Substrate Processing Film Thickness Control for High Aspect Ratio Etching

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Solution Overview

Problem

The increasing aspect ratio of patterns in semiconductor manufacturing, particularly in 3D NAND structures, poses challenges in achieving high accuracy and uniformity in etching and film formation, leading to shape abnormalities such as bowing and tapering, which existing methods struggle to correct effectively.

Innovation Solution

A substrate processing method involving the formation of a film with varying thickness along the film thickness direction on the side wall of high aspect ratio openings, using techniques like sub-conformal ALD, followed by trimming to correct shape abnormalities, allowing for precise control of opening dimensions and preventing the closure of openings during etching.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If etching and film formation are repeatedly performed to suppress lateral etching, then etching accuracy is improved, but manufacturing complexity increases

Engineering Contradiction:
Improveetching accuracyVSAvoidmanufacturing complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

A film is formed in advance on the side wall of the opening before the etching process. This preliminary film formation creates a protective layer that prevents lateral etching, eliminating the need for repeated etching and film formation cycles. The film is formed once, then the etching process can proceed without causing lateral erosion.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The film formed on the side wall acts as an intermediary protective layer between the etching environment and the opening structure. This intermediate film prevents direct contact between the etching agents and the opening walls, thereby suppressing lateral etching while allowing the etching process to continue.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of manufacture

If a uniform thickness film is formed on the side wall, then film formation simplicity is maintained, but shape abnormalities such as bowing and tapering occur

Engineering Contradiction:
Improvefilm formation simplicityVSAvoidshape abnormalities
Core Design Contradiction:
Ease of manufactureVSShape

Solution Approach 1:

The film thickness is made non-uniform, with different thicknesses at different positions along the side wall. Specifically, the film is thicker at the upper portion and thinner at the lower portion of the opening. This local variation in film thickness compensates for shape abnormalities by providing greater support where needed, thereby correcting bowing and tapering effects.

Inventive Principle:
Principle #3Local quality

3Quantity of substance

If the opening aspect ratio is increased for 3D NAND structures, then integration density is improved, but etching and film formation uniformity deteriorates

Engineering Contradiction:
Improveintegration densityVSAvoidetching and film formation uniformity
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The film thickness is varied locally along the side wall, being thicker at the upper portion and thinner at the lower portion. This local quality variation compensates for the difficulties of forming uniform films in high aspect ratio openings, ensuring adequate coverage and protection where most needed while maintaining process feasibility.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The film formation parameters are changed to create a non-uniform thickness profile. By controlling deposition conditions, the film is formed with varying thickness along the side wall, which improves uniformity of the overall structure despite the high aspect ratio of the opening.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method effectively corrects shape abnormalities in high aspect ratio patterns, ensures uniformity of opening dimensions, and maintains high etching selectivity, thereby improving the accuracy and reliability of semiconductor manufacturing processes.

Implementation Method 1

forming a film having a thickness that differs along the film thickness direction of the mask, on a side wall of the opening

Methodology Applied
Scientific EffectSub-conformal ALD: Chemical Vapour Deposition

Data Source

PatentUS11728166B2Substrate processing method and substrate processing apparatus
Publication Date: 2023.08.15 TOKYO ELECTRON LTD
  • US11728166B2 patent drawing
  • US11728166B2 patent drawing
  • US11728166B2 patent drawing

AI summary

Provided is a method of processing a substrate including an etching target film and a mask having an opening formed on the etching target film. The method includes a) providing the substrate on a stage in a chamber and b) forming a film having a thickness that differs along a film thickness direction of the mask, on a side wall of the opening.