electrical properties and scalability

Inventive Principle:
Principle #40Composite materials

2Area of stationary object

If multiple layers of single-crystal copper foils are laminated and pressurized-annealed or hot-rolled, then large-area single-crystal copper material is produced, but grain boundary formation may occur during processing

Engineering Contradiction:
Improvematerial areaVSAvoidsingle-crystal structure integrity
Core Design Contradiction:
Area of stationary objectVSReliability

Solution Approach 1:

The invention carefully controls processing parameters including temperature (500-1100°C for pressurizing-annealing, or appropriate temperatures for hot rolling), pressure (0.5-200 MPa), and deformation amount to enable the laminated foils to bond together while maintaining their single-crystal structure. The parameters are optimized to prevent grain boundary formation during the consolidation process

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention performs preliminary preparation by selecting foils with appropriate single-crystal orientations (such as <100>, <110>, or <111> orientations) before lamination. This preliminary orientation control ensures that the final laminated structure maintains excellent electrical properties and prevents grain boundary formation during subsequent processing

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method results in a copper material with conductivity greater than or equal to 105% IACS, suitable for large-scale applications in microelectronic industry and traditional power transmission, while reducing production costs.

Implementation Method 1

pressurizing and annealing the laminate as one piece by performing pressurizing and high-temperature annealing at the same time

Methodology Applied
Scientific EffectAnnealing: Annealing

Implementation Method 2

pressurizing and annealing the laminate as one piece... keeping the static pressure of 0.5 MPa to 200 MPa constant... when the temperature of the annealing furnace is raised to 500-1100° C.

Methodology Applied
Scientific EffectDiffusion bonding: Diffusion Welding

Implementation Method 3

pressing the laminate as one piece by means of direct hot rolling... placing it in front of a hot roller of a hot rolling mill... elevating the temperature of the hot roller... keeping the pressure between the hot rollers of 0.5 MPa to 200 MPa constant

Methodology Applied
Scientific EffectHot rolling:

Data Source

PatentUS12203193B2Preparation method for ultrahigh-conductivity multilayer single-crystal laminated copper material, and copper material
Publication Date: 2025.01.21 PEKING UNIV
  • US12203193B2 patent drawing

AI summary

Provided is a preparation method for an ultrahigh-conductivity multilayer single-crystal laminated copper material, where multiple layers of single-crystal copper foils are laminated together to form a laminate, and the laminate is pressurized and annealed as one piece by performing pressurizing and high-temperature annealing at the same time, or the laminate is pressed as one piece by means of direct hot rolling, thereby obtaining an ultrahigh-conductivity multi-layer single-crystal laminated copper material, whereby, according to the method, multiple layers of single-crystal copper foils are used as raw materials, an ultrahigh-conductivity multi-layer single-crystal laminated copper material is prepared by means of hot rolling or pressing and annealing, and the conductivity of the copper material is greater than or equal to 105% IACS.