Urea-Formaldehyde Polyester Binder Toughness Shelf Life

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Solution Overview

Problem

Urea-formaldehyde (UF) resin binder compositions face challenges with brittleness, increased process time and cost, pH reactivity issues, and reduced shelf life due to the use of polymer latex modifiers, which affect the strength and stability of nonwoven fiber mats.

Innovation Solution

A binder system comprising a water-dispersible polyester and a water-dispersible urea-formaldehyde resin, where the polyester is blended with UF resin to enhance toughness and strength, reducing the need for latex modifiers and improving the shelf life and processing efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If polymer latex is added to UF binder to improve toughness, then strength properties improve, but process time increases and cost increases

Engineering Contradiction:
ImprovetoughnessVSAvoidprocess time
Core Design Contradiction:
StrengthVSLoss of time

Solution Approach 1:

The patent extracts and removes the polymer latex component from the binder system, replacing it with a polyester-modified UF resin system. This eliminates the need for separate latex addition while maintaining toughness through the polyester modification of the UF resin itself, thereby reducing process time and complexity.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent merges the toughness-providing function into the UF resin base itself through polyester modification, rather than combining separate latex and UF resin components. This integration eliminates the need for additional latex addition steps and simplifies the binder system while maintaining improved toughness.

Inventive Principle:
Principle #5Merging (Combining)

2Strength

If polymer latex is added to UF binder to improve toughness, then strength properties improve, but manufacturing cost increases

Engineering Contradiction:
ImprovetoughnessVSAvoidmanufacturing cost
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent removes the expensive polymer latex component and replaces it with polyester-modified UF resin, which is more cost-effective. This extraction of the costly latex while maintaining toughness through alternative means directly reduces manufacturing cost.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent uses polyester modification of UF resin as a more economical alternative to expensive polymer latex. The polyester-modified UF resin provides the necessary toughness at a lower cost, making it a more economically viable binder system.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Strength

If latex is used as binder modifier, then toughness improves, but shelf life decreases due to pH and reactivity effects

Engineering Contradiction:
ImprovetoughnessVSAvoidshelf life
Core Design Contradiction:
StrengthVSDuration of action of stationary object

Solution Approach 1:

The patent extracts and eliminates the latex component that causes pH and reactivity issues, replacing it with polyester-modified UF resin. This removal of the problematic latex eliminates the shelf life degradation mechanisms while maintaining toughness through the polyester modification.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent converts the harmful effect of latex on shelf life into a beneficial polyester-modified UF resin system. The polyester modification provides the necessary toughness without the harmful pH and reactivity effects that plague latex-based systems, thereby extending shelf life.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Ease of manufacture

If standard non-latex modified UF resin is used, then manufacturing cost is lower, but shelf life is limited to about 30 days

Engineering Contradiction:
Improvemanufacturing costVSAvoidshelf life
Core Design Contradiction:
Ease of manufactureVSDuration of action of stationary object

Solution Approach 1:

The patent changes the chemical parameters of the UF resin by incorporating polyester modification, which alters the molecular structure and properties. This parameter change extends the shelf life from 30 days to over 6 months while maintaining the cost-effectiveness of the UF resin base system.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite binder system by combining UF resin with polyester modification. This composite approach leverages the cost-effectiveness of UF resin while adding the extended shelf life and improved toughness characteristics provided by the polyester component.

Inventive Principle:
Principle #40Composite materials

5Ease of operation

If latex is diluted with water, then application flexibility improves, but water dilution stability decreases causing precipitation

Engineering Contradiction:
Improveapplication flexibilityVSAvoidwater dilution stability
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The patent removes the latex component that is prone to precipitation upon dilution, replacing it with polyester-modified UF resin. This extraction eliminates the water dilution stability issues while maintaining application flexibility through the properties of the modified UF resin system.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The binder system provides improved wet and dry tensile properties, tear strength, and cure speed while maintaining lower raw material costs, and is supplied in a one-piece package with adequate foam control, extending the shelf life of UF resin binders beyond traditional 30 days.

Implementation Method 1

binder compositions comprising a blend of urea-formaldehyde ('UF') and water dispersible polyester

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 2

UF-binders are used in a number of products... when used as a binder, the UF-binders may be modified with polymer latex... acrylic copolymer latex, such as a self-cross linking acrylic copolymer

Methodology Applied
Scientific EffectCuring:

Data Source

PatentUS9708503B2Resin-polyester blend binder compositions, method of making same and articles made therefrom
Publication Date: 2017.07.18 BAKELITE UK HLDG LTD
  • US9708503B2 patent drawing
  • US9708503B2 patent drawing
  • US9708503B2 patent drawing

AI summary

An aqueous binder system including a mixture of urea-formaldehyde resin and water-dispersible polyester resin. A combination of the binder system applied to fiber insulation, a composite glass mat, glass/polyester mat, polyester mat, or substrate of a coated abrasive product. Fiber insulation, a composite glass mat, glass/polyester mat, polyester mat, or coated abrasive product with the binder system including urea-formaldehyde resin and water-dispersible polyester.