Time-Modulation Plasma Mode for Substrate Processing

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Solution Overview

Problem

High-density plasma processing in semiconductor manufacturing causes plasma-induced damage (PID) due to non-uniform deposition and photo-conduction effects, which degrade the quality of insulating films and gate oxide layers, especially in structures with large aspect ratios.

Innovation Solution

Implementing a time-modulation plasma mode by periodically turning on and off the plasma power and process gas supply in a high-density plasma chemical vapor deposition (HDP-CVD) apparatus to reduce plasma-induced damage, using both upper and lower RF power and high-speed gas puffing valves to control plasma conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If high-density plasma is used for processing, then gap-filling capacity is improved, but plasma-induced damage occurs to the substrate

Engineering Contradiction:
Improvegap-filling capacityVSAvoidplasma-induced damage
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent applies periodic action by implementing time-modulation plasma mode where plasma is periodically turned on and off during processing. This periodic operation allows the substrate to recover between plasma exposure cycles, reducing cumulative plasma-induced damage while maintaining effective gap-filling capability through repeated deposition cycles.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent implements dynamics by making plasma power and gas flow dynamic rather than static. The RF power to plasma-generating electrodes is modulated in time, and gas flow rates are dynamically adjusted during processing. This dynamic control enables optimization of both gap-filling performance and reduction of plasma damage by adapting conditions throughout the processing cycle.

Inventive Principle:
Principle #15Dynamics

2Productivity

If plasma is continuously applied to deposit material layer, then deposition efficiency is improved, but plasma-induced damage accumulates in the substrate

Engineering Contradiction:
Improvedeposition efficiencyVSAvoidplasma-induced damage
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent applies periodic action by implementing time-modulation plasma mode where plasma is periodically turned on and off during processing. This periodic operation allows the substrate to recover between plasma exposure cycles, reducing cumulative plasma-induced damage while maintaining effective gap-filling capability through repeated deposition cycles.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent maintains continuity of useful action by ensuring that material deposition continues effectively through repeated plasma cycles. The periodic plasma application is structured so that deposition occurs during plasma-on periods while recovery occurs during plasma-off periods, maintaining overall productive progress without continuous harmful exposure.

Inventive Principle:
Principle #20Continuity of useful action

3Quantity of substance

If high RF power is supplied to induce plasma, then plasma density is improved for better deposition, but substrate damage increases

Engineering Contradiction:
Improveplasma densityVSAvoidsubstrate damage
Core Design Contradiction:
Quantity of substanceVSObject-affected harmful factors

Solution Approach 1:

The patent applies periodic action by implementing time-modulation plasma mode where plasma is periodically turned on and off during processing. This periodic operation allows the substrate to recover between plasma exposure cycles, reducing cumulative plasma-induced damage while maintaining effective gap-filling capability through repeated deposition cycles.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent implements dynamics by making plasma power and gas flow dynamic rather than static. The RF power to plasma-generating electrodes is modulated in time, and gas flow rates are dynamically adjusted during processing. This dynamic control enables optimization of both gap-filling performance and reduction of plasma damage by adapting conditions throughout the processing cycle.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The time-modulation plasma mode effectively reduces plasma-induced damage by controlling plasma application and pressure, improving the uniformity and quality of deposited material layers and preventing degradation of insulating films and gate oxide layers.

Implementation Method 1

processing the substrate with a first plasma mode and then with a second plasma mode, wherein at least one of the first plasma mode and the second plasma mode is a time-modulation mode in which a plasma induced in the chamber is periodically turned on and off

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

The power supply for inducing the plasma can be an upper radio-frequency (RF) power supplied to upper electrodes disposed on the substrate

Methodology Applied
Scientific EffectRadio-frequency power induction: Electromagnetic Induction

Implementation Method 3

Introduction of the at least one process gas can be controlled by periodically turning on and off at least one high-speed gas puffing valve attached to the chamber

Methodology Applied
Scientific EffectGas puffing:

Implementation Method 4

The chamber can occupy at least a portion of a high-density plasma chemical vapor deposition (HDP-CVD) apparatus. The first processing of the substrate (with the first plasma mode) and/or the second processing of the substrate (with the second plasma mode) can include depositing a material layer on the substrate

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Data Source

PatentUS8277906B2Method of processing a substrate
Publication Date: 2012.10.02 SAMSUNG ELECTRONICS CO LTD
  • US8277906B2 patent drawing
  • US8277906B2 patent drawing
  • US8277906B2 patent drawing

AI summary

A method of processing a substrate using plasma includes loading a substrate into a chamber, processing the substrate with a first plasma mode and then processing the substrate with a second plasma mode, wherein at least one of the first plasma mode and the second plasma mode is a time-modulation mode in which a plasma induced in the chamber is periodically turned on and off to reduce plasma-induced damage in the substrate.