Transparent Particle Electrode Assembly for Angle-Independent Light Harvesting

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Solution Overview

Problem

Conventional solar panels face inefficiencies due to varying incident angles and light intensities, particularly when fixedly mounted on roofs or windows, as they struggle to optimize energy harvesting across different sunlight conditions.

Innovation Solution

An electrode assembly featuring a non-close packed monolayer of transparent particles, integrated with electron transport and light-absorbing layers, enhances light-matter interaction by creating a photonic nano-structured heterojunction, allowing for efficient energy harvesting regardless of incident angle and light intensity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If automated solar panels are moved along tracks to follow the sun, then light harvesting efficiency is improved, but device complexity and cost increase

Engineering Contradiction:
Improvelight harvesting efficiencyVSAvoidmechanical tracking system
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent replaces the mechanical tracking system with a photonic nanostructured electrode assembly that passively optimizes light absorption. The nanoscale heterojunction structure with particles creates angle-independent light harvesting through optical effects rather than mechanical movement, eliminating the need for motors, tracks, and control systems while maintaining high productivity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention transitions from a planar electrode structure to a three-dimensional nanoscale heterojunction architecture. By creating vertical nanoscale interfaces between electron transport material, hole transport material, and particles, the system achieves enhanced light absorption in the third dimension without requiring mechanical complexity.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Device complexity

If solar panels are fixed at a non-optimal angle, then device complexity is reduced, but light harvesting efficiency deteriorates

Engineering Contradiction:
Improvefixed installation structureVSAvoidlight harvesting efficiency
Core Design Contradiction:
Device complexityVSProductivity

Solution Approach 1:

The patent changes the optical parameters of the electrode assembly through nanoscale structuring. The photonic nanostructured heterojunction with particles of specific sizes and arrangements modifies light interaction at the nanoscale, creating angle-independent absorption characteristics that maintain high efficiency regardless of the panel's macroscopic orientation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention applies localized nanoscale heterojunction structures at specific regions of the electrode assembly. The particles and material interfaces are strategically positioned to create local optical fields that enhance absorption throughout the device, allowing the entire panel to perform optimally at fixed angles without requiring global structural complexity.

Inventive Principle:
Principle #3Local quality

3Ease of manufacture

If close-packed monolayers of particles are used, then manufacturing simplicity is improved, but light-matter interaction efficiency deteriorates

Engineering Contradiction:
Improveparticle assembly processVSAvoidlight absorption efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The patent employs a non-close-packed monolayer configuration that creates controlled void spaces between particles. This porous-like structure at the particle arrangement level increases the effective interface area and allows broader angular acceptance of light, improving light-matter interaction while maintaining relatively simple manufacturing through self-assembly or deposition techniques.

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration increases light absorption and photogenerated charge production, improving solar energy harvesting efficiency and aesthetic appeal, while being suitable for various photovoltaic technologies, including thin-film and emerging solar cells.

Implementation Method 1

The light paths in the light absorber are enlarged with respect to a planar configuration, hence the electrode assembly, when implemented in a solar cell, is able to absorb light more efficiently

Methodology Applied
Scientific EffectLight absorption: Absorption (EM radiation)

Implementation Method 2

Photovoltaic technologies aim at getting as much energy from photovoltaic devices, like, for example, solar panels

Methodology Applied
Scientific EffectPhotovoltaic effect: Photovoltaic Effect

Data Source

PatentEP4231367A1Electrode assembly, process for manufacturing an electrode assembly, photovoltaic device, and use of a non-close packed monolayer of transparent particles in an electrode assembly
Publication Date: 2023.08.23 FRIEDRICH ALEXANDER UNIV ERLANGEN NUERNBERG

AI summary

An electrode assembly is provided, comprising (a) a first electrode (1), (b) a monolayer of particles (2), (c) an electron transport material (ETM) layer (3), (d) a light-absorbing layer (4), (e) a hole transport material (HTM) layer (5), and (f) a second electrode (6), wherein at least one of the first and the second electrode (1, 6) is transparent; wherein said monolayer of particles (2) is a non-close packed monolayer; wherein the monolayer of particles (2) is obtained by depositing a non-close packed monolayer of core-shell particles and subsequently removing the shell from said as-deposited non-close packed monolayer of core-shell particles; and wherein a minimum interparticle distance in the monolayer of particles (2) is equal to or greater than two times the thickness of the shell of said core-shell particles. Furthermore, a process for manufacturing the electrode assembly as well as photovoltaic device, comprising the electrode assembly and the use of a non-close packed monolayer of transparent particles in an electrode assembly are provided.