A method for preparing and flotating gypsum-containing zinc oxide ore

By adding a high-molecular-weight calcium ion chelating agent and sodium carbonate during the grinding and flotation slurry preparation of zinc oxide ore, the influence of gypsum-dissolved calcium ions on the surface of zinc oxide minerals was resolved, the sulfidation efficiency of the sulfiding agent was improved, and efficient flotation recovery of zinc oxide minerals was achieved.

CN119500415BActive Publication Date: 2025-12-02CENT SOUTH UNIV
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Patent Information

Application Number
CN202411734483.8
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2024-11-29
Publication Date
2025-12-02
Estimated Expiration
2044-11-29

AI Technical Summary

Technical Problem

The presence of soluble salts such as gypsum in zinc oxide ore affects the flotation process, resulting in poor separation performance, and existing technologies are unable to effectively recover zinc oxide resources.

Method used

During the grinding and flotation slurry preparation process, a high molecular weight calcium ion chelating agent and sodium carbonate are added. Through chelation and flocculation reactions, the impact of gypsum-dissolved calcium ions on the surface of zinc oxide minerals is reduced, and the sulfidation efficiency of the sulfiding agent is improved. Sodium sulfide and a collector are used for flotation.

Benefits of technology

It effectively reduces the adsorption of calcium ions dissolved in gypsum on the surface of zinc oxide minerals, improves the surface sulfidation efficiency of sodium sulfide, achieves efficient flotation recovery of zinc oxide minerals, and obtains better flotation indicators.

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Abstract

This invention discloses a method for preparing and flotating gypsum-containing zinc oxide ore, comprising the following steps: grinding the raw ore finely, sequentially adding a high-molecular-weight calcium ion chelating agent, sodium carbonate, and sodium sulfide to prepare the slurry, and finally adding a collector to perform zinc oxide mineral flotation to obtain zinc oxide rough concentrate. This invention overcomes the influence of soluble salt mineral gypsum, has strong adaptability, is simple to apply, and is convenient for large-scale production management, enabling efficient flotation recovery of this type of zinc resource.
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