Rubber composition

Abstract

The invention relates to a rubber composition comprising a highly saturated diene elastomer which is a copolymer containing units of a 1,3-diene and more than 50 mole percent of ethylene units and bearing at one of its chain ends a functional group of formula -CH2-CH(CH3)-COOZ, Z being a hydrocarbon group substituted by an alkoxysilane or silanol function, a crosslinking system and a reinforcing inorganic filler, the highly saturated diene elastomer being a copolymer of ethylene and a 1,3-diene or a copolymer of ethylene, a 1,3-diene and an α-monoolefin.

Description

Description Title of the invention: Rubber composition The field of the invention is that of rubber compositions which can be used in particular for the manufacture of tires and which comprise a silica and a highly saturated diene elastomer, A tire must comply with a large number of technical requirements, often contradictory, including low rolling resistance, high wear resistance, and high grip on both dry and wet roads. This compromise of properties, particularly from the point of view of rolling resistance and wear resistance, has been improved in recent years on low-energy "Green Tires", intended in particular for passenger vehicles, thanks in particular to the use of new low-hysteretic rubber compositions whose characteristic is to be reinforced mainly with highly dispersible silicas known as "HDS" (Highly Dispersible Silica), capable of competing, from the point of view of reinforcing power, with conventional tire-grade carbon blacks. The Applicant has described in document WO 2014114607 the use of highly saturated diene elastomers in tire rubber compositions to modify the performance trade-off between rolling resistance and wear. These highly saturated diene elastomers contain 1,3-diene units and more than 50 mol% of ethylene units. To further reduce the hysteresis of these rubber compositions, the Applicant has described in document WO 2018224776 the use of highly saturated diene elastomers carrying a silanol or alkoxysilane function at the chain end. The functionalization at the chain end is carried out using a modifying agent which is an alkoxysilane compound. Continuing its efforts, Demandcressc has developed a new low-hysteretic rubber composition which contains a highly saturated diene elastomer and a silica, again with the aim of reducing the rolling resistance of a tire. Indeed, against all expectations, it has developed a low-hysteretic rubber composition which comprises a highly saturated diene elastomer which contains, as a functional group, at the end of the elastomer chain, a single monomer unit of a methacrylate carrying an alkoxysilane function which can be hydrolyzed into a silanol function. Thus a first object of the invention is a rubber composition which comprises a highly saturated diene elastomer containing units of a 1,3-diene and more than 50 mol% of ethylene units and carrying at one of its chain ends a functional group of formula -CH,-CH(CHz)-COOZ, Z being a hydrocarbon group substituted by an alkoxysilane or silanol function, a crosslinking system and a reinforcing inorganic filler, the highly saturated diene elastomer being a copolymer of ethylene and a 1,3-diene or a copolymer of ethylene, a 1,3-diene and an α-monoolefin. A second subject of the invention is a tire which comprises a tread, which tire comprises a rubber composition in accordance with the invention, preferably in its tread. Detailed description Any interval of values ​​designated by the expression "between a and b" represents the domain of values ​​greater than "a" and less than "b" (i.e., excluding the limits a and b), while any interval of values ​​designated by the expression "from a to b" means the domain of values ​​from "a" to "b" (i.e., including the strict limits a and b). The abbreviation “pce” means parts by weight per hundred parts of elastomer (of the total elastomers if more than one elastomer is present). In the present disclosure of the invention, the formalism alkyl1(C,-Cn) is used to denote an alkyl radical having n to m carbon atoms, n being an integer greater than or equal to 1, m being an integer greater than n. For example, alkyl(C,-C;) denotes an alkyl radical having 1 to 2 carbon atoms. Similarly, alkoxy(C,-C,) denotes an alkoxy radical having n to m carbon atoms. The compounds mentioned in the description may be of fossil or bio-sourced origin. In the latter case, they may be, partially or totally, derived from biomass or obtained from renewable raw materials derived from biomass. Similarly, the compounds mentioned may also come from the recycling of materials already in use, that is to say, they may be, partially or totally, derived from a recycling process, or obtained from raw materials themselves derived from a recycling process. In the present invention, the term "tyre" means a pneumatic or non-pneumatic tire. A pneumatic tire usually comprises two beads intended to come into contact with a rim, a crown composed of at least one crown reinforcement and a tread, two sidewalls, the tire being reinforced by a carcass reinforcement anchored in the two beads. A non-pneumatic tire, for its part, usually comprises a base, designed for example for mounting on a rigid rim, a crown reinforcement, ensuring the connection with a tread and a deformable structure, such as spokes, ribs or cells, this structure being arranged between the base and the summit. Such non-pneumatic tires do not necessarily include a sidewall. Non-pneumatic tires are described for example in documents WO 03 / 018332 and FR2898077. According to any of the embodiments of the invention, the tire according to the invention is preferably a pneumatic tire. The expression "based on" used to define the constituents of the catalytic system (or catalytic composition) means the mixture of these constituents, or the product of the reaction of some or all of these constituents with each other. The elastomer useful for the purposes of the invention is a highly saturated diene elastomer, since the ethylene units represent more than 50 mol% of all the monomer units of the highly saturated diene elastomer. Preferably, the highly saturated diene elastomer is a random copolymer. As is known, the expression "ethylene unit" refers to the -(CH,-CH 2)- unit resulting from the insertion of ethylene into the elastomer chain. The ethylene units in the highly saturated diene elastomer preferably represent at least 60 mol% of all the monomer units of the highly saturated diene elastomer, more preferably at least 65 mol% of all the monomer units of the highly saturated diene elastomer. Even more preferably, the ethylene units in the highly saturated diene elastomer represent at least 70 mol% of all the monomer units of the highly saturated diene elastomer. Preferably, the ethylene units in the highly saturated diene elastomer represent less than 90 mol% of all the monomer units of the highly saturated diene elastomer. More preferably, the ethylene units in the highly saturated diene elastomer represent at most 85 mol% of all the monomer units of the highly saturated diene elastomer. Even more preferably, the ethylene units in the highly saturated diene elastomer represent at most 80 mol% of all the monomer units of the highly saturated diene elastomer. According to an advantageous embodiment, the highly saturated diene elastomer comprises from 60% to less than 90 mol% of ethylene unit, particularly from 60% to 85 mol% of ethylene unit, molar percentage calculated on the basis of all the monomer units of the highly saturated diene elastomer. More advantageously, the highly saturated diene elastomer comprises from 60% to 80 mol% of ethylene