Multifunctional self-assembled monolayer, perovskite solar cell and preparation method thereof

By using multifunctional self-assembled single-molecule compounds in NiOx-based perovskite solar cells, anchoring groups form covalent bonds with the oxide layer and perovskite surface, reducing interface defects and resistance, solving the problem of NiOx thin film-perovskite interface recombination, and improving photoelectric conversion efficiency.

CN122213086APending Publication Date: 2026-06-16CHINT NEW ENERGY TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
CHINT NEW ENERGY TECH CO LTD
Filing Date
2026-03-18
Publication Date
2026-06-16

AI Technical Summary

Technical Problem

In the prior art, the photovoltaic performance of NiOx-based perovskite solar cells is limited by defects at the interface between the NiOx thin film and the perovskite and nonradiative recombination caused by deep potential wells. Furthermore, the modification of the interface layer affects the performance of the perovskite light-absorbing layer, making it difficult to select suitable materials to improve compatibility.

Method used

A multifunctional self-assembled monomolecule compound is used to form covalent bonds on the oxide layer and perovskite surface through anchoring groups, reducing interface defects. Furthermore, benzothiadiazole is used to enhance π-π conjugation and promote lateral charge transport, forming a dense monolayer to reduce interface resistance.

🎯Benefits of technology

It effectively reduces interface defects and resistance, improves the photoelectric conversion efficiency of perovskite solar cells, and enhances their performance.

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Abstract

The application provides a multifunctional self-assembled monomer, a perovskite solar cell and a preparation method thereof.The multifunctional self-assembled monomer has a benzothiadiazole structure shown in formula 1.By introducing the multifunctional self-assembled monomer, interface defects can be reduced, interface resistance can be reduced, and the photoelectric conversion efficiency of the perovskite solar cell is improved.
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