Deeply modified coating and deeply modified coating composite separation membrane

By preparing a deep-modified coating on the surface and inside the pores of the substrate membrane and combining it with an interfacial polymerization process, the problem that conventional coating modification cannot improve the adsorption capacity of amine monomers in the substrate membrane is solved, and the desalination performance and ion selectivity of the composite separation membrane are significantly improved.

CN117619166BActive Publication Date: 2026-04-21CHINA UNIV OF PETROLEUM (EAST CHINA)
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Patent Information

Application Number
CN202311593636.7
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2023-11-27
Publication Date
2026-04-21
Estimated Expiration
2043-11-27

AI Technical Summary

Technical Problem

In existing technologies, conventional coating modification only modifies the substrate surface and fails to effectively improve the amine monomer adsorption capacity of ultrafiltration or microfiltration membranes, resulting in limited performance improvement of composite separation membranes.

Method used

A deep-modified coating was prepared on the surface of the substrate and inside the pores using a surface tension gradient-driven Marangoni convection process. The stability of the coating was enhanced by a crosslinking agent, and a dense ultrathin separation layer was prepared by an interfacial polymerization process to form a deep-modified coating composite separation membrane.

Benefits of technology

It significantly improves the adsorption capacity of the bottom membrane for amine monomers, promotes the diffusion-reaction process in the interfacial polymerization process, and thus enhances the desalination performance and selectivity of mono/divalent anions of the composite separation membrane.

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Abstract

This invention relates to deeply modified coatings and deeply modified coating composite separation membranes. The deeply modified coating is prepared using a surface tension gradient-driven Marangoni convection process and is used to deeply modify the surface and pores of an ultrafiltration or microfiltration substrate membrane. Further crosslinking with a crosslinking agent enhances the coating's stability. The deeply modified coating composite separation membrane has a three-layer structure, with the deeply modified coating as the middle layer, and also includes a bottom substrate membrane and a top dense ultrathin separation layer. The deeply modified coating significantly enhances the adsorption capacity of the substrate membrane for amine monomers and ultimately improves the desalination performance of the composite separation membrane.
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