Underfill Material Copolymerization for Voidless Mounting

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Solution Overview

Problem

Conventional semiconductor chip mounting methods face challenges in achieving low-pressure and voidless mounting, with existing underfill materials often requiring high pressing forces and risking chip warping or solder flow during the process.

Innovation Solution

An underfill material comprising an acrylic polymer, an acrylic monomer, and a maleimide compound, with specific mass ratios and molecular weight ranges, which forms a copolymer upon heating or UV irradiation, providing excellent heat resistance and adhesion, allowing for low-pressure mounting and voidless attachment of semiconductor chips to circuit boards.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional underfill materials are used for semiconductor chip mounting, then adhesion is achieved, but high pressing force is required causing chip warping or solder flow

Engineering Contradiction:
ImproveadhesionVSAvoidpressing force
Core Design Contradiction:
StrengthVSForce

Solution Approach 1:

The patent changes the chemical composition parameters of the underfill material by incorporating specific ratios of acrylic polymer (10-60 parts), acrylic monomer (10-60 parts), and maleimide compound (20-70 parts). This compositional parameter change enables the material to achieve adequate adhesion at lower pressing forces, resolving the contradiction between adhesion strength and pressing force requirements

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite underfill material system combining acrylic polymer, acrylic monomer, and maleimide compound. This composite formulation synergistically provides both adhesion capability and low-pressing-force characteristics, eliminating the need to choose between strong adhesion and low pressing force

Inventive Principle:
Principle #40Composite materials

2Reliability

If high pressing force is applied during mounting, then adhesion is ensured, but chip warping and solder flow occur

Engineering Contradiction:
Improveadhesion reliabilityVSAvoidchip warping and solder flow
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent modifies the rheological and chemical parameters of the underfill material through specific compositional ratios and molecular weight control (Mw: 100,000-1,200,000). These parameter changes enable the material to provide reliable adhesion while flowing easily at low pressures, preventing chip warping and solder flow that occur with conventional high-pressure mounting

Inventive Principle:
Principle #35Parameter changes

3Productivity

If conventional underfill materials are used, then mounting is achieved, but bubbles are formed during curing

Engineering Contradiction:
Improvemounting efficiencyVSAvoidvoidless mounting
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent changes the viscosity and curing characteristics of the underfill material through its specific compositional parameters. The material maintains low viscosity for easy application and bubble-free filling, then cures to form a voidless, reliable bond, achieving both high productivity and manufacturing precision

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables fluidization of the underfill material with minimal pressing force, prevents bubble formation during curing, and ensures stable, long-term adhesion without chip peeling, reducing warping and solder flow issues while accommodating increased pin counts.

Implementation Method 1

forms a copolymer upon heating or UV irradiation

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 2

forms a copolymer upon heating or UV irradiation

Methodology Applied
Scientific EffectThermal curing: Heating

Data Source

PatentUS11084941B2Underfill material, underfill film, and method for manufacturing semiconductor device using same
Publication Date: 2021.08.10 DEXERIALS CORP
  • US11084941B2 patent drawing
  • US11084941B2 patent drawing
  • US11084941B2 patent drawing

AI summary

Provided are an underfill material capable of realizing low-pressure mounting and voidless mounting, and a method for manufacturing a semiconductor device using the same. The underfill material includes a main composition containing an acrylic polymer, an acrylic monomer, and a maleimide compound, and the acrylic polymer is contained in a range of 10 parts by mass or more and 60 parts by mass or less in 100 parts by mass of the main composition, and the maleimide compound is contained in a range of 20 parts by mass or more and 70 parts by mass or less in 100 parts by mass of the main composition. Low-pressure mounting and the voidless mounting can be realized.