Vacuum Multi-Chamber Halide Scavenging for Semiconductor Processing

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Solution Overview

Problem

Existing semiconductor processing technologies face challenges in reducing film contamination and improving device quality due to moisture interaction with fluorine or halides remaining on silicon oxide surfaces, leading to aging defects and quality issues.

Innovation Solution

The development of advanced substrate processing systems and methods that include multiple processing chambers and a treatment chamber with plasma and ultraviolet light capabilities, allowing for controlled etching and scavenging operations to remove contaminants and prevent moisture interaction, maintaining a moisture-free environment to minimize halide contamination.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If wet HF etch is used to remove silicon oxide, then etching selectivity is improved, but moisture contamination and aging defects increase

Engineering Contradiction:
Improveetching selectivityVSAvoidmoisture contamination
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent extracts the harmful moisture from the processing environment by implementing a vacuum-based multi-chamber system. Substrates are transferred through vacuum chambers that prevent moisture ingress, effectively removing the moisture contamination source while maintaining the wet etching process benefits.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent introduces vacuum transfer chambers as intermediary environments between the wet etching process and subsequent processing steps. These chambers act as mediators that prevent direct exposure to atmospheric moisture while allowing substrate transfer, thus eliminating aging defects without compromising etching selectivity.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If dry etching with local plasma is used to penetrate constrained trenches, then etching capability is improved, but substrate damage from electric arcs increases

Engineering Contradiction:
Improveetching capabilityVSAvoidsubstrate damage
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The patent removes the harmful electric arcs from the etching process by extracting plasma generation to a remote source. The plasma is generated in a separate chamber and the reactive species are transported to the substrate, eliminating direct arc contact with the substrate while maintaining etching capability.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent replaces the direct plasma-substrate interaction mechanism with a remote plasma delivery system. Instead of applying plasma directly to the substrate (which causes arcs), the system uses gas flow to transport reactive species, substituting a gentler transport mechanism for the harsh direct plasma application.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Device complexity

If multiple processing steps are performed in atmospheric conditions, then process simplicity is improved, but film contamination and aging defects increase

Engineering Contradiction:
Improveprocess simplicityVSAvoidfilm contamination
Core Design Contradiction:
Device complexityVSObject-affected harmful factors

Solution Approach 1:

The patent combines multiple processing chambers into a single vacuum-based processing system. By merging deposition, etching, and treatment functions into interconnected vacuum chambers, the system maintains process simplicity through integration while preventing contamination via vacuum isolation.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent creates an inert vacuum environment throughout the processing system to replace atmospheric conditions. This inert environment prevents moisture-related aging defects and film contamination while allowing all processing steps to be performed in sequence without breaking vacuum, thus preventing contamination without significantly increasing complexity.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These systems and methods effectively reduce halide contamination and aging defects, improving the quality and reliability of semiconductor devices by maintaining a controlled environment that limits moisture exposure and enhances contaminant removal processes.

Implementation Method 1

The treatment chamber may include components configured to generate a direct plasma within the treatment chamber

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

The treatment chamber may also include components configured to generate an ultraviolet light treatment within the treatment chamber

Methodology Applied
Scientific EffectUltraviolet light: Light

Data Source

PatentUS9991134B2Processing systems and methods for halide scavenging
Publication Date: 2018.06.05 APPLIED MATERIALS INC
  • US9991134B2 patent drawing
  • US9991134B2 patent drawing
  • US9991134B2 patent drawing

AI summary

Systems, chambers, and processes are provided for controlling process defects caused by moisture contamination. The systems may provide configurations for chambers to perform multiple operations in a vacuum or controlled environment. The chambers may include configurations to provide additional processing capabilities in combination chamber designs. The methods may provide for the limiting, prevention, and correction of aging defects that may be caused as a result of etching processes performed by system tools.