unit, molar percentage calculated on the basis of all the monomer units of the highly saturated diene elastomer. According to another advantageous embodiment, the highly saturated diene elastomer comprises from 65% to less than 90% mol of ethylene unit, particularly 65% to 85% mol of ethylene unit, molar percentage calculated on the basis of all the monomer units of the highly saturated diene elastomer. More preferably, the highly saturated diene elastomer comprises from 65% to 80% mol of ethylene unit, molar percentage calculated on the basis of all the monomer units of the highly saturated diene elastomer. According to yet another advantageous embodiment of the invention, the highly saturated diene elastomer comprises from 70% to less than 90 mol% of ethylene unit, particularly from 70% to 85 mol% of ethylene unit, molar percentage calculated on the basis of all the monomer units of the highly saturated diene elastomer. More advantageously, the highly saturated diene elastomer comprises from 70% to 80 mol% of ethylene unit, molar percentage calculated on the basis of all the monomer units of the highly saturated diene elastomer. The highly saturated diene elastomer also includes 1,3-diene units resulting from the polymerization of a 1,3-diene. As is known, the expression "1,3-diene unit" or "diene unit" refers to the units resulting from the insertion of the 1,3-diene by a 1,4-addition, a 1,2-addition or a 3,4-addition in the case of isoprene for example. According to one embodiment of the invention, the 1,3-diene units represent at least 35 mol% of the monomer units of the highly saturated diene elastomer. According to another embodiment of the invention, the 1,3-diene units represent less than 35 mol% of the monomer units of the highly saturated diene elastomer. The highly saturated diene elastomer may contain units of an α-monoolefin. An α-monoolefin is understood to mean an ε-olefin that contains at least 3 carbon atoms and has a single carbon-carbon double bond, with double bonds in aromatic compounds not being considered. For example, styrene is considered an α-monoolefin. The ε-monoolefin is preferably aromatic, more preferably styrene or a styrene whose benzene ring is substituted by one or more alkyl groups. Even more preferably, the α-monoolefin is styrene. 1,3-diene is a single compound, i.e., a single (in English "one") 1,3-diene, or a mixture of 1,3-dienes that differ from each other in chemical structure. Suitable 1,3-dienes are 1,3-dienes having 4 to 20 carbon atoms. Preferably, the 1,3-diene is 1,3-butadiene, isoprene, myrcene, B-farnesene or mixtures thereof such as a mixture of at least two of them. The mixture of at least two of them is advantageously a mixture that contains 1,3-butadiene. The mixture of 1,3-dienes is preferably a mixture of 1,3-butadiene and myrcene or a mixture of 1,3-butadiene and B-farnesene. According to a particularly preferred embodiment of the invention, the 1,3-diene is a mixture of 1,3-butadiene and myrcene or a mixture of 1,3-butadiene and B-farnesene. According to another particularly preferred embodiment of the invention, the 1,3-diene is 1,3-butadiene. Advantageously, the highly saturated diene elastomer is a copolymer of ethylene and a 1,3-diene, in which case the constituent units of the highly saturated diene elastomer are those resulting from the polymerization of a 1,3-diene and ethylene. In particular, the highly saturated diene elastomer is a copolymer of ethylene and 1,3-butadiene or a copolymer of ethylene, 1,3-butadiene and myrcene or a copolymer of ethylene, 1,3-butadiene and β-farnesene. More preferably, the highly saturated diene elastomer is a random copolymer of ethylene and 1,3-butadiene or a random copolymer of ethylene, 1,3-butadiene and myrcene or a random copolymer of ethylene, 1,3-butadiene and β-farnesene. According to a particularly preferred embodiment of the invention, in particular when the 1,3-diene is 1,3-butadiene or a mixture of 1,3-dienes, one of which is 1,3-butadiene, the highly saturated diene elastomer contains 1,2-cyclohexane units, cyclic units of formula (D. Pie x = a * in CH { Cu-cH # 4 The presence of a saturated 6-membered cyclic unit, 1,2-cyclohexane, of formula (I) in the highly saturated diene elastomer may result from a series of very specific insertions of ethylene and 1,3-butadiene into the polymer chain during its growth. The mechanism for obtaining such a microstructure is, for example, described in Macromolecules 2009, 42, 3774-3779. When the highly saturated diene elastomer comprises units of formula (I), it preferably contains at most 15 mol% thereof, the percentage being expressed relative to all the monomer units of the highly saturated diene elastomer. The highly saturated diene elastomer also has the additional characteristic of carrying at one of its chain ends a functional group of formula -CH,-CH(CH, )-COOZ. The functional group is typically covalently attached to the chain end of the highly saturated diene elastomer, with one of the methylene carbon atoms (CH) of the functional group being covalently bonded to a carbon atom constituting the terminal monomer unit of the highly saturated diene elastomer. The symbol Z denotes a hydrocarbon group substituted by an alkoxysilane or silanol function. Preferably, Z denotes an alkyl substituted by an alkoxysilane or silanol function. More preferably, the alkyl substituted by an alkoxysilane or silanol function is an alkyl which contains 1 to 3 carbon atoms. According to a first embodiment, Z represents an alkyl substituted by an alkoxydialkylsilyl group, in particular alkoxy(C,-C)dialkyl(C,-C,)silyl such as methoxydimethylsilyl, methoxydiethylsilyl, ethoxydimethylsilyl, ethoxydiethylsilyl, by a dialkoxyalkylsilyl group, in particular dialkoxy(C,-C; alkyl(C,-C»)silyl such as dimethoxymethylsilyl, diethoxymethylsilyl, dimethoxyethylsilyl, diethoxyethylsilyl, or by a trialkoxysilyl group, in particular trialkoxy(C,-C»)silyl such as trimethoxysilyl, triethoxysilyl. According to this first embodiment, Z preferentially represents a alkoxy(C,-C2)dialky1(C,-C» )silylalkyle(C,-C3) such as methoxydimethylsilylpropyl, ethoxydimethylsilylpropyl, a dialkoxy(C,-Cz)alkyl(C,-Ca)silylalkyl(C;-C3) such as dimethoxymethylsilylmethyl, diethoxymethylsilylpropyl, or a trialkoxy(C,-C, )silylalkyl(C,-C4) such as trimethoxysilylmethyl, 3-trimethoxysilylpropyl. According to a second embodiment of the invention, Z represents an alkyl substituted by a hydroxydialkylsilyl group, in particular hydroxydialky1(C,-C; )silyl such as hydroxydimethylsilyl, hydroxydiethylsilyl, or by a dihydroxyalkylsilyl group, in particular dihydroxyalkyl(C,-Cz)silyl such as dihydroxymethylsilyl, dihydroxyethylsilyl. According to this second embodiment, Z preferentially represents a hydroxydialkyl(C,-Cz)silylalkyl(C,-Cz) such as hydroxydimethylsilylpropyl. The functional highly saturated diene elastomer useful for the purposes of the invention can be prepared by a process which comprises the successive steps a), b) and c) and, where appropriate, a step d), - step a) being the polymerization of a monomer mixture containing 1,3-diene and ethylene and where appropriate α-monoolefin in the presence of a catalytic system based at least on one metallocene of formula (Ia) and an organomagnesium compound {P(Cp')(Cp*)Nd(BH4)(1+y-Ly-N,} (Ja) Cp' and Cp”, identical or different, being chosen from the group consisting of fluorenyl groups, cyclopentadienyl groups and indenyl groups, the groups being substituted or unsubstituted, Being a group bridging the two groups Cp' and Cp”, and comprising a silicon or carbon atom, Nd denoting the neodymium atom, L representing an alkali metal chosen from the group