Solder Paste Flux Composition for Wetting and Void Reduction

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Solution Overview

Problem

Existing soldering fluxes face challenges in achieving stable wet spreadability and reducing void generation, particularly due to variations in heating history and the limited effectiveness of organic acids and halogens in improving wettability and void reduction.

Innovation Solution

A flux containing a (carboxyalkyl) isocyanurate adduct, preferably combined with rosin and acrylic resin, which enhances wet spreadability and reduces void formation by removing oxides that cause non-wetting during soldering in a reflow furnace.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional fluxes with organic acids, amines, and halogens are used to improve activity, then wettability is enhanced, but void generation is not sufficiently reduced

Engineering Contradiction:
ImprovewettabilityVSAvoidvoid generation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the flux by incorporating specific compounds (carboxylic acid with 12-24 carbon atoms, sulfur compound, and phosphorus compound) in optimized proportions. This parameter change resolves the contradiction by achieving both improved wettability and reduced void generation through the synergistic effect of these specific chemical components.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite flux formulation by combining multiple active ingredients (carboxylic acid, sulfur compound, phosphorus compound) with resin and solvent. This composite approach allows the flux to simultaneously achieve enhanced wettability from the carboxylic acid and reduced void generation from the sulfur and phosphorus compounds, resolving the technical contradiction.

Inventive Principle:
Principle #40Composite materials

2Reliability

If heating history varies during soldering, then soldering results become unstable, but consistent finishing quality is required

Engineering Contradiction:
Improvesoldering consistencyVSAvoidsensitivity to heating history
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent incorporates sulfur compounds and phosphorus compounds in the flux formulation that act as cushioning agents against variations in heating history. These compounds provide a buffer effect that stabilizes the soldering process, ensuring consistent finishing quality regardless of heating variations through their controlled chemical reactions during the soldering process.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Solution Approach 2:

The patent optimizes the concentration parameters of multiple flux components to create a formulation that is less sensitive to heating history variations. By carefully balancing the proportions of carboxylic acid, sulfur compound, phosphorus compound, and resin, the flux achieves stable performance across different heating conditions.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The flux improves solder wettability and reduces voids, leading to better temperature cycle reliability and consistent soldering performance regardless of heating history.

Implementation Method 1

a flux used for soldering has an effect of chemically removing metal oxides present on surfaces of solder and metal

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 2

enabling movement of metallic elements at the boundary between the two surfaces

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 3

the substrate is heated in a heating furnace called a reflow furnace to melt the solder

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 4

intermetallic compounds may be formed between the surfaces of the solder and the metal which is a joining object by performing soldering using the flux, whereby firm joining is obtained

Methodology Applied
Scientific EffectIntermetallic compound formation: Chemical Bonding

Data Source

PatentUS11833620B2Flux and solder paste
Publication Date: 2023.12.05 SENJU METAL IND CO LTD
  • US11833620B2 patent drawing
  • US11833620B2 patent drawing
  • US11833620B2 patent drawing

AI summary

Provided are flux in which solder wettability is improved, and a solder paste in which the flux is used. The flux contains 0.5-20.0 wt % of a (carboxyalkyl)isocyanurate adduct, and 5.0-45.0 wt % of a rosin, and furthermore contains a solvent. The (carboxyalkyl)isocyanurate adduct is a mono(carboxyalkyl)isocyanurate adduct, a bis(carboxyalkyl)isocyanurate adduct, a tris(carboxyalkyl)isocyanurate adduct, or a combination of two or more of these.