Twin-Chamber Remote Plasma System for Deposition Stability

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Solution Overview

Problem

Conventional semiconductor processing chambers using a shared remote plasma system for both deposition and cleaning gases suffer from instability due to aluminum component reactions with fluorine-containing cleaning gases, leading to aluminum fluoride formation, erosion, and consumption of precursor gases, resulting in deposition rate instability and frequent component replacement.

Innovation Solution

A twin-chamber system with dedicated remote plasma systems for deposition and cleaning precursors, where each processing region has a first remote plasma system for deposition precursors and a shared second remote plasma system for cleaning precursors, strategically injecting cleaning radicals through a plasma distribution ring to prevent over-cleaning and AlF formation, and using an argon purge to prevent AlF residue transport.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a shared remote plasma system is used for both deposition and cleaning gases, then device complexity is reduced, but deposition rate stability deteriorates due to aluminum fluoride formation and precursor gas consumption

Engineering Contradiction:
Improveremote plasma system configurationVSAvoiddeposition rate stability
Core Design Contradiction:
Device complexityVSStability of the object's composition

Solution Approach 1:

The patent divides the remote plasma system into separate dedicated systems: one remote plasma system for deposition precursors and another for cleaning precursors. This segmentation prevents the formation of aluminum fluoride by eliminating the reaction between fluorine radicals and aluminum components, thereby maintaining stable deposition rates while managing device complexity through functional separation.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent extracts the cleaning plasma generation function from the deposition plasma system by introducing a dedicated cleaning remote plasma system. This extraction removes the harmful interaction between cleaning gases and aluminum components that causes deposition rate instability, while the separated systems can be optimized for their respective functions.

Inventive Principle:
Principle #2Taking out (Extraction)

2Reliability

If cleaning gases are flowed through aluminum components, then cleaning effectiveness is improved, but harmful factors increase due to aluminum fluoride formation and component erosion

Engineering Contradiction:
Improvecleaning effectivenessVSAvoidaluminum fluoride formation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent introduces an intermediary approach by using a dedicated cleaning remote plasma system that generates cleaning radicals in a separate environment. The cleaning precursors are activated in this dedicated system where aluminum fluoride formation is minimized, and the cleaned radicals are then introduced to the chamber for cleaning, thus maintaining cleaning effectiveness while reducing harmful byproduct formation.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates an inert environment for cleaning plasma generation by using a dedicated cleaning remote plasma system with minimal aluminum component exposure. This inert environment prevents the reaction between fluorine radicals and aluminum, eliminating aluminum fluoride formation while maintaining cleaning effectiveness through controlled radical generation and delivery.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

3Adaptability or versatility

If the same remote plasma system is used for both deposition and cleaning, then system versatility is improved, but component lifespan decreases due to erosion and residue buildup

Engineering Contradiction:
Improveremote plasma system versatilityVSAvoidcomponent lifespan
Core Design Contradiction:
Adaptability or versatilityVSDuration of action of stationary object

Solution Approach 1:

The patent segments the remote plasma system into dedicated deposition and cleaning systems, which extends component lifespan by preventing erosion and aluminum fluoride buildup in the deposition system. Each dedicated system is optimized for its specific function, reducing the degradation that would occur from alternating between deposition and cleaning modes in a shared system.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent extracts the cleaning function into a separate dedicated system, removing the source of erosion and residue buildup from the deposition remote plasma system. This extraction preserves the deposition system components from harmful reactions, significantly extending their operational lifespan while the cleaning system handles the harsh cleaning gas environment.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This design stabilizes deposition rates, reduces AlF formation and defects, and significantly extends the lifespan of remote plasma system components by preventing AlF residue buildup and erosion, achieving a stable deposition rate with reduced defect performance.

Implementation Method 1

plasma processes are often used for deposition or etching of various material layers

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

plasma enhanced chemical vapor deposition (PECVD) allows deposition processes to be performed at lower temperatures

Methodology Applied
Scientific EffectPlasma enhanced chemical vapor deposition: Plasma Enhanced Chemical Vapour Deposition

Implementation Method 3

the reaction of fluorine radicals with aluminum surfaces to form aluminum fluorides (i.e., one or more species of the genus of AlFX)

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 4

strategically injecting cleaning radicals through a plasma distribution ring

Methodology Applied
Scientific EffectGas flow: Convection

Implementation Method 5

using an argon purge to prevent AlF residue transport

Methodology Applied
Scientific EffectInert gas purge: Convection

Data Source

PatentUS10428426B2Method and apparatus to prevent deposition rate/thickness drift, reduce particle defects and increase remote plasma system lifetime
Publication Date: 2019.10.01 APPLIED MATERIALS INC
  • US10428426B2 patent drawing
  • US10428426B2 patent drawing
  • US10428426B2 patent drawing

AI summary

A method and apparatus for a deposition chamber is provided and includes a twin chamber that includes a first remote plasma system coupled and dedicated to a first processing region, a second remote plasma system coupled and dedicated to a second processing region, and a third remote plasma system shared by the first processing region and the second processing region.