consisting of lithium, sodium and potassium, N representing a molecule of an ether, x, whole number or not, being equal to or greater than A, y, integer, being equal to or greater than 0, the olefin being ethylene or a mixture of ethylene and an α-monoolefin, - step b) being the reaction of a methacrylate with the reaction product of the polymerization of step a), - step c) being a chain termination reaction, - step d) being a hydrolysis reaction. Step a) of the process is a polymerization reaction of a monomer mixture containing 1,3-diene and ethylene and, where appropriate, α-monoolefin, which makes it possible to prepare the chains of the highly saturated diene elastomer, growing chains intended to react in the following step, step b), with a functionalizing agent, a methacrylate. Preferably, the monomer mixture of step a) contains more than 50 mol% of ethylene, the percentage being expressed relative to the total number of moles of monomers of the monomer mixture of step a). When the monomer mixture contains an α-monoolefin, such as styrene, it preferably contains less than 40 mol% of the α-monoolefin, the percentage being expressed relative to the total number of moles of monomers of the monomer mixture of step a). Preferably, the monomer mixture of step a) is a mixture of 1,3-diene and ethylene. The copolymerization of the monomer mixture can be carried out in accordance with patent applications WO 2007054223 A2 and WO 2007054224 A2 using a catalyst system composed of a metallocene and an organomagnesium. In the present application, the term metallocene means an organometallic complex in which the metal, in this case the neodymium atom, is linked to a molecule called ligand and consisting of two groups Cp! and Cp? linked together by a P bridge. These groups Cp' and Cp”, which may be identical or different, are chosen from the group consisting of fluorenyl groups, cyclopentadienyl groups and indenyl groups, these groups being able to be substituted or unsubstituted. According to the invention, the metallocene used as a basic constituent in the catalytic system corresponds to the formula (Ta) {P(Cp')(Cp*)Nd(BH4)1+yp-Ly-N,} (Ja) Being a group bridging the two groups Cp' and Cp”, and comprising a silicon or carbon atom, Cp' and Cp”, identical or different, being chosen from the group consisting of the fluorenyl groups, cyclopentadienyl groups and indenyl groups, the groups being substituted or unsubstituted, Nd denoting the neodymium atom, L representing an alkali metal chosen from the group consisting of lithium, sodium and potassium, N representing a molecule of an ether, x, whole number or not, being equal to or greater than A, y, an integer, being equal to or greater than 0. Any ether that has the power to complex the alkali metal is suitable as an ether, especially diethyl ether, methyltetrahydrofuran and tetrahydrofuran. Examples of substituted cyclopentadienyl, fluorenyl and indenyl groups include those substituted by alkyl radicals having 1 to 6 carbon atoms or by aryl radicals having 6 to 12 carbon atoms or by trialkylsilyl radicals such as SiMez. The choice of radicals is also guided by the accessibility of the corresponding molecules, namely substituted cyclopentadienyl, fluorenyl and indene, because the latter are commercially available or easily synthesized. As substituted fluorenyl groups, mention may be made of those substituted in position 2, 7, 3 or 6, particularly 2,7-ditertiobutyl-fluorenyl, 3,6-di-tert-butyl-fluorenyl. Positions 2, 3, 6 and 7 respectively designate the position of the carbon atoms of the rings as shown in the diagram below, with position 9 corresponding to the carbon atom to which the P bridge is attached. at 4 ESEN 6 8 Examples of substituted cyclopentadienyl groups include those substituted in both the 2- (or 5-) and 3- (or 4-) positions, particularly those substituted in the 2-position, more particularly the tetramethylcyclopentadienyl group. The 2- (or 5-) position refers to the position of the carbon atom adjacent to the carbon atom to which the P-bridge is attached, as shown in the diagram below. It is recalled that a substitution in the 2- or 5-position is also referred to as an alpha substitution of the bridge. 3-é ÿ % 28 7 { £ As substituted indenyl groups, mention may be made in particular of those substituted in position 2, more particularly 2-methylindenyl, 2-phenylindenyl. Position 2 designates the position of the carbon atom which is adjacent to the carbon atom to which the P bridge is attached, as shown in the diagram below. 7 2 5 È Preferably, Cp! and Cp?, which may be identical or different, are cyclopentadienyls substituted in the alpha position of the bridge, substituted fluorenyls, substituted indenyls or fluorenyl of formula C;3H; or indenyl of formula C,H,. More preferably, Cp! and Cp?, which may be identical or different, are chosen from the group consisting of substituted fluorenyl groups and the unsubstituted fluorenyl group of formula C;3Hz. Advantageously, Cp! and Cp? are identical and each represent an unsubstituted fluorenyl group of formula C;;H;, represented by the symbol Flu. Preferably, the bridge P connecting the groups Cp! and Cp” is of formula ZR,R2, in which Z represents a silicon or carbon atom, R, and Ra, identical or different, each represent an alkyl group comprising from 1 to 20 carbon atoms, preferably a methyl. In the formula ZR;R;, Z advantageously represents a silicon atom, Si. Better, the metallocene is of formula (I-1), (I-2), (I-3), (I-4) or (I-5): [Me:Si(Flu),Nd(u-BH,),Li(THF)] (I-1) [{Me-SiFlu,Nd(u-BH,)Li(THF)}”] (1-2) [Me:SiFlu,Nd(u-BH,)(THF)] (1-3) [{Me;SiFlu,Nd(u-BH,)(THF)}»] (-4) [Me:SiFlu,Nd(u-BH4)] (I-5) in which Flu represents the C,3H group;. The metallocene useful for the synthesis of the catalytic system can be found in the form of crystallized or non-crystalline powder, or in the form of single crystals. The me- Tallocene may be in monomeric or dimeric form, these forms depending on the method of preparation of the metallocene, as for example described in patent application WO 2007054224 A2 or WO 2007054223 A2. The metallocene may be prepared in a conventional manner by a process analogous to that described in patent application WO 2007054224 A2 or WO 2007054223 A2, in particular by reaction under inert and anhydrous conditions of the salt of an alkali metal of the ligand with a borohydride of the rare earth, neodymium, in a suitable solvent, such as an ether, such as diethyl ether or tetrahydrofuran or any other solvent known to those skilled in the art. After reaction, the metallocene is separated from the reaction by-products by techniques known to those skilled in the art, such as filtration or precipitation in a second solvent. The metallocene is finally dried and isolated in solid form. The organomagnesium, another basic constituent of the catalytic system, is the co-catalyst of the catalytic system. Typically, the organomagnesium may be a diorganomagnesium or a halide of an organomagnesium. Preferably, the organomagnesium is of formula (IIa) or (IIb), in which R* and R*, identical or different, represent a carbon group, X is a halogen atom. MgR*R° (Ia) XMgR; (IIb) A carbon group is understood to mean a group that contains one or more carbon atoms. The carbon group may be a hydrocarbon group (hydrocarbyl group) or a heterohydrocarbon group, i.e. a group containing one or more heteroatoms in addition to carbon and hydrogen atoms. Suitable organomagnesium compounds having a heterohydrocarbon group are the compounds described as transfer agents in patent application WO2016092227 A1. The carbon group represented by the symbols R* and R* are preferably hydrocarbon groups. The carbon groups