Solid Oxide Fuel Cell Reinforced Electrolyte Membrane

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Solution Overview

Problem

Solid oxide fuel cells require high operating temperatures and utilize fragile submicron electrolyte membranes that are prone to rupture under pressure, vibration, or thermal stress, limiting their operational stability.

Innovation Solution

The implementation of a reinforced membrane-electrode assembly in solid oxide fuel cells, where a gel is used to provide mechanical stabilization, acting as a structural support while maintaining gas permeability, often using conductive gels like carbon aerogels to support the electrolyte membrane between electrode layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If submicron electrolyte membranes are used to decrease operating temperature, then energy efficiency is improved, but mechanical strength deteriorates causing easy rupture under pressure, vibration or thermal stress

Engineering Contradiction:
Improveoperating temperatureVSAvoidmechanical strength
Core Design Contradiction:
TemperatureVSStrength

Solution Approach 1:

The patent applies composite materials by combining the submicron electrolyte membrane with a porous support layer to create a composite structure. The support layer provides mechanical strength while the membrane maintains its ion-conducting function, resolving the contradiction between low operating temperature requirement and mechanical strength deficiency.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent uses porous materials for the support layer, which allows gas permeability while providing mechanical reinforcement. The porous structure enables the membrane to maintain its functionality while the supporting matrix prevents rupture under stress, addressing both the temperature reduction goal and the strength weakness.

Inventive Principle:
Principle #31Porous materials

2Temperature

If submicron electrolyte membranes are used to decrease operating temperature, then energy efficiency is improved, but reliability deteriorates due to susceptibility to pressure, vibration or thermal stress

Engineering Contradiction:
Improveoperating temperatureVSAvoidoperational stability
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

By creating a composite structure where the fragile membrane is integrated with a robust porous support, the system achieves both low operating temperature and high reliability. The support layer acts as a protective framework that prevents membrane rupture while maintaining operational stability under various stress conditions.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The porous support layer serves as an intermediary between the fragile membrane and the external environment (pressure, vibration, thermal stress). It mediates the mechanical stresses, protecting the membrane from direct exposure to damaging forces while allowing the membrane to function at reduced temperatures with improved reliability.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Temperature

If the electrolyte membrane is made thinner to reduce operating temperature, then energy efficiency is improved, but ease of manufacture deteriorates due to handling difficulty

Engineering Contradiction:
Improveoperating temperatureVSAvoidhandling ease
Core Design Contradiction:
TemperatureVSEase of manufacture

Solution Approach 1:

The patent merges the thin membrane with the porous support layer into an integrated composite structure. This combination makes the otherwise fragile thin membrane easier to handle during manufacturing, as the support layer provides mechanical robustness while the membrane maintains its temperature-reducing functionality.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

By forming a composite material system, the patent improves ease of manufacture. The composite structure is easier to handle, process, and assemble than the thin membrane alone, while achieving the desired low operating temperature through the membrane's reduced thickness.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The reinforced membrane-electrode assembly enhances the mechanical stability and operational robustness of solid oxide fuel cells, allowing for lower operating temperatures and improved durability, enabling the cells to withstand mechanical stress and maintain efficient gas flow and reactant concentration.

Implementation Method 1

a gel is used to provide mechanical stabilization, acting as a structural support while maintaining gas permeability

Methodology Applied
Scientific EffectPorosity: Porosity

Implementation Method 2

often using conductive gels like carbon aerogels to support the electrolyte membrane between electrode layers

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Data Source

PatentUS9620803B2Solid oxide fuel cell with reinforced electrolyte membrane
Publication Date: 2017.04.11 PRESIDENT & FELLOWS OF HARVARD COLLEGE
  • US9620803B2 patent drawing
  • US9620803B2 patent drawing
  • US9620803B2 patent drawing

AI summary

A solid oxide fuel cell has a reinforced membrane-electrode assembly. The solid oxide fuel cell includes a first electrode layer, a second electrode layer, and an electrolyte membrane disposed between the first and second electrode layers. The solid oxide fuel cell further includes a gas-permeable structure adjacent to one or both of the electrode layers, for mechanical stabilization.