Intelligent response organic room temperature phosphorescent material and preparation method and application thereof

CN117964838BActive Publication Date: 2026-08-28NINGBO INST OF MATERIALS TECH & ENG CHINESE ACAD OF SCI
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Patent Information

Application Number
CN202410108141.9
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2024-01-25
Publication Date
2026-08-28
Estimated Expiration
2044-01-25

AI Technical Summary

Technical Problem

[0005]虽然现有技术对有机室温磷光材料进行了较多的报道,但在已报道的智能响应有机室温磷光材料体系中,存在智能响应性较差、刺激源种类较少(多为温度、湿度、激发波长依赖)、刺激响应后磷光性能下降等问题,严重限制了刺激响应型室温磷光材料在实际生活中的应用

Benefits of technology

[0034](1)本发明刺激响应型有机室温磷光材料利用过饱和溶液的亚稳定性,开发了“触碰”作为新的刺激源,刺激响应性优异。

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Abstract

The application discloses an intelligent response organic room-temperature phosphorescent material and a preparation method and application thereof. The method comprises the following steps: dissolving a dipyridyl phosphor, a monomer and a crosslinking agent in a supersaturated solution obtained by melting a hydrated salt to obtain a mixed solution, adding an initiator into the mixed solution, stirring, and obtaining a precursor solution; and the monomer comprises acrylamide, acrylic acid or methyl methacrylate. The preparation method has the advantages of mild conditions, short preparation process, low cost, cheap and easily available raw materials, and the prepared material has the advantages of good stimulus response, long afterglow time, long phosphorescent lifetime and the like, and the material can realize response through touching, and has a wide application prospect in the fields of afterglow imaging, information encryption and anti-counterfeiting, warning or sensing.
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Citation Information

Patent Citations

  • Preparation method of organic room-temperature phosphorescent material with ultra-long phosphorescent lifetime

    CN114774113A

  • Organic-inorganic hybrid long afterglow material, preparation method thereof and application of organic-inorganic hybrid long afterglow material in ink-jet printing

    CN112341491A

  • Flexible organic room-temperature phosphorescent material as well as preparation method and application thereof

    CN116240015A