represented by R* and R* may be aliphatic or aromatic. They may contain one or more heteroatoms such as oxygen, nitrogen, silicon or sulfur. Preferably, they are alkyl, phenyl or aryl. They may contain 1 to 20 carbon atoms. The alkyls represented by R* and R* may contain 2 to 10 carbon atoms and include ethyl, butyl, octyl. The aryls represented by R* and R* may contain 7 to 20 carbon atoms and are in particular a phenyl substituted by one or more alkyls such as methyl, ethyl, isopropyl. R3 and R* are preferably alkyls containing 2 to 10 carbon atoms, phenyls or aryls containing 7 to 20 carbon atoms. According to a particular embodiment of the invention, R* comprises a core benzene of which two carbon atoms are substituted, one of the two is substituted by a methyl, an ethyl or an isopropyl or forms a ring with the carbon atom which is its closest neighbor, the second carbon atom being substituted by a methyl, an ethyl or an isopropyl, the magnesium atom being in the ortho position with respect to each of said two carbon atoms and R“ is an alkyl. According to this particular embodiment, R* is advantageously 1,3-dimethylphenyl, 1,3-diethylphenyl, mesityl, or 1,3,5 triethylphenyl and R* is advantageously ethyl, butyl, octyl. According to another particular embodiment of the invention, R° and R* are alkyls containing 2 to 10 carbon atoms, in particular ethyl, butyl, octyl. For example, suitable organomagnesium compounds are butylethylmagnesium, butyloctylmagnesium, ethylmagnesium chloride, butylmagnesium chloride, ethylmagnesium bromide, butylmagnesium bromide, octylmagnesium chloride, octylmagnesium bromide, 1,3-dimethylphenylbutylmagnesium, 1,3-diethylphenylethylmagnesium, butylmesitylmagnesium, ethylmesitylmagnesium, 1,3-diethylphenylbutylmagnesium, 1,3-diethylphenylethylmagnesium, 1,3-diisopropylphenylbutylmagnesium, 1,3-disopropylphenylethylmagnesium, 1,3,5-triethylphenylbutylmagnesium, 1,3,5-triethylphenylethylmagnesium, 1,3,5-triisopropylphenylbutylmagnesium, 1,3,5-triisopropylphenylethylmagnesium. Compounds of formula (IIa) and (IIb) which are Grignard reagents are well known, even some of them are commercial products. For their synthesis, one can also refer, for example, to the collection of volumes of "Organic Synthesis". Like any organomagnesium compound, the organomagnesium compound constituting the catalytic system, in particular of formula (Ia) or (IIb) can be in the form of a monomeric entity or in the form of a polymeric entity. By way of illustration, the organomagnesium (IIa) can be in the form of a monomeric entity (MgR*R), or in the form of a polymeric entity (MgR°R*), p being an integer greater than 1, in particular dimeric (MgR>R#). Furthermore, whether in the form of a monomeric or polymeric entity, the organomagnesium compound can also be in the form of an entity coordinated to one or more molecules of a solvent, preferably an ether such as diethyl ether, tetrahydrofuran or methyltetrahydrofuran. According to any of the embodiments of the invention, the organomagnesium compound is preferably of formula (Ia). The quantities of co-catalyst and metallocene reacted are such that the ratio between the number of moles of Mg in the co-catalyst and the number of moles of the rare earth metallocene, neodymium, preferably ranges from 0.5 to 200, more preferably from 1 to less than 20. The range of values ​​from 1 to less than 20 is particularly favorable for obtaining copolymers with high molar masses. According to one embodiment, the catalytic system is prepared in a conventional manner by a process analogous to that described in patent application WO 2007054224 A2 or WO 2007054223 A2. For example, the co-catalyst, in this case the organomagnesium compound, and the metallocene are reacted in a hydrocarbon solvent, typically at a temperature ranging from 20 to 80°C for a period of between 5 and 60 minutes. The catalytic system is generally prepared in a hydrocarbon solvent, aliphatic such as methylcyclohexane or aromatic such as toluene, preferably in an aliphatic hydrocarbon solvent such as methylcyclohexane. Generally, after its synthesis, the catalytic system is used as is for step a). According to another embodiment, the catalytic system is prepared by a process analogous to that described in patent application WO 2017093654 A1 or in patent application WO 2018020122 A1: it is said to be of the preformed type. For example, the organomagnesium compound and the metallocene are reacted in a hydrocarbon solvent, typically at a temperature of 20 to 80°C for 10 to 20 minutes to obtain a first reaction product, then a preformed monomer is reacted with this first reaction product at a temperature ranging from 40 to 90°C for 1 hour to 12 hours. The pre-forming monomer is preferably used in a molar ratio (pre-forming monomer / metal of the metallocene) ranging from 5 to 1000, preferably from 10 to 500. Before its use in polymerization, the pre-formed type catalytic system can be stored in an inert atmosphere, in particular at a temperature ranging from -20°C to room temperature (23°C).The preformed type catalytic system has as its basic constituent a preforming monomer chosen from 1,3-dienes, ethylene and their mixtures. In other words, the so-called preformed catalytic system contains, in addition to the metallocene and the co-catalyst, a preforming monomer. The 1,3-diene as preforming monomer can be 1,3-butadiene, isoprene or a 1,3-diene of formula CH;=CRS-CH=CH,, the symbol RS representing a hydrocarbon group having 3 to 20 carbon atoms, in particular myrcene or β-farnesene. The preforming monomer is preferably 1,3-butadiene. The catalytic system is typically present in a solvent which is preferably the solvent in which it was prepared, and the concentration of rare earth metal, i.e. neodymium, of metallocene is then included in a range preferably from 0.0001 to 0.2 mol / L more preferably from 0.001 to 0.03 mol / L. Like any synthesis carried out in the presence of organometallic compounds, the synthesis of metallocene, the synthesis of organomagnesium and the synthesis of the catalytic system take place under anhydrous conditions under an inert atmosphere. Typically, the reactions are carried out from solvents and anhydrous compounds under anhydrous nitrogen or argon. The polymerization of the monomer mixture is preferably carried out in solution, continuously or discontinuously. The polymerization solvent is typically a hydrocarbon solvent, preferably aliphatic. As an example of an aliphatic hydrocarbon solvent, methylcyclohexane is particularly suitable. The monomer mixture can be introduced into the reactor containing the polymerization solvent and the catalytic system or conversely the catalytic system can be introduced into the reactor containing the polymerization solvent and the monomer mixture. The monomer mixture and the catalytic system can be introduced simultaneously into the reactor containing the polymerization solvent, in particular in the case of continuous polymerization. The polymerization is typically carried out under anhydrous conditions and in the absence of oxygen, in the optional presence of an inert gas.The polymerization temperature generally varies in a range from 40 to 150°C, preferably 40 to 120°C. A person skilled in the art adapts the polymerization conditions such as the polymerization temperature, the concentration of each of the reactants, the reactor pressure according to the composition of the monomer mixture, the polymerization reactor, the desired microstructure and macrostructure of the copolymer chain. The polymerization is preferably carried out at constant pressure in monomers. A continuous addition of each of the monomers or one of them can be