TiO2 Scattering Layer for OLED Light Extraction

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Solution Overview

Problem

Current OLED devices suffer from low light extraction efficiency due to total internal reflection and waveguide effects caused by differences in refractive indices between the organic light-emitting layer and the glass substrate, resulting in only about 20% of generated light being emitted, while 80% is lost.

Innovation Solution

A light extraction substrate with a scattering layer formed from TiO2, incorporating irregular-shaped voids and a planarization layer from organic/inorganic hybrimer, which creates a multi-refractive-index core-shell structure to scatter light and improve extraction efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a planar glass substrate is used, then manufacturing is simple and cost is low, but light extraction efficiency is poor due to total internal reflection and waveguide effects

Engineering Contradiction:
Improvesubstrate manufacturing simplicityVSAvoidlight extraction efficiency
Core Design Contradiction:
Ease of manufactureVSLoss of energy

Solution Approach 1:

The patent applies porous materials by forming a scattering layer with controlled porosity on the glass substrate. The porous structure creates air-substrate interfaces that scatter light and reduce total internal reflection, improving light extraction efficiency while maintaining the simplicity of using a glass substrate base

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent creates a composite structure by combining the glass substrate with a scattering layer formed from sol-gel processed materials. This composite approach integrates the optical scattering function into the substrate structure, enhancing light extraction while maintaining manufacturing feasibility

Inventive Principle:
Principle #40Composite materials

2Loss of energy

If the scattering layer porosity is increased to improve light scattering, then light extraction efficiency improves, but non-radiative energy transfer increases reducing OLED reliability

Engineering Contradiction:
Improvelight extraction efficiencyVSAvoidOLED device reliability
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The patent applies local quality by creating specific porosity distributions and controlling the local optical properties of the scattering layer. The sol-gel process allows precise control over pore size, shape, and distribution, optimizing light scattering while minimizing areas that could cause non-radiative energy transfer

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent utilizes parameter changes by controlling the sol-gel processing parameters (precursor composition, drying conditions, firing temperature) to achieve optimal porosity levels. This enables tuning of the scattering layer properties to balance light extraction enhancement with prevention of non-radiative energy transfer

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly enhances light extraction efficiency, contributing to the reliability and performance of OLED devices by increasing the amount of emitted light and reducing manufacturing costs through optimized refractive index management.

Implementation Method 1

a scattering layer formed from TiO2, incorporating irregular-shaped voids and a planarization layer from organic/inorganic hybrimer, which creates a multi-refractive-index core-shell structure to scatter light

Methodology Applied
Scientific EffectLight scattering: Scattering

Implementation Method 2

the efficiency with which light generated by the light-emitting layer is extracted... depends on the refractive indices of OLED layers... total internal reflection originating from the difference in refractive indices between the glass substrate and ambient air

Methodology Applied
Scientific EffectRefraction: Refraction

Data Source

PatentEP3249712B1Light extraction substrate for organic light emitting device, and organic light emitting device comprising same
Publication Date: 2022.12.21 SAMSUNG CORNING PRECISION MATERIALS CO LTD
  • EP3249712B1 patent drawingFigure 1
  • EP3249712B1 patent drawingFigure 2
  • EP3249712B1 patent drawingFigure 3~4

AI summary

The present invention provides a light extraction substrate for an organic light emitting device, comprising: a base substrate; a scattering layer formed on the base substrate and made of TiO2; a plurality of first light scatterers formed inside the scattering layer and having a porous form; and a flat layer formed on the scattering layer, wherein the scattering layer is internally permeated by a part of the materials constituting the flat layer.