An anthracene-based fluorescent polymer, its preparation method and application

By introducing anthracene groups into the all-aromatic polyimide, a fluorescent anthracene fluorescent polymer was prepared, which solved the problem that Ar-PIs did not have fluorescence and film formation difficulties, achieved good dissolution and film formation in organic solvents, and expanded its application in light-emitting devices.

CN118791737BActive Publication Date: 2025-08-01CHANGZHOU UNIV
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Patent Information

Application Number
CN202410854540.X
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2024-06-28
Publication Date
2025-08-01
Estimated Expiration
2044-06-28

AI Technical Summary

Technical Problem

Simple all-aromatic polyimides (Ar-PIs) do not have fluorescence and are difficult to form films, so they cannot be directly applied to light-emitting devices.

Method used

By introducing anthracene groups, an anthracene fluorescent polymer is prepared. A specific chemical reaction step is used to react 9,10-dibromoanthracene with 3-nitrophenylene boric acid and other raw materials under certain conditions to form a fluorescent polymer, and a film is formed in an organic solvent through a two-step method.

Benefits of technology

The obtained anthracene-based fluorescent polymer has good fluorescence and solubility, and can directly form films in a variety of organic solvents, and is used in light-emitting devices such as fluorescent probes and fluorescent sensing films, which improves the application potential of polyimide.

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Abstract

The present invention relates to the technical field of fluorescent polymers, and specifically relates to an anthracene-based fluorescent polymer, a preparation method thereof, and an application thereof. Pure Ar-PIs do not have fluorescence and cannot be directly applied to light-emitting devices. In view of the above problems, the present invention provides an anthracene-based fluorescent polymer. An anthracene-based luminescent group is introduced into the molecular structure of the polyimide. The obtained anthracene-based fluorescent polymer has good solubility in a variety of organic solvents and can be prepared into a fluorescent probe or a fluorescent polymer film with recognition and detection functions, having good application prospects.
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