carried out in the polymerization reactor, in which case the polymerization reactor is a fed reactor. This embodiment is particularly suitable for a random incorporation of the monomers. Preferably, the polymerization of step a) is a random polymerization, which results in a random incorporation of the monomers of the monomer mixture used in step a). Once the desired monomer conversion rate is reached in the polymerization reaction of step a), step b) is proceeded to. Step b) of the process according to the invention brings together a functionalizing agent, a methacrylate, with the reaction product of step a) to introduce a single methacrylate monomer unit at one of the ends of the chain of the highly saturated diene elastomer produced at the end of step a). Step b) is a functionalization reaction of the chain end of the highly saturated diene elastomer without there being any subsequent polymerization of the methacrylate. Methacrylate is a so-called functional methacrylate and has the formula CH;=CCH3 COOR”, R° being a hydrocarbon group substituted by an alkoxysilane function. The hydrocarbon group of the symbol R' is preferably saturated. The number of carbon atoms in the hydrocarbon group of the symbol R' is not limited per se. The hydrocarbon group may contain up to 20 carbon atoms. Preferably, the hydrocarbon group of the symbol R° contains from 1 to 6 carbon atoms, more preferably from 1 to 3 carbon atoms. Preferably, the hydrocarbon group of the symbol R° is an alkyl group substituted by said alkoxysilane function. Preferably, the methacrylate is of formula CH;=CCH,COOR” in which R° is an alkyl substituted by an alkoxydialkylsilyl group, in particular alkoxy(C,-C; )dialkyl(C,-C»)silyl such as methoxydimethylsilyl, methoxydiethylsilyl, ethoxydimethylsilyl, ethoxydiethylsilyl, by a dialkoxyalkylsilyl group, in particular dialkoxy(C,-C»)alkyl(C;-C;)silyl such as dimethoxymethylsilyl, diethoxymethylsilyl, dimethoxyethylsilyl, diethoxyethylsilyl, by a trialkoxysilyl group, in particular trialkoxy(C;-C2)silyl such as trimethoxysilyl, triethoxysilyl. More preferably, the methacrylate is a (C1-C2)alkoxy(C1-C2)dialkyl(C1-C2)silylalkyl(C1-C2) methacrylate such as methoxydimethylsilylmethyl methacrylate, ethoxydimethylsilylmethyl methacrylate, methoxydimethylsilylpropyl methacrylate, ethoxydimethylsilylpropyl methacrylate, a dialkoxy(C1-C2)alkyl(C1-C2)methacrylate.)silylalkyl(C,-C3) such as dimethoxymethylsilylmethyl methacrylate, diethoxymethylsilylmethyl methacrylate, dimethoxymethylsilylpropyl methacrylate, diethoxymethylsilylpropyl methacrylate, a trialkoxy(C,-C»)silylalkyl(C;-C3) methacrylate such as trimethoxysilylmethyl methacrylate, 3-(trimethoxysilyl)propyl methacrylate. Even more preferably, the methacrylate is a trialkoxy(C,-C»)silylalkyl(C,-C4) methacrylate such as trimethoxysilylmethyl methacrylate, 3-(trimethoxysilyl)propyl methacrylate. The methacrylates useful for the purposes of the invention may be commercial products. They are generally commercially available products. When the methacrylates are packaged in the presence of a stabilizer, as is the case for most commercial methacrylates, they are typically used after removal of the stabilizer which can be carried out in a well-known manner by distillation or by treatment on alumina columns. Preferably, step b) is carried out in an aliphatic hydrocarbon solvent, such as methylcyclohexane. Advantageously, it is carried out in the reaction medium resulting from step a). It is generally carried out by adding the methacrylate to the reaction product of step a) in its reaction medium with stirring. Before adding the methacrylate, the reactor is preferably degassed and inerted. Degassing the reactor removes residual gaseous monomers and also facilitates the addition of the methacrylate to the reactor. Inerting the reactor, for example with nitrogen, prevents the carbon-metal bonds present in the reaction medium and necessary for the functionalization reaction of the copolymer from being deactivated. The methacrylate can be added pure or diluted in a hydrocarbon solvent, preferably aliphatic such as methylcyclohexane. The methacrylate is left in contact with the reaction product of step a) for the time required for the functionalization reaction of the chain end of the copolymer. The functionalization reaction can typically be monitored by chromatographic analysis to track the consumption of the methacrylate.The functionalization reaction is preferably carried out at a temperature ranging from 23 to 120°C, for 1 to 60 minutes with stirring. The functionalization reaction is preferably carried out with a molar excess of methacrylate relative to the number of moles of neodymium and magnesium. To obtain quasi-quantitative functionalization, the molar ratio between the number of moles of methacrylate and the number of moles of neodymium and magnesium is greater than 2, in particular greater than or equal to 4. The molar ratio between the number of moles of methacrylate and the number of moles of neodymium and magnesium is preferably from 4 to 50, more preferably from 4 to 10. Once the chain end is modified, step b) is followed by step c). Step c), chain termination reaction, is typically a reaction that deactivates the reactive sites still present in the reaction medium resulting from step b). In step c), a chain terminating agent is brought into contact with the reaction product of step b), generally in its reaction medium, for example by adding the terminating agent to the reaction medium at the end of step b) or by pouring the reaction medium obtained at the end of step b) onto a solution containing the terminating agent. The terminating agent is generally added in excess relative to the number of carbon-metal bonds such as C-Mg and C-Nd present in the reaction medium. The terminating agent is typically a protic compound, a compound that has a relatively acidic proton.As a terminating agent, mention may be made of water, carboxylic acids, in particular C, -C, fatty acids; such as acetic acid, stearic acid, aliphatic or aromatic alcohols, such as methanol, ethanol, isopropanol, phenolic antioxidants. After reaction with a protic compound, the process leads to the highly saturated diene elastomer carrying an alkoxysilane function at one of its chain ends. Step c) is followed by step d) when the highly saturated diene elastomer useful for the purposes of the invention carries a silanol function at one of its chain ends. Step d) is a hydrolysis reaction of the alkoxysilane function as a function silanol. The hydrolysis reaction of the alkoxysilane function into a silanol function can be carried out by an acid treatment of the highly saturated diene elastomer obtained at the end of step c). The acid treatment is typically carried out in solution in the presence of aqueous hydrochloric acid, followed by stripping, for example according to the conditions described in patent application EP 266 819 AJ. The highly saturated diene elastomer carrying at one of its chain ends said function, alkoxysilane or silanol, can be separated from the reaction medium of step c) or d) according to methods well known to those skilled in the art, for example by an operation of evaporation of the solvent under reduced pressure or by a steam stripping operation. Preferably, the rubber composition contains more than 50 phr of the highly saturated diene elastomer useful for the purposes of the invention, more preferably at least 80 phr of the highly saturated diene elastomer useful for the purposes of the invention. The balance to 100 phr may consist entirely or partly of a diene and ethylenic elastomer lacking the functional group useful for the purposes of the invention