Vertical Resistive Memory Stack With Graphene and BN Layers

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Solution Overview

Problem

Existing vertical variable resistance memory devices face challenges with electron mobility due to surface roughness of insulation patterns between gate electrodes, and thick insulation layers are required to prevent leakage current, making it difficult to form vertical electrodes.

Innovation Solution

The use of graphene for gate electrodes and hexagonal or amorphous boron nitride (h-BN or a-BN) for insulation patterns, which reduces surface roughness and thickness, enhancing electron mobility and facilitating the formation of vertical electrodes with smaller dimensions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If thick insulation layers are used to prevent leakage current, then leakage prevention is improved, but device complexity and manufacturing difficulty increase

Engineering Contradiction:
Improveleakage current preventionVSAvoidinsulation layer thickness
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent changes the material parameter of the insulation layer from conventional materials to hexagonal boron nitride (h-BN), which has inherently superior electrical insulation properties. This material substitution allows achieving the same leakage prevention performance with significantly reduced thickness, resolving the contradiction between reliability and device complexity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs ultrathin h-BN insulation layers that can be precisely controlled in thickness, replacing the need for thick insulation layers. This approach uses a 'shorter' (thinner) object that achieves the same functional purpose with reduced dimensions, simplifying the overall device structure

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Reliability

If surface roughness of insulation patterns is reduced to improve electron mobility, then electron mobility is improved, but manufacturing precision requirements increase

Engineering Contradiction:
Improveelectron mobilityVSAvoidsurface roughness control
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent changes the material parameter from conventional insulation materials to h-BN, which naturally provides an atomically flat surface with extremely low roughness. This material parameter change inherently achieves smooth surfaces without requiring excessively tight manufacturing tolerances, as h-BN's crystalline structure naturally resists surface defects

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite material structures combining h-BN insulation layers with graphene gate electrodes. This composite approach leverages the complementary properties of both materials: h-BN provides both insulation and surface smoothness, while graphene provides high electron mobility, together resolving the contradiction between mobility improvement and manufacturing precision

Inventive Principle:
Principle #40Composite materials

3Quantity of substance

If vertical electrodes are made with smaller dimensions to improve integration density, then integration density is improved, but manufacturing difficulty increases

Engineering Contradiction:
Improveintegration densityVSAvoidvertical electrode formation
Core Design Contradiction:
Quantity of substanceVSEase of manufacture

Solution Approach 1:

The patent changes the surface energy and adhesion parameters by using h-BN as the insulation layer material. This creates an ideal interface for subsequent electrode material deposition, enabling precise formation of small-dimension vertical electrodes through standard fabrication processes without requiring advanced manufacturing techniques

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The h-BN insulation layer acts as an intermediary that facilitates the formation of small-dimension vertical electrodes. Its atomically smooth surface serves as an ideal template for controlled material deposition, enabling precise electrode patterning at small dimensions while maintaining manufacturing feasibility through standard semiconductor fabrication processes

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration improves electron mobility and integration density by reducing resistance and preventing leakage current, while allowing for easier formation of vertical electrodes, thus enhancing the performance of the vertical variable resistance memory device.

Implementation Method 1

the mobility of electrons in gate electrodes may be considered

Methodology Applied
Scientific EffectElectron mobility: Conduction (electrical)

Implementation Method 2

first insulation patterns between the gate electrodes, each of the first insulation patterns including boron nitride (BN)

Methodology Applied
Scientific EffectElectrical insulation: Dielectric

Data Source

PatentUS12193343B2Vertical variable resistance memory devices
Publication Date: 2025.01.07 SAMSUNG ELECTRONICS CO LTD
  • US12193343B2 patent drawing
  • US12193343B2 patent drawing
  • US12193343B2 patent drawing

AI summary

A vertical variable resistance memory device including gate electrodes spaced apart from each other in a first direction on a substrate, each of the gate electrodes including graphene and extending in a second direction, the first direction being substantially perpendicular to an upper surface of the substrate and the second direction being substantially parallel to the upper surface of the substrate; first insulation patterns between the gate electrodes, each of the first insulation patterns including boron nitride (BN); and at least one pillar structure extending in the first direction through the gate electrodes and the first insulation patterns on the substrate, wherein the at least one pillar structure includes a vertical gate electrode extending in the first direction; and a variable resistance pattern on a sidewall of the vertical gate electrode.