UV-Cleavable Release Layer for Thick Substrate Separation

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Solution Overview

Problem

Existing methods for separating a device substrate from a carrier substrate in semiconductor device fabrication are inefficient and require multiple processes, particularly when dealing with thick release layers, which can reduce fabrication efficiency.

Innovation Solution

A method involving a release layer composed of an aromatic polymerization unit and a siloxane polymerization unit, where the aromatic unit is decomposed by ultraviolet light and the siloxane unit is decomposed by a cleansing agent, allowing for simplified separation of the carrier substrate, followed by a cleaning process to expose the device substrate.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a thick release layer is used to attach the device substrate to the carrier substrate, then the attachment strength is improved, but the separation process becomes more complex and time-consuming

Engineering Contradiction:
Improveattachment strengthVSAvoidseparation process complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The release layer is segmented into two distinct functional units: an aromatic polymerization unit that provides UV-responsive decomposition and a siloxane polymerization unit that provides cleansing agent-responsive decomposition. This segmentation allows the thick release layer to be removed in two separate, simplified stages rather than requiring complex multi-step processes, thereby maintaining attachment strength while reducing separation process complexity

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The release layer utilizes parameter changes in response to different stimuli: UV irradiation triggers decomposition of the aromatic polymerization unit, and subsequent cleansing agent application triggers decomposition of the siloxane polymerization unit. This dual-parameter approach enables efficient removal of thick release layers through controlled chemical changes rather than mechanical or thermal processes, reducing both process complexity and time

Inventive Principle:
Principle #35Parameter changes

2Reliability

If a thick release layer is used to ensure proper attachment, then the attachment reliability is improved, but the fabrication time increases

Engineering Contradiction:
Improveattachment reliabilityVSAvoidfabrication time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The release layer is pre-configured with two distinct decomposition mechanisms before the attachment process begins. The aromatic polymerization unit is designed to decompose upon UV irradiation, and the siloxane polymerization unit is designed to decompose upon cleansing agent exposure. This preliminary action ensures that the thick release layer can be reliably removed through predetermined, efficient pathways, maintaining attachment reliability while minimizing fabrication time

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The removal of the thick release layer is achieved by substituting mechanical or thermal separation methods with chemical decomposition processes. UV irradiation induces photodecomposition of the aromatic unit, and cleansing agents induce chemical decomposition of the siloxane unit. This substitution enables rapid, controlled removal of thick release layers without the time-consuming mechanical scraping or heating processes, thereby reducing fabrication time while maintaining reliability

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Ease of manufacture

If a simple release layer composition is used, then the ease of manufacture is improved, but the separation efficiency decreases

Engineering Contradiction:
Improveease of manufactureVSAvoidseparation efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The release layer employs a composite material structure combining aromatic polymerization units and siloxane polymerization units in a single layer. This composite approach integrates two distinct chemical functionalities that respond to different stimuli (UV light and cleansing agents), enabling efficient separation through a simplified two-step process. The composite structure maintains ease of manufacture as a single layer while achieving high separation efficiency through the synergistic combination of different decomposition mechanisms

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables efficient separation of the carrier substrate, reducing the time and complexity of the fabrication process while maintaining high fabrication efficiency, even with thicker release layers, and allows for further processing into semiconductor devices.

Implementation Method 1

irradiating the carrier substrate with an ultraviolet ray to separate the carrier substrate from the release layer

Methodology Applied
Scientific EffectUltraviolet decomposition: Photodissociation

Implementation Method 2

a siloxane polymerization unit that is decomposed by the cleansing agent

Methodology Applied
Scientific EffectChemical decomposition: Decomposition (biological)

Data Source

PatentUS12354879B2Method of fabricating semiconductor device and method of separating substrate
Publication Date: 2025.07.08 SAMSUNG ELECTRONICS CO LTD
  • US12354879B2 patent drawing
  • US12354879B2 patent drawing
  • US12354879B2 patent drawing

AI summary

Disclosed are methods of fabricating semiconductor devices and methods of separating substrates. The semiconductor device fabricating method comprises providing a release layer between a carrier substrate and a first surface of a device substrate to attach the device substrate to the carrier substrate, irradiating the carrier substrate with an ultraviolet ray to separate the carrier substrate from the release layer and to expose one surface of the release layer, and performing a cleaning process on the one surface of the release layer to expose the first surface of the device substrate. The release layer includes an aromatic polymerization unit and a siloxane polymerization unit.