Wafer Bonding via Plasma-Activated Atomic Diffusion

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Solution Overview

Problem

Conventional wafer bonding methods, such as indirect and direct bonding, face challenges when bonding dissimilar materials with different coefficients of thermal expansion, particularly for single-crystalline oxide materials like lithium niobate, as they often result in stress and are not suitable for high-temperature or opto-electronic applications due to adhesive or intermediate layer issues.

Innovation Solution

A novel apparatus and method utilizing a UHV environment with a plasma deposition source and high-force actuation for surface activation and bonding, allowing for atomic diffusion bonding or surface-activated bonding of polished surfaces, including the use of uniquely structured hinges and annealing to achieve low-loss optical waveguides and other electronic devices.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If indirect wafer bonding with adhesive is used, then bonding of dissimilar materials is enabled, but high-temperature processing compatibility is lost and optical transparency is reduced

Engineering Contradiction:
Improvebonding capability for dissimilar materialsVSAvoidhigh-temperature processing compatibility and optical transparency
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The invention removes the adhesive or intermediate layer from the bonding interface, achieving direct bonding between dissimilar materials. This extraction of the intermediate layer eliminates the trade-off between bonding capability and optical transparency, as the direct bond provides both strong adhesion and optical clarity without requiring temperature-compatible adhesives.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the bonding parameters by performing bonding at room temperature or low temperatures in a UHV environment, rather than requiring high temperatures. This parameter change enables direct bonding of dissimilar materials without thermal stress while maintaining material integrity and optical properties.

Inventive Principle:
Principle #35Parameter changes

2Strength

If high temperature direct bonding is used, then strong bonding is achieved, but stress occurs when bonding materials with different CTE

Engineering Contradiction:
Improvebond strengthVSAvoidthermal expansion stress
Core Design Contradiction:
StrengthVSStress or pressure

Solution Approach 1:

The invention changes the temperature parameter from high temperature to room temperature or low temperature bonding. This eliminates thermal expansion stress between materials with different CTE while still achieving strong bonding through surface activation and atomic diffusion mechanisms in the UHV environment.

Inventive Principle:
Principle #35Parameter changes

3Adaptability or versatility

If low temperature direct bonding is used, then bonding of dissimilar materials is enabled, but bonding strength is insufficient

Engineering Contradiction:
Improvebonding capability for dissimilar materialsVSAvoidbond strength
Core Design Contradiction:
Adaptability or versatilityVSStrength

Solution Approach 1:

The invention applies preliminary surface activation treatment to the wafer surfaces before bonding. This preliminary action modifies the surface chemistry to enhance adhesion at low temperatures, enabling strong bonding of dissimilar materials without requiring high temperatures that would cause thermal stress.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention uses a UHV environment as an inert atmosphere during bonding. This inert environment prevents oxidation and contamination at low temperatures while allowing atomic diffusion bonding to proceed, achieving both strong bonding and compatibility with dissimilar materials.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

4Adaptability or versatility

If room temperature UHV bonding is used, then bonding of dissimilar materials with different CTE is achieved, but process complexity increases

Engineering Contradiction:
Improvebonding capability for dissimilar materialsVSAvoidUHV chamber and plasma source requirements
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The invention integrates multiple functions into a single UHV chamber system that performs surface activation, deposition, and bonding operations. This multi-functionality reduces the need for separate processing chambers and steps, thereby reducing overall process complexity despite the advanced capabilities required.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables reliable bonding of dissimilar materials at room temperature with high bonding throughput and low optical loss, suitable for high-power electronic and photonic devices, while maintaining transparency and minimizing interference with electronic or photonic properties.

Implementation Method 1

A plasma deposition source is used to deposit a mono layer of metal atoms on the wafer surfaces

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Implementation Method 2

The metal atoms are then diffused across the wafer surfaces to form a bonded wafer pair

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 3

The bonded wafer pair is then ion-sliced or thinned and annealed

Methodology Applied
Scientific EffectAnnealing: Annealing

Data Source

PatentUS10948653B2Apparatus for bonding wafers and an optically-transparent thin film made from the same
Publication Date: 2021.03.16 PARTOW TECHNOLOGIES LLC
  • US10948653B2 patent drawing
  • US10948653B2 patent drawing
  • US10948653B2 patent drawing

AI summary

A novel apparatus for bonding of two polished substrates includes a plasma source in a ultra-high vacuum (UHV) chamber and a wafer-guiding element to control and guide wafers in the UHV chamber, where after a plasma activation process the wafers are guided and pressed against each other to form a covalent bond between wafer surfaces. The plasma activation process involves deposition of mono-layer or sub-monolayer metallic atom on the surface of substrates. After deposition of metallic layers, a high-force actuation presses the wafers and forms a covalent bond between the wafers. Then, the bonded wafer pair is ion-sliced or thinned to form single crystalline optical thin film. An annealing process oxidizes the deposited metallic layers and produces optically-transparent single crystalline thin film. An optical waveguide may be fabricated by this thin film while utilizing an electro-optic effect to produce optical modulators and other photonic devices.