of formula -CH;-CH(CH;)-COOZ as described in the present application. The rubber composition may also comprise an elastomer chosen from the group of diene elastomers consisting of polybutadienes, polyisoprenes, butadiene copolymers, isoprene copolymers and their mixture. Advantageously, the level of the highly saturated diene elastomer useful for the purposes of the invention is 100 phr.The highly saturated diene elastomer useful for the purposes of the invention may consist of a mixture of highly saturated diene elastomers useful for the purposes of the invention which differ from each other by their microstructures or by their macrostructures. The rubber composition also has the essential characteristic of containing a reinforcing inorganic filler. By "reinforcing inorganic filler" is meant in the present application, by definition, any inorganic or mineral filler (whatever its color and origin (natural or synthetic), also called "white" filler, "clear" filler or even "non-black filler" as opposed to carbon black, capable of reinforcing on its own, without any other means than an intermediate coupling agent, a rubber composition intended for the manufacture of tires, in other words capable of replacing, in its reinforcing function, a conventional tire-grade carbon black; such a filler is generally characterized, in a known manner, by the presence of hydroxyl groups (-OH) on its surface. Suitable reinforcing inorganic fillers are, in particular, mineral fillers of the siliceous type, preferably silica (SiOz). The silica used may be any reinforcing silica known to those skilled in the art, in particular any silica precipitated or pyrogenic having a BET surface area and a CTAB specific surface area both less than 450 m° / g, preferably from 30 to 400 m / g, in particular between 60 and 300 m” / g. Examples of highly dispersible precipitated silicas (known as “HDS”) include “Ultrasil” 7000 and “Ultrasil” 7005 silicas from Degussa, “Zeosil” 1165MP, 1135MP and 1115MP silicas from Rhodia, “Hi-Sil” EZ150G silica from PPG, “Zeopol” 8715, 8745 and 8755 silicas from Huber, and high specific surface silicas as described in application WO 03 / 016387. In this presentation, the BET specific surface area is determined in a known manner by gas adsorption using the Brunauer-Emmett-Teller method described in "The Journal of the American Chemical Society" Vol. 60, page 309, February 1938, more precisely according to the French standard NF ISO 9277 of December 1996 (multipoint volumetric method (5 points) - gas: nitrogen - degassing: 1 hour at 160°C - relative pressure range p / po: 0.05 to 0.17). The CTAB specific surface area is the external surface area determined according to the French standard NF T 45-007 of November 1987 (method B). The physical state in which the reinforcing inorganic filler is present is indifferent, whether in the form of powder, microbeads, granules, or even beads. Of course, the term reinforcing inorganic filler also means mixtures of different reinforcing inorganic fillers, in particular highly dispersible silicas as described above. Those skilled in the art will understand that, as an equivalent filler to the reinforcing inorganic filler described in this paragraph, a reinforcing filler of another nature, in particular organic such as carbon black, could be used, provided that this reinforcing filler is covered with an inorganic layer such as silica, or else has functional sites on its surface, in particular hydroxyl sites, requiring the use of a coupling agent to establish the bond between the filler and the elastomer. By way of example, mention may be made, for example, of carbon blacks for tires as described, for example, in patent documents WO 96 / 37547, WO 99 / 28380. Preferably, the level of reinforcing inorganic filler is between 30 and 200 phr, more preferably between 40 and 160 phr. Any of these ranges of reinforcing inorganic filler levels may be applied to any of the embodiments of the invention. Advantageously, the reinforcing inorganic filler is a silica. The rubber composition may further comprise carbon black. Suitable carbon blacks are all carbon blacks, in particular blacks of the HAF, ISAF, SAF, FF, FEF, GPF and SRF types conventionally used in com- rubber positions for tires (so-called tire-grade blacks). Carbon black, when present, is preferably used at a rate of less than 20 pce, more preferably less than 10 pce (for example between 0.5 and 20 pce, in particular between 2 and 10 pce). Within the indicated ranges, the coloring (black pigmenting agent) and anti-UV properties of carbon blacks are benefited from, without otherwise penalizing the typical performances provided by the reinforcing inorganic filler, in particular silica. To couple the reinforcing inorganic filler to the elastomer, a coupling agent is used in a well-known manner, in particular a silane (or bonding agent) which is at least bifunctional and is intended to ensure a sufficient connection between the inorganic filler (surface of its particles) and the elastomer. In particular, organosilanes or polyorganosiloxanes which are at least bifunctional are used. In particular, polysulfurized silanes are used, called “symmetrical” or “asymmetrical” depending on their particular structure, as described for example in applications WO03 / 002648 (or US 2005 / 016651) and WO03 / 002649 (or US 2005 / 016650). In particular, polysulfurized silanes corresponding to the general formula (IIT) are suitable, without the following definition being limiting. JGS,-GJ(IID in which: - x is an integer from 2 to 8 (preferably from 2 to 5); - the symbols G, identical or different, represent a divalent hydrocarbon radical (preferably a C1-C2 alkylene group or a C3-C4 arylene group, more particularly a C1-C5 alkylene, in particular a C1-C6 alkylene, in particular propylene); - the symbols J, identical or different, correspond to one of the three formulas below: R* Ri R2 —Sj—R1 SR _ di Ra R2 Re Ra in which: - the radicals R!, substituted or unsubstituted, identical or different from each other, represent a C1-C3 alkyl, C8-C1 cycloalkyl or C8-C1 aryl group (preferably C1-C4 alkyl, cyclohexyl or phenyl groups, in particular C1-C1 alkyl groups, more particularly methyl and / or ethyl), - the radicals R?, substituted or unsubstituted, identical or different from each other, represent a C,-C,z alkoxyl group or a Cs-Cy5 cycloalkoxyl group (preferably a group chosen from C,-C; alkoxyls and C--C, cycloalkoxyls, more preferably also a group chosen from C1-C4 alkoxyls, in particular methoxyl and ethoxyl). In the case of a mixture of polysulfurized alkoxysilanes corresponding to formula (I) above, in particular usual commercially available mixtures, the average value of "x" is a fractional number preferably between 2 and 5, more preferably close to 4. But the invention can also be advantageously implemented for example with disulfurized alkoxysilanes (x = 2). Examples of polysulfurized silanes include bis-(alkoxyl(C1-C1)alkyl(C1-C1)silyl-alkyl(C1-C4)) polysulfides (especially disulfides, trisulfides or tetrasulfides), such as bis(3-trimethoxysilylpropyl) or bis(3-triethoxysilylpropyl) polysulfides. Among these compounds, bis(3-triethoxysilylpropyl) tetrasulfide, abbreviated to TESPT, of formula [(C1H0),Si(CH3),Sz]; or bis-(triethoxysilylpropyl) disulfide, abbreviated to TESPD, of formula [(CH1O)-Si(CH3):8]. As coupling agent other than polysulfurized alkoxysilane, mention will be made in particular of bifunctional POSS (polyorganosiloxanes) or hydroxysilane polysulfides as described in patent applications WO 02 / 30939 (or US 6,774,255), WO 02 / 31041 (or US 2004 / 051210) or silanes or POSS carrying azo-dicarbonyl functional