Combined XRD and XRF Detection Using Scanning Wavelength Selector

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Solution Overview

Problem

Current X-ray diffraction (XRD) and X-ray fluorescence (XRF) analysis techniques require separate instruments, leading to increased complexity, cost, and space requirements, as they have different technical requirements and cannot be easily combined into a single apparatus without compromising performance.

Innovation Solution

A method and apparatus that utilize a single combined detection arrangement capable of performing both XRD and XRF analysis, employing a polychromatic X-ray source and a scanning wavelength selector to switch between XRD and XRF modes, allowing for cost and space savings by sharing components.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If separate instruments are used for XRD and XRF analysis, then each technique can be optimized for its specific requirements, but device complexity and cost increase

Engineering Contradiction:
Improveanalysis performanceVSAvoidinstrument complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent implements a single X-ray source and detection arrangement that can perform both XRD and XRF analyses by switching between operational modes. The system uses a polychromatic X-ray source that can operate in fluorescence mode for XRF and diffraction mode for XRD, eliminating the need for separate instruments while maintaining optimized performance for both techniques

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The system dynamically switches between XRD and XRF operational modes by adjusting the X-ray source characteristics and detection parameters. The polychromatic source can be configured to emit appropriate spectra for each mode, and the detection arrangement can be optimized accordingly, allowing one instrument to adapt to different analytical requirements

Inventive Principle:
Principle #15Dynamics

2Reliability

If separate instruments are used for XRD and XRF analysis, then each technique can be optimized, but cost increases

Engineering Contradiction:
Improveanalysis performanceVSAvoidinstrument cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent implements a single X-ray source and detection arrangement that can perform both XRD and XRF analyses by switching between operational modes. The system uses a polychromatic X-ray source that can operate in fluorescence mode for XRF and diffraction mode for XRD, eliminating the need for separate instruments while maintaining optimized performance for both techniques

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Reliability

If separate instruments are used for XRD and XRF analysis, then each technique can be optimized, but space requirements increase

Engineering Contradiction:
Improveanalysis performanceVSAvoidlaboratory space
Core Design Contradiction:
ReliabilityVSArea of stationary object

Solution Approach 1:

The patent implements a single X-ray source and detection arrangement that can perform both XRD and XRF analyses by switching between operational modes. The system uses a polychromatic X-ray source that can operate in fluorescence mode for XRF and diffraction mode for XRD, eliminating the need for separate instruments while maintaining optimized performance for both techniques

Inventive Principle:
Principle #6Universality (Multi-functionality)

4Device complexity

If a single combined detection arrangement is used for XRD and XRF, then device complexity and cost are reduced, but measurement precision may be compromised

Engineering Contradiction:
Improveinstrument complexityVSAvoidanalysis precision
Core Design Contradiction:
Device complexityVSMeasurement precision

Solution Approach 1:

The system dynamically switches between XRD and XRF operational modes by adjusting the X-ray source characteristics and detection parameters. The polychromatic source can be configured to emit appropriate spectra for each mode, and the detection arrangement can be optimized accordingly, allowing one instrument to adapt to different analytical requirements

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent changes operational parameters such as X-ray source spectrum, detection mode, and geometric configuration to optimize performance for each analysis type. By adjusting these parameters, the system maintains high measurement precision while using a single combined detection arrangement

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables simultaneous XRD and XRF analysis with a single instrument, reducing complexity and cost while maintaining high performance, by using a single X-ray source and detection arrangement, thus providing a compact and efficient analytical tool for both structural and elemental composition analysis.

Implementation Method 1

In the XRF technique, a sample is irradiated with an X-Ray beam which induces the emission of secondary X-rays having wavelengths characteristic of the constituents elements of the material

Methodology Applied
Scientific EffectX-ray fluorescence: Fluorescence

Implementation Method 2

Detection of the diffracted X-rays over a range of angles provides an angular diffraction pattern or diffractogram having characteristic peaks of diffracted intensity when the condition of Bragg's law is satisfied

Methodology Applied
Scientific EffectX-ray diffraction: Bragg Diffraction

Data Source

PatentEP2513641B1Method and apparatus for performing x-ray analysis of a sample
Publication Date: 2019.04.10 THERMO FISHER SCI ECUBLENS
  • EP2513641B1 patent drawingFigure 1
  • EP2513641B1 patent drawingFigure 2
  • EP2513641B1 patent drawingFigure 3

AI summary

The invention provides a method of performing X-ray diffraction (XRD) and/or X-ray fluorescence (XRF) analysis of a sample, comprising: irradiating a sample with X-rays from an X-ray source; providing a combined XRD and XRF detection arrangement comprising a scanning wavelength selector and at least one X-ray detector for detecting X-rays selected by the wavelength selector; and performing XRD analysis of the sample by selecting at least one fixed wavelength of X-rays diffracted by the sample using the scanning wavelength selector and detecting X-rays of the selected fixed wavelength(s) at one or more values of the diffraction angle f at the sample using the X-ray detector(s); and/or performing XRF analysis of the sample by scanning wavelengths of X-rays emitted by the sample using the scanning wavelength selector and detecting X-rays of the scanned wavelengths using the X-ray detector(s). Also provided is an apparatus for performing both X-ray diffraction (XRD) and X-ray fluorescence (XRF) analysis of a sample comprising a combined XRD and XRF detection arrangement comprising a scanning wavelength selector and at least one X-ray detector for detecting X-rays selected by the wavelength selector.