Virtual Cathode Deposition for Thin Film Manufacturing

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Solution Overview

Problem

The industrial application of Pulsed Electron Deposition (PED) is hindered by the short lifespan of dielectric tubular elements, low reproducibility of pulses, and scalability issues in wide area deposition due to the channel-spark discharge (CSD) electron beam source.

Innovation Solution

A thin film deposition apparatus utilizing a virtual cathode group with a high voltage and high current electrical pulse to generate a high-energy electron beam, avoiding contamination and improving reproducibility by forming a virtual cathode that temporarily ablates the target and deposits material onto a substrate.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of stationary object

If a conventional solid cathode is used in PED, then electron beam generation is achieved, but the cathode becomes contaminated by ablated material leading to short lifespan

Engineering Contradiction:
Improvecathode lifespanVSAvoidcathode contamination
Core Design Contradiction:
Duration of action of stationary objectVSObject-affected harmful factors

Solution Approach 1:

A gas flow intermediary is introduced between the target and cathode regions. The gas flows from the target area through the cathode region to the vacuum pump, carrying away ablated material before it can contaminate the cathode. This intermediary gas flow protects the cathode from direct exposure to contaminating particles while maintaining the electron beam generation function.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The harmful ablated material is extracted from the deposition chamber through a dedicated gas flow path. By routing gas flow to carry particles away from the cathode region and directly to the vacuum pump, the system removes the contaminating substance before it can deposit on the cathode surface, thereby extending cathode lifespan.

Inventive Principle:
Principle #2Taking out (Extraction)

2Area of stationary object

If CSD electron beam source is used for wide area deposition, then deposition area is increased, but reproducibility of pulses deteriorates

Engineering Contradiction:
Improvedeposition areaVSAvoidpulse reproducibility
Core Design Contradiction:
Area of stationary objectVSReliability

Solution Approach 1:

The cathode structure is segmented into multiple independent discharge regions arranged in an array. Each segment can be independently controlled to generate electron beams, allowing the system to achieve wide area deposition while maintaining consistent pulse characteristics in each segment. This segmentation prevents the reproducibility issues associated with single large-area CSD sources.

Inventive Principle:
Principle #1Segmentation

3Manufacturing precision

If high energy density pulse is applied to ablate target, then film deposition quality is improved, but device complexity increases

Engineering Contradiction:
Improvefilm deposition qualityVSAvoidelectron beam source complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The system uses the energy from the electron beam itself to sustain the plasma discharge and maintain the deposition process. The electron beam ionizes the gas and sustains the plasma without requiring external heating or complex control systems, allowing high energy density pulses to be applied effectively while keeping the overall device complexity manageable.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution extends the uptime of the electron beam source, enhances reproducibility, and enables scalable wide area deposition by preventing cathode contamination and optimizing plasma generation for high-energy and high-current electron beam production.

Implementation Method 1

application high voltage (1-60 kV) high current (0.1-10 kA) electrical pulse, generated by a pulsed power group, to a virtual cathode group. The virtual cathode group apparatus generates initial plasma from a gas supplied in a gas container

Methodology Applied
Scientific EffectElectrical discharge: Electric Spark

Implementation Method 2

This virtual cathode plasma obtains a negative potential bias, provided by the pulsed power supply, that leads to generation of an electron beam. The formation of the electron beam occurs in the thin sheath which is formed between the boundary of the plasma serving as virtual cathode and the target serving as an anode. Due to the small distance between the plasma boundary and target the space-charge limit is high and this allows high-energy and high-current pulsed electron beam generation

Methodology Applied
Scientific EffectElectron beam generation: Electron Beam

Implementation Method 3

The extremely high energy density pulse of from the laser or electron beam can ablate the target (turn some amount of solid target into plasma). This plasma expands outward towards the target in the form of a plasma plume with a composition comprising the target compounds

Methodology Applied
Scientific EffectAblation: Ablation

Implementation Method 4

This plasma expands outward towards the target in the form of a plasma plume with a composition comprising the target compounds. The ablated material, in a form of a plasma plume, propagates outward the target surface through the section where the virtual cathode plasma was located. In this way, the factor restricting the uptime of electron beam sources - contamination of the cathode by the ablated material - is avoided

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentEP3195344B1Apparatus and method for virtual cathode deposition (VCD) for thin film manufacturing
Publication Date: 2020.08.26 PLASMA APP
  • EP3195344B1 patent drawingFigure 1
  • EP3195344B1 patent drawingFigure 2
  • EP3195344B1 patent drawingFigure 3

AI summary

A virtual cathode deposition apparatus utilises virtual plasma cathode for generation of high density electron beam to ablate a solid target. A high voltage electrical pulse ionizes gas to produce a plasma which temporarily appears in front of the target and serves as the virtual plasma cathode at the vicinity of target. This plasma then disappears allowing the ablated target material in a form of a plasma plume to propagate toward the substrate. Several virtual cathodes operating in parallel provide plumes that merge into a uniform plasma which when condensing on a nearby substrate leads to wide area deposition of a uniform thickness thin film.