groups, as described for example in patent applications WO 2006 / 125532, WO 2006 / 125533, WO 2006 / 125534. The coupling agent content is advantageously less than 30 phr, it being understood that it is generally desirable to use as little as possible. Typically the coupling agent content represents from 0.5% to 15% by weight relative to the quantity of inorganic filler. Its content is preferably between 0.5 and 16 phr, more preferably within a range of 3 to 10 phr. This content is easily adjusted by a person skilled in the art according to the content of inorganic filler used in the composition. The rubber composition in accordance with the invention may also contain, in addition to the coupling agents, coupling activators, agents for covering inorganic fillers or more generally processing aids capable, in a known manner, thanks to an improvement in the dispersion of the filler in the rubber matrix and a reduction in the viscosity of the compositions, of improving their ability to be processed in the raw state. The rubber composition has the further essential characteristic of containing a crosslinking system. Chemical crosslinking allows the formation of covalent bonds between the elastomer chains. The crosslinking system may be a vulcanization system or one or more peroxide compounds. According to any of the embodiments of the invention, the crosslinking system is pre- preferably a vulcanization system. The vulcanization system itself is based on sulfur (or a sulfur-donating agent) and a primary vulcanization accelerator. Added to this basic vulcanization system are, incorporated during the first non-productive phase and / or during the productive phase as described later, various known secondary accelerators or vulcanization activators such as zinc oxide, stearic acid or equivalent compounds, guanidine derivatives (in particular diphenylguanidine). The sulfur is used at a preferential rate of 0.5 to 12 phr, in particular 1 to 10 phr. The primary vulcanization accelerator is used at a preferential rate of between 0.5 and 10 phr, more preferably between 0.5 and 5 phr.Any compound capable of acting as an accelerator (primary or secondary) for the vulcanization of diene elastomers in the presence of sulfur can be used, in particular accelerators of the thiazole type and their derivatives, accelerators of the thiuram type, zinc dithiocarbamate. Preferably, a primary accelerator of the sulfenamide type is used. When the chemical crosslinking is carried out by means of one or more peroxide compounds, said peroxide compound(s) preferably represent from 0.01 to 10 pce. Peroxide compounds which can be used as a chemical crosslinking system include acyl peroxides, for example benzoyl peroxide or p-chlorobenzoyl peroxide, ketone peroxides, for example methyl ethyl ketone peroxide, peroxyesters, for example t-butylperoxyacetate, t- butylperoxybenzoate and t-butylperoxyphthalate, alkyl peroxides, e.g. dicumyl peroxide, di-t-butyl peroxybenzoate and 1,3-bis(t-butyl peroxyisopropyl)benzene, hydroperoxides, e.g. t-butyl hydroperoxide. The rubber composition in accordance with the invention may also comprise all or part of the usual additives normally used in elastomer compositions intended to constitute external mixtures of finished rubber articles such as tires, in particular treads, such as for example plasticizers or extender oils, whether the latter are of an aromatic or non-aromatic nature, in particular hydrocarbon plasticizing resins, very weakly or non-aromatic oils (e.g., paraffinic oils, hydrogenated naphthenic oils, MES or TDAE oils), vegetable oils, in particular glycerol esters such as glycerol trioleates, pigments, protective agents such as anti-ozone waxes, chemical anti-ozonants, antioxidants. The rubber composition according to the invention can be manufactured in suitable mixers, using two successive preparation phases according to a general procedure well known to those skilled in the art: a first phase of working or thermo-mechanical mixing (sometimes referred to as a "non-productive" phase) at high temperature, up to a maximum temperature of between 130°C and 200°C, preferably between 145°C and 185°C, followed by a second phase of mechanical working (sometimes referred to as the "productive" phase) at a lower temperature, typically below 120°C, for example between 60°C and 100°C, a finishing phase during which the chemical crosslinking agent, in particular the vulcanization system, is incorporated. Generally speaking, all the basic constituents of the composition included in the tire of the invention, with the exception of the crosslinking system, namely the reinforcing inorganic filler, the coupling agent where appropriate, are incorporated intimately, by kneading, into the elastomer, during the first so-called non-productive phase, that is to say that at least these different basic constituents are introduced into the mixer and kneaded thermomechanically, in one or more stages, until the maximum temperature of between 130°C and 200°C, preferably between 145°C and 185°C, is reached. For example, the first (non-productive) phase is carried out in a single thermomechanical step during which all the necessary constituents, any additional processing agents and other various additives, with the exception of the chemical crosslinking agent, are introduced into a suitable mixer such as a conventional internal mixer. The total mixing time in this non-productive phase is preferably between 1 and 15 min. After cooling the mixture thus obtained during the first non-productive phase, the crosslinking system is then incorporated at low temperature, generally in an external mixer such as a roller mixer; everything is then mixed (productive phase) for a few minutes, for example between 2 and 15 min. The final composition thus obtained is then calendered, for example, in the form of a sheet or plate, in particular for characterization in the laboratory, or extruded in the form of a rubber profile usable as a semi-finished vehicle tire. Thus, according to a particular embodiment of the invention, the rubber composition in accordance with the invention, which can be either in the raw state (before crosslinking or vulcanization), or in the cooked state (after crosslinking or vulcanization), is a semi-finished product which can be used in a tire, in particular as a tire tread. In summary, the invention is advantageously implemented according to any one of the following embodiments 1 to 24: Mode 1: Rubber composition which comprises a highly saturated diene elastomer containing units of a 1,3-diene and more than 50 mol% of ethylene units and carrying at one of its chain ends a functional group of formula -CH,-CH(CH;)-COOZ, Z being a hydrocarbon group substituted by an alkoxysilane or silanol function, a crosslinking system and a reinforcing inorganic filler, the highly saturated diene elastomer being a copolymer of ethylene and a 1,3-diene or a copolymer of ethylene, a 1,3-diene and an α-monoolefin. Method 2: Rubber composition according to method | in which Z denotes an alkyl substituted by an alkoxysilane or silanol function. Mode 3: Rubber composition according to mode 2 in which the alkyl substituted by an alkoxysilane or silanol function is an alkyl which contains 1 to 3 carbon atoms. Mode 4: Rubber composition according to any one of modes | to 3 in which Z represents an alkyl substituted by an alkoxydialkylsilyl group, by a dialkoxyalkylsilyl group or by a trialkoxysilyl group. Method 5: Rubber composition according to any one of methods | to 4 in which Z represents an alkoxy(C,-C»)dialkyl(C;-Cz)silylalkyl(C,-C3), a dialkoxy(C;-C>)alkyl(C,-C>)silylalkyl(C,-C4) or a trialkoxy(C,-C»)silylalkyl(C;-C31). Mode 