Nix-CoPyOz nano material and preparation method and application thereof

By growing Nix-CoPyOz nanofilm materials on conductive substrates, using radiation-heating preparation method, the problem of irreversible active lithium loss in the cycle process of negative electrode lithium metal batteries is solved, and high energy density and long cycle performance are improved.

CN119695048AActive Publication Date: 2025-03-25RES INST OF CHEM DEFENSE PLA ACAD OF MILITARY SCI
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Patent Information

Application Number
CN202411754560.6
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2024-12-02
Publication Date
2025-03-25
Estimated Expiration
2044-12-02

AI Technical Summary

Technical Problem

The irreversible loss of active lithium in the existing negative electrode-free lithium metal batteries during the cycle leads to a low battery capacity retention rate, which cannot meet the needs of high energy density.

Method used

Nix-CoPyOz nanofilm material is grown on the conductive substrate by radiation-heating preparation method, improving its lithium-philicity and lithium binding energy, thereby improving the specific energy and long-cycle performance of the battery.

Benefits of technology

It realizes the construction of super lithium-philic materials on the current collector without metal negative electrodes, improves battery capacity and cycle stability, and meets the needs of high energy density.

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Abstract

The invention belongs to the field of energy storage and materials, and particularly relates to a Nix-CoPyOz nano material and a preparation method and application thereof. The invention develops a gamma ray radiation reduction and heat treatment method. The Nix-CoPyOz nano material is regulated and grown on a conductive substrate. When the Nix-CoPyOz nano-film material growing on the CC is used as an anode, a lithium sheet or graphite is used as a cathode, and a diaphragm adopts Celgard2035 to assemble a battery, the potential of deposited lithium is 5.3 mV. The Nix-CoPyOz nano-film material prepared by the invention has the characteristics of super lithium affinity or relatively high binding energy with lithium, and lithium can be uniformly deposited on a current collector when the metal-free negative electrode is used as the current collector, so that the battery capacity and the cycling stability are further improved.
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