Single-Stranded DNA Library Preparation with Anti-Dimer Ligation

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Solution Overview

Problem

Existing methods for preparing double-stranded DNA libraries from single-stranded DNA fragments face inefficiencies in yield and produce significant amounts of adaptor dimers, which complicate sequencing and purification.

Innovation Solution

A method involving TACS ligation followed by topoisomerase I (VTopoI) ligation to minimize adaptor dimers, using a sequence with a nick and uracil or dSpacer to prevent dimer formation, and PCR to amplify the tagged DNA.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional library preparation methods (e.g., TACS-T4) are used to improve library yield, then library yield increases significantly, but adaptor dimer production increases as a harmful by-product

Engineering Contradiction:
Improvelibrary yieldVSAvoidadaptor dimer production
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The invention extracts and removes the harmful adaptor dimer by-products from the library preparation process through selective purification steps, separating them from the desired library products to resolve the contradiction between high yield and low dimer contamination

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the chemical parameters of the adaptor sequences by introducing specific modifications (such as different phosphorylation patterns, overhang sequences, or chemical modifications) that prevent adaptor dimers from forming while maintaining efficient ligation to target DNA, thus achieving high yield without dimer by-products

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If adaptor dimers are removed by purification to improve sequencing quality, then sequencing accuracy improves, but the process becomes more complex and time-consuming

Engineering Contradiction:
Improvesequencing qualityVSAvoidpurification process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention performs preliminary action by designing adaptors with built-in anti-dimer features (such as asymmetric phosphorylation or specific overhang sequences) that prevent dimer formation at the source, eliminating the need for complex post-preparation purification steps and simplifying the overall workflow while maintaining high sequencing quality

Inventive Principle:
Principle #10Preliminary action

3Manufacturing precision

If adaptor dimers are removed by purification, then sequencing accuracy improves, but the process requires additional time and reagents

Engineering Contradiction:
Improvesequencing accuracyVSAvoidpurification time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The invention converts the potential harm of adaptor dimers into a benefit by using the presence of unreacted adaptors as a useful feature - the modified adaptors specifically bind to target DNA through their designed sequences, and any unreacted adaptors can be easily distinguished and removed by simple methods, thus achieving high sequencing accuracy without time-consuming purification

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method significantly enhances library yield and reduces adaptor dimer production, improving sequencing efficiency and library preparation from as little as 24 pg of single-stranded DNA.

Implementation Method 1

TACS ligation is a highly efficient single-stranded DNA ligation technique and is a unique reaction that ligates single-stranded DNAs to each other, which was developed based on the fact that the reaction efficiency is particularly high when the 3'-end of nucleotides on which the RNA ligase acts is RNA

Methodology Applied
Scientific EffectRNA ligase activity on ribonucleotide-tailed DNA: Enzyme

Implementation Method 2

a step of annealing a single-stranded adaptor sequence A2 to the adaptor sequence A1 portion contained in the adaptor-tagged single-stranded DNA and then elongating the 3'-end of the adaptor sequence A2 by DNA polymerase to produce adaptor-tagged double-stranded DNA

Methodology Applied
Scientific EffectDNA polymerase elongation: Enzyme

Implementation Method 3

a step of reacting topoisomerase with a double-stranded adaptor sequence B1, which has only one 5'-end phosphorylated and has a topoisomerase recognition sequence in the region containing the 3'-end complementary to said 5'-end, to produce a topoisomerase-linked double-stranded adaptor sequence B2 having topoisomerase conjugated to the 3'-end of said recognition sequence

Methodology Applied
Scientific EffectTopoisomerase conjugation: Enzyme

Implementation Method 4

a step of performing PCR using the double-stranded DNA having both ends tagged with adaptor sequences as a template to obtain a library containing a plurality of said double-stranded DNAs

Methodology Applied
Scientific EffectPCR amplification: Enzyme

Data Source

PatentEP4596711A1DNA library preparation method
Publication Date: 2025.08.06 KYUSHU UNIV
  • EP4596711A1 patent drawingFigure 1A~1D
  • EP4596711A1 patent drawingFigure 2A~2B
  • EP4596711A1 patent drawingFigure 3A~3C

AI summary

The present invention relates to a method for preparing a double-stranded DNA library from single-stranded DNA fragments and provides a highly efficient library preparation method, etc., that generates or contains few adapter dimers. The present invention is a method for preparing a double-stranded DNA library from single-stranded DNA fragments that includes the specific steps (i) to (v).