Thin Film Transistor Grain Boundary Control via Metal Catalyst

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Solution Overview

Problem

Existing thin film transistor and organic light emitting diode display technologies face challenges in controlling metal silicide formation and grain boundary orientation, leading to suboptimal semiconductor layer characteristics and performance.

Innovation Solution

A method involving a protection layer pattern on an amorphous silicon layer, using a metal catalyst to crystallize the layer and control the formation of low and high angle grain boundaries, ensuring the channel region has only low angle grain boundaries aligned with current flow, while high angle grain boundaries are positioned outside, thereby improving semiconductor layer quality.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a metal catalyst is used to crystallize the amorphous silicon layer, then the polysilicon layer can be formed with controlled grain boundaries, but metal silicide may form and contaminate the channel region, degrading device performance

Engineering Contradiction:
Improvegrain boundary controlVSAvoidmetal silicide contamination
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent divides the substrate into different regions with distinct functions: a first region for forming metal silicide as crystal seeds, a second region (channel region) protected from metal silicide formation, and a third region for high angle grain boundary formation. This spatial segmentation allows controlled grain boundary orientation while preventing metal contamination in the channel region through selective area treatment.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the semiconductor layer are given different local characteristics: the channel region is engineered to have only low angle grain boundaries extending in the current flow direction for optimal electrical properties, while other regions can contain high angle grain boundaries or metal silicide. This local differentiation optimizes performance in critical areas without compromising overall manufacturability.

Inventive Principle:
Principle #3Local quality

2Productivity

If high angle grain boundaries are present in the channel region, then crystal growth can be achieved, but device characteristics deteriorate due to increased leakage current and reduced mobility

Engineering Contradiction:
Improvecrystal growth efficiencyVSAvoiddevice characteristics
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies different grain boundary characteristics to different regions: low angle grain boundaries are formed in the channel region to maintain high carrier mobility and low leakage current, while high angle grain boundaries are intentionally formed in non-channel regions where they do not affect device performance. This allows efficient crystal growth overall while protecting critical areas.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The substrate is segmented into regions where crystal growth conditions are optimized for productivity in non-channel areas, while channel regions are protected to maintain reliability. The metal catalyst distribution and annealing process are designed to produce this segmented grain boundary structure.

Inventive Principle:
Principle #1Segmentation

3Ease of manufacture

If conventional crystallization methods are used, then manufacturing process is simpler, but expensive laser annealing or metal contamination is required to achieve acceptable grain boundary control

Engineering Contradiction:
Improveprocess simplicityVSAvoidgrain boundary orientation control
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent uses a segmented metal catalyst layer deposited at different locations and concentrations to control crystal growth. By placing metal catalyst in specific patterns (higher concentration at edges, lower in center), the process achieves precise grain boundary orientation control through conventional annealing without requiring expensive laser equipment or complex additional processing steps.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent controls grain boundary characteristics by changing parameters of the metal catalyst layer (concentration, distribution pattern, thickness) and annealing conditions. This allows precise control of grain boundary orientation and type through parameter optimization rather than complex process equipment, maintaining ease of manufacture while achieving high manufacturing precision.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the characteristics of the thin film transistor and organic light emitting diode display devices by reducing leakage current and improving overall performance without the need for expensive laser annealing or metal contamination.

Implementation Method 1

crystallizing the amorphous silicon layer to form a preliminary polysilicon layer

Methodology Applied
Scientific EffectSolid-phase crystallization: Crystallisation

Implementation Method 2

crystallizing the amorphous silicon layer to form a preliminary polysilicon layer using the metal silicide as a seed

Methodology Applied
Scientific EffectEpitaxial growth: Epitaxy

Data Source

PatentUS8384087B2Thin film transistor, organic light emitting diode display device having the same, and method of fabricating the same
Publication Date: 2013.02.26 SAMSUNG DISPLAY CO LTD
  • US8384087B2 patent drawing
  • US8384087B2 patent drawing
  • US8384087B2 patent drawing

AI summary

A thin film transistor includes a substrate, a buffer layer on the substrate, a semiconductor layer including source/drain regions and a channel region on the buffer layer, a gate insulating layer corresponding to the channel region, a gate electrode corresponding to the channel region, and source/drain electrodes electrically connected to the semiconductor layer. A polysilicon layer of the channel region may include only a low angle grain boundary, and a high angle grain boundary may be disposed in a region of the semiconductor layer that is apart from the channel region.