Lead-Free Solder Alloy Electro-Migration Suppression

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Solution Overview

Problem

Conventional lead-free solder alloys fail to sufficiently suppress electro-migration in solder joint portions, particularly in miniaturized components, leading to void formation and disconnection due to high current density.

Innovation Solution

A lead-free solder alloy comprising Sb in the range of 3.0% to 10% by mass, with Sn as the main component, and optionally including Ag, Cu, Ni, Co, and Ge, which maintains appropriate melting temperatures and flowability while effectively reducing electro-migration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional lead-free solder alloys are used, then the solder joint can be formed, but electro-migration occurs leading to void formation and disconnection in miniaturized components

Engineering Contradiction:
Improveelectro-migration suppressionVSAvoidvoid formation and disconnection
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention changes the compositional parameters of the solder alloy by specifying precise ranges for Sn (90-99.5 mass%), Sb (0.5-10 mass%), and Cu (0-5 mass%). This parameter optimization resolves the contradiction by achieving electro-migration suppression while maintaining solder joint integrity, directly addressing the void formation and disconnection problems in miniaturized components

Inventive Principle:
Principle #35Parameter changes

2Volume of moving object

If the solder joint portion is miniaturized, then component size is reduced, but electro-migration increases causing reliability issues

Engineering Contradiction:
Improvesolder joint sizeVSAvoidelectro-migration resistance
Core Design Contradiction:
Volume of moving objectVSReliability

Solution Approach 1:

The invention optimizes the compositional parameters of the solder alloy with specific ranges for Sn, Sb, and Cu to address electro-migration in miniaturized solder joints. The controlled composition maintains appropriate melting characteristics and flowability while providing electro-migration suppression, enabling reliable connections in fine solder joints without requiring changes to the miniaturization trend

Inventive Principle:
Principle #35Parameter changes

3Reliability

If Ag or Cu is added to suppress electro-migration, then electro-migration resistance improves, but melting temperature control becomes difficult

Engineering Contradiction:
Improveelectro-migration suppressionVSAvoidmelting temperature
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The invention carefully controls the compositional parameters with Sn at 90-99.5 mass%, Sb at 0.5-10 mass%, and Cu at 0-5 mass% to achieve both electro-migration suppression and appropriate melting temperature. This balanced composition resolves the contradiction by preventing excessive melting temperature while maintaining electro-migration resistance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite solder alloy system combining Sn, Sb, and Cu in optimized proportions. This composite material approach resolves the contradiction by leveraging the complementary properties of each element: Sn provides base solder characteristics, Sb enhances electro-migration resistance, and Cu improves strength while controlling melting behavior

Inventive Principle:
Principle #40Composite materials

Data Source

PatentUS9764430B2Lead-free solder alloy, solder material and joined structure
Publication Date: 2017.09.19 KOKI COMPANY LTD
  • US9764430B2 patent drawing
  • US9764430B2 patent drawing

AI summary

Provided are a lead-free solder alloy which consists of Sb in an amount of more than 3.0% but 10% or less by mass, and the balance including Sn, and others.