System and method for treating high-concentration organic wastewater containing sulfate

By coupling electrochemical and biological processes, the methanogenesis and sulfate reduction processes are decoupled, and sulfides are fixed using zero-valent iron. This achieves efficient treatment of organic wastewater with high sulfate concentrations, solves the problems of microbial competition and sulfide toxicity, and improves the stability and economy of the system.

CN122166951APending Publication Date: 2026-06-09BEIJING ZHONGKE GUOYI ENVIRONMENTAL PROTECTION ENG CO LTD
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Patent Information

Application Number
CN202610311188.4
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-03-14
Publication Date
2026-06-09

AI Technical Summary

Technical Problem

Existing technologies are insufficient to efficiently and synergistically achieve the deep reduction and stabilization of methanogens and sulfates in organic wastewater containing high concentrations of sulfate. Biological methods suffer from issues of microbial competitive inhibition and sulfide toxicity, while physicochemical methods pose risks of incomplete treatment and secondary pollution.

Method used

By coupling electrochemical and biological processes, the methanogenesis/electricity generation process and the sulfate reduction/sulfur fixation process are decoupled through ion exchange membranes and external circuits. Sulfides are fixed using zero-valent iron packing material, and the efficient energy conversion of organic matter and the deep and stable removal of sulfate are achieved through an intelligent collaborative control unit.

Benefits of technology

It achieves efficient energy recovery of organic matter and deep stabilization and fixation of sulfate, improving the system's treatment efficiency, resistance to load shocks and effluent stability, reducing operating costs and realizing resource recycling.

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Abstract

The invention provides a system and a method for treating sulfate-containing high-concentration organic wastewater, belongs to the technical field of industrial wastewater treatment, and is used for solving the problems of low methanogenesis efficiency caused by substrate competition of sulfate reducing bacteria and methanogens and inhibition of microbial activity by sulfide accumulation in related technologies. According to the system, a methanogenesis electrochemical oxidation unit and a sulfate bioelectrochemical reduction and sulfur fixation unit are separated and coupled through an ion exchange membrane and an external circuit, a cross series multi-stage treatment structure is constructed, and an intelligent cooperative control and sludge recycling unit is integrated; according to the method, efficient methane production of organic matters, deep reduction of sulfate and in-situ sulfur fixation are synchronously carried out, the removal rate of COD and sulfate in treated effluent is high, the content of HS in produced biogas is low, and sulfur and iron resources can be recycled.
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