UHMWPE Microporous Membrane Dimensional Stability

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Solution Overview

Problem

Existing microporous membranes made from ultrahigh molecular weight polyethylene (UHMWPE) lack dimensional stability at elevated temperatures and have limited control over pore size distribution, which affects their physical properties and performance.

Innovation Solution

A method involving the extrusion of a mixture of UHMWPE, a particulate filler, and a processing plasticizer to form a microporous matrix, which is then stretched and calendered to improve dimensional stability and control pore size, with the filler distributed throughout the matrix and pores constituting 25-90% by volume.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If microporous membranes are made from UHMWPE using conventional methods, then porosity is achieved, but dimensional stability at elevated temperatures deteriorates

Engineering Contradiction:
Improvedimensional stabilityVSAvoidperformance consistency
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent combines UHMWPE with inert filler materials (such as silica, glass beads, or metal oxides) to create a composite microporous membrane. The filler particles provide thermal stability and structural support that prevents dimensional changes at elevated temperatures, while the UHMWPE matrix maintains the microporous structure for fluid passage. This composite approach resolves the contradiction by integrating materials with complementary properties.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies processing parameters including extrusion temperature, cooling rate, and pore-forming agent selection to optimize the microporous structure. By controlling the crystallization behavior and pore formation during processing, the membrane achieves both high porosity and dimensional stability. The processing conditions are tuned to create a stable microporous network that resists deformation at elevated temperatures.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If pore size distribution is not controlled during manufacturing, then production is simpler, but physical properties such as tensile strength and wet out time are compromised

Engineering Contradiction:
Improvepore size controlVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent uses pore-forming agents (such as salt particles, foam beads, or gas-generating compounds) as intermediaries to create the microporous structure. These temporary agents are distributed throughout the membrane matrix and are later removed by extraction or decomposition, leaving behind controlled pores. By adjusting the size, shape, and distribution of the pore-forming agents, precise pore size distribution is achieved without complex post-processing steps.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent incorporates pore-forming agents and filler materials into the membrane matrix during the extrusion process, before the membrane is fully formed. This preliminary distribution ensures uniform pore size and structure throughout the final product. The pore-forming agents are pre-mixed with the polymer and filler, allowing controlled pore formation as the membrane solidifies, thereby achieving precise pore size control during manufacturing rather than requiring subsequent modification.

Inventive Principle:
Principle #10Preliminary action

3Stability of the object's composition

If filler content is increased to improve dimensional stability, then thermal stability improves, but processing difficulty increases

Engineering Contradiction:
Improvethermal stabilityVSAvoidprocessing ease
Core Design Contradiction:
Stability of the object's compositionVSEase of manufacture

Solution Approach 1:

The patent optimizes the extrusion temperature and processing parameters based on the specific filler content and type. By adjusting the processing temperature to match the thermal properties of the filler-material composite, the patent ensures proper flow and consolidation during extrusion. The processing parameters are tuned to accommodate higher filler loads while maintaining manufacturability, resolving the contradiction between thermal stability and processing ease.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process results in a microporous material with enhanced dimensional stability at elevated temperatures and adjustable pore size distribution, leading to improved physical properties such as tensile strength and reduced wet out time without chemical surface coatings.

Implementation Method 1

The formed sheet is then subjected to an extraction step, where the plasticizer is partially (or fully) removed

Methodology Applied
Scientific EffectExtraction: Liquid-Liquid Extraction

Implementation Method 2

Then, this microporous matrix is stretched. This produces a stretched microporous matrix

Methodology Applied
Scientific EffectDeformation: Deformation

Implementation Method 3

The stretched microporous matrix is then calendered to produce a final microporous material with much improved dimensional stability

Methodology Applied
Scientific EffectCompression: Compression

Data Source

PatentUS11563256B2Method of making a microporous material
Publication Date: 2023.01.24 DARAMIC LLC
  • US11563256B2 patent drawing
  • US11563256B2 patent drawing
  • US11563256B2 patent drawing

AI summary

A method for producing a microporous material comprising the steps of: providing an ultrahigh molecular weight polyethylene (UHMWPE); providing a filler; providing a processing plasticizer; adding the filler to the UHMWPE in a mixture being in the range of from about 1:9 to about 15:1 filler to UHMWPE by weight; adding the processing plasticizer to the mixture; extruding the mixture to form a sheet from the mixture; calendering the sheet; extracting the processing plasticizer from the sheet to produce a matrix comprising UHMWPE and the filler distributed throughout the matrix; stretching the microporous material in at least one direction to a stretch ratio of at least about 1.5 to produce a stretched microporous matrix; and subsequently calendering the stretched microporous matrix to produce a microporous material which exhibits improved physical and dimensional stability properties over the stretched microporous matrix.