Cyclic olefin ring-opening polymer, cyclic olefin ring-opening polymer hydride, resin composition, and resin molded article

By introducing 1,2,3,3a,4,6a-hexahydro-1,2,4-methylbridged pentanene and aromatic ring structural units into cyclic olefin ring-opening polymers, the problem that existing cyclic olefin ring-opening polymer hydrides are difficult to achieve both a moderate Abbe number and low birefringence is solved, thus realizing a high-performance material suitable for optical components.

CN122095006APending Publication Date: 2026-05-26ZEON CORP
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Patent Information

Application Number
CN202480068862.X
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Priority Date
2023-11-09
Filing Date
2024-11-05
Publication Date
2026-05-26

AI Technical Summary

Technical Problem

Existing cyclic olefin ring-opening polymer hydrides cannot simultaneously possess a suitable Abbe number and low birefringence, thus failing to meet the requirements for high Abbe number optical elements and low to medium Abbe number optical elements.

Method used

Hydrogenation of a cyclic olefin ring-opening polymer containing 1,2,3,3a,4,6a-hexahydro-1,2,4-methylbridged pentanene structural units and cyclic olefin monomer structural units with aromatic ring structures is carried out to form a cyclic olefin ring-opening polymer hydride with both moderate Abbe number and low birefringence.

Benefits of technology

This invention achieves cyclic olefin ring-opening polymer hydrides with moderate Abbe numbers and low birefringence, making them suitable for various molded materials, especially optical components, thus increasing the freedom of optical design.

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Abstract

The purpose of the present invention is to provide: a cyclic olefin ring-opening polymer hydride which has a low birefringence and an Abbe number of an appropriate size; and a starting material for the cyclic olefin ring-opening polymer hydride. This cyclic olefin ring-opened polymer is characterized by containing a structural unit (A) derived from 1, 2, 3, 3a, 4, 6a-hexahydro-1, 2, 4-methylpentalene and a structural unit (B) derived from a cyclic olefin monomer having an aromatic ring structure. The cyclic olefin ring-opening polymer hydride according to the present invention is characterized by being obtained by hydrogenating the cyclic olefin ring-opening polymer according to the present invention.
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