Adsorbent, hydrogen production system, and hydrogen production method

CN122912797APending Publication Date: 2026-10-16CHINA RAILWAY 22ND BUREAU GROUP CORP LTD +1
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Patent Information

Application Number
CN202611091617.8
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-07-22
Publication Date
2026-10-16

AI Technical Summary

Technical Problem

[0004]本发明的目的是提供一种制氢系统及制氢方法,旨在解决现有天然气重整制氢能耗高、碳排放大、吸附剂稳定性差、无法适配燃料电池用氢需求、能量利用率低的行业痛点,通过材料改性、余热梯度利用、多塔联动控制、高纯氢纯化、碳能双向循环的一体化设计,实现稳定高效、低碳节能、可直接配套氢燃料电池的工业化制氢

Benefits of technology

[0023]本发明相较于传统技术具备四大核心创新优势:第一,本发明专属改性的锆-镍-氧吸附剂,解决传统吸附剂高温失效、易中毒、循环寿命短的缺陷,高温碳捕捉率可达92.3%以上,且经过上千次吸附-洗脱-再生循环后吸附容量保留率仍超过90%,展现出优异的循环稳定性和高温适配性,避免了传统低温吸附剂需要额外降温的弊端;第二,三级梯度余热利用架构打破传统单一供热模式,最大化回收系统废热,大幅降低制氢能耗与运行成本;第三,三塔错峰自适应控制策略,实现全流程动态平衡,解决传统多塔作业工况波动大、产氢不稳定的问题;第四,增设多级纯化稳压体系,填补传统制氢技术无法直接适配燃料电池的场景空白,产出氢气完全满足车载、固定式燃料电池系统使用标准。

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Abstract

The application discloses a carbon dioxide adsorbent, a hydrogen production system and a method. The hydrogen production system comprises a reforming unit and a carbon capture unit, and a zirconium-nickel-oxygen ternary composite oxide adsorbent is arranged in the carbon capture unit. The mixed gas after decarburization is returned to the reforming unit to promote the forward progress of the reforming reaction. The system adopts gradient waste heat grading utilization, three-tower staggered peak linkage self-adaptive control, and is matched with a fuel cell level five-stage high-purity hydrogen purification and pressure stabilizing buffer unit. The adsorbent is high-temperature resistant to poison and cyclically stable, the hydrogen production system can stably produce fuel cell level high-purity hydrogen, the carbon capture unit can realize self-heating and self-humidification by using reforming waste heat and steam by-products, and the raw materials of the reforming unit can be preheated, the hydrogen production system can also recycle the captured carbon dioxide to make dry ice to supply cooling for a computing power center, and has the advantages of high efficiency, energy saving, low carbon and circulation.
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