UV-Curable Glass Inks for Thin Opaque Automotive Display Layers

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Solution Overview

Problem

Existing inks for decorating automotive display cover glass suffer from low throughput, inadequate adhesion, and undesirable optical density, making them unsuitable for automotive interior applications.

Innovation Solution

UV curable ink compositions comprising specific weight percentages of pigment dispersion, photoinitiator package, reactive diluent, multifunctional monomer, and difunctional monomer, with a pigment content of at least 30 wt % in the pigment dispersion, forming an opaque layer with high adhesion and optical density through controlled curing processes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If existing inks are used for decorating display cover glass, then the decorating process can be performed, but the inks exhibit low adhesion, inadequate optical density, and low throughput

Engineering Contradiction:
ImproveadhesionVSAvoidthroughput
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent changes the chemical composition parameters of the ink by incorporating specific adhesion promoters (silane-modified polymers), optimizing pigment concentrations (10-50 wt%), and adjusting resin content (5-40 wt%) to achieve both high adhesion and adequate throughput in automotive display applications

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite ink formulation combining multiple components: adhesion promoters (silane-modified polymers), pigments, resins, and reactive diluents. This composite approach enables the ink to simultaneously achieve strong adhesion to glass substrates, sufficient optical density, and acceptable throughput for manufacturing

Inventive Principle:
Principle #40Composite materials

2Reliability

If existing inks are used for decorating display cover glass, then the decorating process can be performed, but the inks exhibit inadequate optical density

Engineering Contradiction:
Improveoptical densityVSAvoidink composition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent optimizes the pigment concentration parameter to 10-50 wt% and adjusts the resin content to 5-40 wt% to achieve the required optical density (≥5.0) while maintaining a manageable ink formulation that does not excessively increase composition complexity

Inventive Principle:
Principle #35Parameter changes

3Length of stationary object

If a thin opaque layer is formed (≤15 μm), then the display appearance is improved, but achieving high adhesion and optical density in such a thin layer is challenging

Engineering Contradiction:
Improvelayer thicknessVSAvoidadhesion
Core Design Contradiction:
Length of stationary objectVSReliability

Solution Approach 1:

The patent applies adhesion promoters (silane-modified polymers) that pre-establish strong chemical bonding to the glass substrate before the ink layer is fully cured. This preliminary adhesion enhancement enables the formation of thin layers (≤15 μm) while maintaining adhesion strength (≥4B) that would otherwise be difficult to achieve at such reduced thickness

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent optimizes the concentration of adhesion promoters and pigments within the ink formulation to maximize adhesion strength and optical density per unit thickness, enabling the achievement of ≥4B adhesion and ≥5.0 optical density in layers no thicker than 15 μm

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink compositions achieve high adhesion (≥4B) and optical density (≥5) in a thin layer (≤15 μm) on glass substrates, maintaining adhesion under environmental stress and providing a uniform appearance.

Implementation Method 1

greater than 0 wt % and less than or equal to 10 wt % of a photoinitiator package, the photoinitiator package comprising a type I photoinitiator, a type II photoinitiator, and an amine synergist

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Data Source

PatentUS12473446B2Photocurable inks and primers for automotive interior applications and glass articles comprising same
Publication Date: 2025.11.18 CORNING INC
  • US12473446B2 patent drawing
  • US12473446B2 patent drawing
  • US12473446B2 patent drawing

AI summary

An ultraviolet ink composition includes from 25 wt % to 50 wt % of a pigment dispersion, from greater than 0 wt % to 10 wt % of a photoinitiator package; from 10 wt % to 42 wt % of a reactive diluent; from 10 wt % to 20 wt % of a multifunctional monomer; and from 0 wt % to 25 wt % of a difunctional monomer. An ink primer includes from 2 wt % to 10 wt % of an adhesion promoter configured to bond to glass and from 90 wt % to 98 wt % of a solvent configured to promote bonding of the adhesion promoter to the glass. Another ink primer includes from 2 wt % to 10 wt % of an adhesion promoter configured to bond to glass, from greater than 0 wt % to 10 wt % of a photoinitiator package; and from 30 wt % to 45 wt % of a monofunctional monomer.