Solar Cell Eutectic Contact Layer for Low-Resistance Textured Emitters

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Solution Overview

Problem

Conventional solar cells face poor photoelectric conversion efficiency due to optical and electrical losses, primarily attributed to reflective losses, shadowing, non-absorptive losses, and high contact resistances between metal and semiconductor surfaces.

Innovation Solution

A solar cell design featuring a substrate with a textured emitter structure, passivation layers, and conductive eutectic layers composed of differently shaped conductive particles, which reduce contact resistances and enhance the contact area, thereby improving electrical efficiency and optical absorption.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional metal contact structures are used on the emitter surface, then the device complexity is low and manufacturing is simple, but the contact resistance is high and electrical losses increase

Engineering Contradiction:
Improvecontact resistanceVSAvoidcontact structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent uses a composite conductive eutectic layer comprising multiple types of conductive particles (first conductive particles with branched/linear shapes and second conductive particles with different shapes) embedded in a glass matrix. This composite structure reduces contact resistance between the metal electrode and semiconductor emitter while managing the complexity through a controlled particle ratio (20%-80%) and standardized manufacturing process.

Inventive Principle:
Principle #40Composite materials

2Reliability

If the contact area between metal and semiconductor is increased, then the contact resistance decreases, but the shadowing losses increase and optical absorption decreases

Engineering Contradiction:
Improvecontact resistanceVSAvoidoptical absorption
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent applies local quality by using conductive particles with specific branched and linear shapes that concentrate conductivity at contact points while maintaining optical transparency in non-contact areas. The textured structure on the emitter surface further enhances this by creating localized contact zones that minimize shadowing while maximizing electrical contact.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The conductive particles feature curved branched and linear shapes rather than flat configurations. This curvature allows the particles to conform to the textured emitter surface, increasing contact area through geometric adaptation while the three-dimensional structure minimizes the projected shadow area, thus reducing optical losses.

Inventive Principle:
Principle #14Spheroidality (Curvature)

3Reliability

If conductive particles are placed close to the emitter surface, then the contact resistance decreases, but the corrosion of the textured structure increases

Engineering Contradiction:
Improvecontact resistanceVSAvoidcorrosion
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The glass matrix acts as an intermediary between the conductive particles and the semiconductor emitter. It provides a protective barrier that prevents direct corrosive interaction between the conductive particles and the textured structure, while still allowing electrical contact to occur. The eutectic composition of the glass matrix is specifically designed to reduce corrosion at the interface.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Reliability

If uniform conductive particles are used in the eutectic layer, then the manufacturing precision is high and process control is simple, but the contact area and electrical conductivity are insufficient

Engineering Contradiction:
Improveelectrical conductivityVSAvoidparticle distribution control
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent changes the parameter of particle shape diversity by incorporating both branched and linear shaped first conductive particles along with second conductive particles of different shapes. This parameter change increases the contact area and electrical conductivity. The manufacturing precision is maintained through controlling the ratio of first to second conductive particles within 20%-80% and using standardized screen printing and energy injection processes.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The design significantly reduces electrical losses, increases open-circuit voltage, and enhances photoelectric conversion efficiency by increasing the contact area and distance between conductive particles and the PN junction, while preventing excessive corrosion and maintaining optical performance.

Implementation Method 1

conductive eutectic layers, where each of the conductive eutectic layers is formed between a respective first electrode of the first electrodes and the emitter and includes first conductive particles and second conductive particles

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 2

Optical losses include reflective losses on a front surface of the cell

Methodology Applied
Scientific EffectLight absorption: Absorption (EM radiation)

Implementation Method 3

Optical losses include reflective losses on a front surface of the cell

Methodology Applied
Scientific EffectReflection: Reflection

Implementation Method 4

a passivation structure formed on the textured structure of the emitter

Methodology Applied
Scientific EffectPassivation:

Implementation Method 5

solar cells are being used more and more widely as a new energy alternative, which convert light energy from the sun into electrical energy. The solar cells utilize the photovoltaic principle to generate carriers

Methodology Applied
Scientific EffectPhotovoltaic effect: Photovoltaic Effect

Data Source

PatentUS12166138B1Solar cell and photovoltaic module
Publication Date: 2024.12.10 JINKO SOLAR CO LTD
  • US12166138B1 patent drawing
  • US12166138B1 patent drawing
  • US12166138B1 patent drawing

AI summary

A solar cell is provided, including a substrate having a first surface and a second surface opposite to each other, an emitter formed on the first surface of the substrate and including a textured structure on a side away from the first surface, a passivation structure formed on the textured structure, first electrodes penetrating the passivation structure and in electrical contact with the textured structure of the emitter, and conductive eutectic layers each formed between a respective first electrode and the emitter and including first conductive particles and second conductive particles. Each of the first conductive particles has a shape different from a shape of any of the second conductive particles. The first conductive particles and the second conductive particles have a first number, the first conductive particles have a second number, and a ratio of the second number to the first number in a range of 20% to 80%.