Transparent MEMS Resonators via Ultrafast Laser Wet Etching

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Solution Overview

Problem

Existing methods for fabricating MEMS resonators, such as plasma etching, face limitations including complex processes, limited aspect ratios, and thermal stress issues due to heat generation and mismatched thermal characteristics with other materials.

Innovation Solution

The use of laser micromachining, specifically ultrafast-laser-induced modification followed by wet etching, to fabricate MEMS resonators from bulk optically transparent materials like fused silica, enabling the creation of resonators with ultra-high aspect ratios and improved thermal and mechanical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If plasma etching is used to fabricate MEMS resonators, then anisotropic etching with controlled etch profile is achieved, but device complexity increases due to multiple process steps and thermal stress issues arise from heat generation

Engineering Contradiction:
Improveetch profile controlVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The fabrication process is segmented into distinct functional modules: laser inscription unit, wet etching unit, and release unit. Each module performs a specific function independently, simplifying the overall process control while maintaining precision. The laser inscription creates precise 3D patterns, wet etching selectively removes material along predefined paths, and release separates the resonator from the substrate.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent replaces the plasma-based mechanical etching system with a laser-assisted wet chemical etching system. The ultrafast laser inscribes the resonator structure by modifying the material properties locally, and subsequent wet etching follows the inscribed paths. This substitution eliminates the complex plasma generation and control systems while achieving comparable or superior etching precision with reduced thermal stress.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Manufacturing precision

If plasma etching is used to achieve high aspect ratios, then etch rate control is improved, but the maximum achievable aspect ratio is limited to below 10:1

Engineering Contradiction:
Improveetch rate controllabilityVSAvoidaspect ratio
Core Design Contradiction:
Manufacturing precisionVSLength of stationary object

Solution Approach 1:

The ultrafast laser performs preliminary action by inscribing the resonator structure and creating chemically modified pathways before the wet etching process. This pre-defined path guidance allows the wet etchant to follow precise trajectories deep into the substrate, achieving aspect ratios exceeding 10:1 without losing etch rate control. The laser inscription acts as a template that directs the subsequent chemical etching process.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the fundamental parameters of the etching process by transitioning from plasma-phase to liquid-phase chemistry. Wet etching with appropriate chemical solutions provides different etching kinetics that are better suited for high aspect ratio structures. The laser-inscribed pathways modify the local chemical environment, enhancing etchant penetration depth and maintaining controlled etching rates throughout the entire etch depth, thereby achieving aspect ratios greater than 10:1.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If conventional laser micromachining is used on fused silica, then material processing is achieved, but surface damage occurs due to laser-induced cracks and material redeposition

Engineering Contradiction:
Improvematerial processabilityVSAvoidsurface damage
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The patent employs periodic pulsed laser action with carefully controlled duty cycles and pulse durations. The ultrafast laser delivers energy in short, intense pulses that allow the material to respond linearly and reversibly between pulses. This periodic delivery method prevents excessive heat accumulation and avoids the nonlinear optical effects that lead to cracking and redeposition. The间歇性 (intermittent) nature of the pulsing allows heat diffusion and stress relaxation between pulses.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent fundamentally changes the laser processing parameters by using ultrafast pulse durations (femtosecond to picosecond range) instead of continuous or long-pulse operation. This parameter change transforms the heating mechanism from thermal diffusion-dominated to localized nonlinear absorption. The ultrafast pulses deposit energy faster than heat can diffuse, creating highly localized modifications without significant thermal damage zones. This parameter transformation enables clean material processing without surface cracks or redeposition.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for the fabrication of MEMS resonators with high aspect ratios and low energy loss, enhancing their sensitivity and accuracy for applications in inertial sensing, time referencing, bio-sensing, and acoustic sensing, while avoiding thermal stress and surface damage issues.

Implementation Method 1

Femtosecond Laser-Induced Chemical Etching (FLICE) technology

Methodology Applied
Scientific EffectLaser-induced chemical etching: Laser Ablation

Implementation Method 2

The resonator structure may then be subsequently defined and released through selective wet etching of the laser-modified areas

Methodology Applied
Scientific EffectWet etching: Erosion

Data Source

PatentUS20250091861A1Laser micromachining of MEMS resonators from bulk optically transparent material
Publication Date: 2025.03.20 RGT UNIV OF CALIFORNIA
  • US20250091861A1 patent drawing
  • US20250091861A1 patent drawing
  • US20250091861A1 patent drawing

AI summary

Systems, processes and devices are provided for laser-based manufacturing of resonators and MEMS devices from bulk material including optically transparent material. Processes include digital marking of resonator structures in bulk material through non-linear interaction of ultrafast laser beam inscribing and material. The resonator structure may be defined and released through selective wet etching of the laser-modified areas, utilizing a combination of basic and acidic aqueous solutions. Processes can also include hydrofluoric thinning prior to wet etching to prevent laser surface damages. Systems and processes can pattern and fabricate resonator structures and concentricring structures. Embodiments provide miniaturized vibratory sensors from low loss material, such as fused silica and quartz, with an improved resolution and accuracy of measurements for inertial sensing, time referencing, bio-sensing and acoustic sensing.