Trenched Bottom Electrode Molecular Spintronics Fabrication

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current methods for fabricating molecular spintronics devices face challenges in mass production due to difficulties in working with small molecules, achieving controlled experiments, and utilizing ferromagnetic electrodes, leading to issues with spin coherence and heat management, as well as the complexity of producing thin, uniform insulators for tunnel junctions.

Innovation Solution

The development of Trenched Bottom Electrode and Liftoff based Molecular Devices (TBELMDs) allows for the fabrication of molecular spintronics devices with smaller molecular channels and thicker insulators, enabling controlled charge and spin transport, using a method that includes creating trenches in electrodes, depositing insulators, and assembling molecules between metal electrodes to avoid heat-related issues and improve device stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional microfabrication tools like photolithography and sputtering are used, then mass production capability is improved, but difficulty in working with small molecules and achieving controlled experiments increases

Engineering Contradiction:
Improvemass production capabilityVSAvoiddifficulty in working with small molecules
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The device is segmented into distinct functional regions: source/drain electrodes, molecular channel region, and gate electrode region. This segmentation allows independent optimization of each component, enabling controlled experiments while maintaining mass production capability through standardized fabrication processes.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention transitions from planar 2D device architecture to a 3D structure with vertical stacking of source/drain electrodes, molecular channel, and gate electrode. This dimensional change enables better control over molecular positioning and improved electrical characteristics while facilitating scalable fabrication.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Reliability

If thin insulators are used for tunnel junctions, then spin coherence is improved, but manufacturing precision requirements increase

Engineering Contradiction:
Improvespin coherenceVSAvoidthin insulator uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent optimizes the insulator thickness parameter to a specific range (2-5 nm) that balances spin coherence requirements with manufacturing feasibility. This parameter change enables achievement of quantum tunneling effects while remaining compatible with conventional sputtering and atomic layer deposition techniques.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

An intermediary layer or buffer layer is introduced between the metal electrodes and insulator to improve adhesion and control the growth of the thin insulator layer. This intermediary enables more uniform thin insulator formation and reduces defects that would degrade spin coherence.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If ferromagnetic electrodes are used, then spin transport control is improved, but heat management difficulties increase

Engineering Contradiction:
Improvespin transport controlVSAvoidheat management
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The device structure provides different local thermal properties in different regions: the ferromagnetic source/drain electrodes provide spin polarization, while the gate electrode and substrate regions provide thermal sinking pathways. This local quality differentiation enables simultaneous spin transport control and heat management.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

Non-magnetic metal layers or buffer layers are introduced as intermediaries between the ferromagnetic electrodes and the substrate. These intermediary layers provide thermal conduction pathways while maintaining the spin-polarized electron transport through the ferromagnetic regions, thus separating the spin and heat management functions.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Length of moving object

If molecular channels are made smaller, then device miniaturization is improved, but difficulty in assembly and controlled experiments increases

Engineering Contradiction:
Improvemolecular channel sizeVSAvoidassembly difficulty
Core Design Contradiction:
Length of moving objectVSEase of manufacture

Solution Approach 1:

The source/drain electrodes and gate electrode are pre-fabricated with precise geometries and positions using conventional lithography before molecular assembly. This preliminary action establishes well-defined binding sites and electrical contacts, enabling controlled assembly of small molecular channels without requiring complex real-time alignment procedures.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

TBELMDs facilitate the production of molecular devices with improved spin coherence and reduced heat damage, enabling the creation of robust, scalable molecular spintronics devices with enhanced performance and longevity.

Implementation Method 1

depositing insulators

Methodology Applied
Scientific EffectElectrical insulation: Electrical Resistance

Data Source

PatentUS11621345B2Systems and methods of fabricating gate electrode on trenched bottom electrode based molecular spintronics device
Publication Date: 2023.04.04 TYAGI PAWAN
  • US11621345B2 patent drawing
  • US11621345B2 patent drawing
  • US11621345B2 patent drawing

AI summary

A system and method comprising the steps of: depositing a first electrode metal on an insulating substrate or layer; creating a trench component, in which said trench component comprises a section of said first electrode metal or both first electrode metal and insulating substrate or layer with a depth based on at least one of, a molecular device element, a trenched bottom electrode, and a liftoff molecular device (TBELMD) to be produced; insulating said first electrode metal from a predetermined material deposited in said trench component; and depositing a second electrode metal on said predetermined material deposited in said trench component.