A class of polynuclear metal catalysts, their preparation methods, and their application in the catalytic alcoholysis of polyester polymers.

A novel metal complex synthesized at room temperature using a polynuclear metal catalyst solves the problems of high energy consumption and high cost in the chemical recycling of plastic waste such as PET, and achieves safe, energy-saving and efficient alcoholysis, which is suitable for industrial-scale production.

CN118666887BActive Publication Date: 2025-10-28SOUTH CHINA UNIV OF TECH
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Patent Information

Application Number
CN202410590483.9
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2024-05-13
Publication Date
2025-10-28
Estimated Expiration
2044-05-13

AI Technical Summary

Technical Problem

The existing chemical recycling process for PET and other plastic waste is energy-intensive, costly, and inefficient. Furthermore, traditional catalysts have low catalytic efficiency, making it difficult to achieve safe, energy-saving, and efficient alcoholysis.

Method used

A polynuclear metal catalyst was developed to synthesize novel polynuclear metal complexes by transesterification of organic ligands with metal ions at room temperature. These complexes are used to catalyze the alcoholysis of polyester polymers such as PET in alcohol solvents at a temperature of 120°C and a pressure of 0-10 MPa.

Benefits of technology

This method enables rapid alcoholysis of polyester polymers such as PET, achieving high monomer purity and yield. It is simple, safe, and efficient, reducing energy consumption and production costs, and is suitable for large-scale industrial production.

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Abstract

This invention discloses a class of polynuclear metal catalysts, their preparation methods, and their application in the catalytic alcoholysis of polyester polymers. The polynuclear metal catalyst comprises an organic ligand and metal ions (titanium ions, zirconium ions, or hafnium ions). The general chemical formula of the polynuclear metal catalyst is shown in formulas (I) and (II). The polynuclear metal catalyst of this invention can catalyze the rapid alcoholysis of general-purpose polyester polymers such as PET in alcohol solvents. The method is simple, safe, efficient, energy-saving, and yields high purity and high efficiency of the recovered monomers.
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