6: Rubber composition according to any one of modes | to 3 in which Z represents an alkyl substituted by a hydroxydialkylsilyl group or by a dihydroxyalkylsilyl group. Mode 7: Rubber composition according to any one of modes | to 3 or mode 6 in which Z represents a hydroxydialkyl(C,-C»)silylalkyl(C,-C3). Mode 8: A rubber composition according to any one of modes | to 7 wherein the highly saturated diene elastomer is a copolymer of ethylene and a 1,3-diene. Mode 9: A rubber composition according to any one of modes | to 8 in which the ethylene units in the highly saturated diene elastomer represent at least 60 mol% of all the monomer units of the highly saturated diene elastomer. Mode 10: A rubber composition according to any one of modes 1 to 9 in which the ethylene units in the highly saturated diene elastomer represent at least 65 mol% of all the monomer units of the highly saturated diene elastomer. Mode 11: A rubber composition according to any one of modes 1 to 10 in which the ethylene units in the highly saturated diene elastomer represent at least 70 mol% of all the monomer units of the highly saturated diene elastomer. Mode 12: A rubber composition according to any one of modes | to 11 in which the ethylene units in the highly saturated diene elastomer represent less than 90 mol% of the total monomer units of the diene elastomer highly saturated. Method 13: Rubber composition according to any one of methods | to 12 in which the ethylene units in the highly saturated diene elastomer represent at most 85 mol% of all the monomer units of the highly saturated diene elastomer. Method 14: Rubber composition according to any one of methods | to 13 in which the ethylene units in the highly saturated diene elastomer represent at most 80 mol% of all the monomer units of the highly saturated diene elastomer. Mode 15: A rubber composition according to any one of modes | to 14 wherein the 1,3-diene is 1,3-butadiene, isoprene, myrcene, B-farnesene or mixtures thereof. Method 16: Rubber composition according to any one of methods | to 15 in which the 1,3-diene is 1,3-butadiene or a mixture of 1,3-butadiene and myrcene or a mixture of 1,3-butadiene and B-farnesene. Mode 17: Rubber composition according to any one of modes | to 16 in which the highly saturated diene elastomer contains 1,2-cyclohexane units of formula (D. CHa-"CR, ; Pt # \ OHa CH Ye / 4 CH ch, ä 'Ç Method 18: Rubber composition according to method 17 in which the highly saturated diene elastomer contains at most 15 mol% of the 1,2-cyclohexane units of formula (I), the percentage being expressed relative to all the monomer units of the highly saturated diene elastomer. Mode 19: Rubber composition according to any one of modes | to 18 in which the Aa-monoolefin is styrene. Mode 20: A rubber composition according to any one of modes 1 to 19 wherein the highly saturated diene elastomer is a random copolymer. Mode 21: A rubber composition according to any one of modes 1 to 20 wherein the reinforcing inorganic filler is a silica. Mode 22: Rubber composition according to any one of modes 1 to 21 in which the crosslinking system is a vulcanization system. Mode 23: A tire that has a tread, which tire comprises a rubber composition defined in any one of modes 1 to 22. Mode 24: Tire according to mode 23, which tire contains said rubber composition in its tread. The above-mentioned characteristics of the present invention, as well as others, will be better understood upon reading the following description of the exemplary embodiments of the invention, given for illustrative and non-limiting purposes. Examples Nuclear Magnetic Resonance (NMR): The functionalization products of the copolymers are characterized by 'H, PC, Si NMR spectrometry. The NMR spectra are recorded on a Brüker Avance III 500 MHz Spectrometer equipped with a BBFOz-grad 5 mm "broadband" cryoprobe. The quantitative 'H NMR experiment uses a single 30° pulse sequence and a 5 second repetition delay between each acquisition. 64 to 256 accumulations are performed. The quantitative *C NMR experiment uses a single 30° pulse sequence with proton decoupling and a 10 second repetition delay between each acquisition. 1024 to 10240 accumulations are performed. The two-dimensional 'H / '°C and 'H / °Si experiments are used to determine the structure of functional polymers. The 'H chemical shift axis is calibrated against the protonated solvent impurity (CDCIs) at 6,; = 7.20 ppm. The !*C chemical shift axis is calibrated against the solvent signal (CDCI) at 13c = 77 ppm.The Si chemical shift axis is calibrated relative to the tetramethylsilane (TMS) signal at 0 ppm (addition of a few microliters of TMS in the NMR tube). The chemical structure of each functional polymer is identified by NMR ('H, ? Cet Si). 3D SEC Analysis: To determine the number-average molar mass (Mn), and where appropriate the weight-average molar mass (Mw) and the polydispersity index (Ip or also noted D = Mw / Mn) of polymers, the method below is used. The number-average molar mass (Mn), weight-average molar mass (Mw) and polydispersity index of the polymer (hereinafter referred to as sample) are determined absolutely by triple detection size exclusion chromatography (SEC). Triple detection size exclusion chromatography has the advantage of measuring average molar masses directly without calibration. The value of the refractive index increment dn / dc of the sample solution is measured online using the peak area detected by the refractometer (RI) of the liquid chromatography equipment. To apply this method, it must be ensured that 100% of the sample mass is injected and eluted through the column. The RI peak area depends on the sample concentration, the RI detector constant, and the dn / dc value. To determine the average molar masses, the previously prepared and filtered 1g / l solution in tetrahydrofuran is used and injected into the chromatographic chain. The equipment used is a "Wyatt" chromatographic chain. The elution solvent is tetrahydrofuran containing 250 ppm of BHT (2,6-diter-butyl 4-hydroxy toluene), the flow rate is 1 mL.mirr, the system temperature is 35°C and the analysis time is 60 min. The columns used are a set of three AGILENT columns with the trade name "PL GEL MIXED B LS". The injected volume of the sample solution is 100 uL.The detection system is composed of a Wyatt differential viscometer with the trade name “VISCOSTAR II”, a Wyatt differential refractometer with the trade name “OPTILAB T-REX” with a wavelength of 658 nm, a Wyatt multi-angle static light scattering detector with a wavelength of 658 nm and the trade name “DAWN HELEOS 8+”. For the calculation of the number-average molar masses and the polydispersity index, the value of the refractive index increment dn / de of the sample solution obtained above is integrated. The software for processing the chromatographic data is the “ASTRA de Wyatt” system. Determination of | glass transition of polymers: The glass transition temperature (Tg) is measured using a differential scanning calorimeter according to ASTM D3418 (1999). Property innes + The dynamic properties are measured on a viscoanalyzer (Metravib VA4000), according to the ASTM D 5992-96 standard. The response of a sample of vulcanized composition (cylindrical specimen 4 mm thick and 400 mm² in cross-section) is recorded, subjected to sinusoidal stress in alternating simple shear, at a frequency of 10 Hz, under normal temperature conditions (23°C) according to the ASTM D 1349-99 standard. A strain amplitude sweep is carried out from 0.1% to 50% (forward cycle), then from 50% to 0.1% (return cycle). The result used is the loss factor tan(6). For the return cycle, the maximum value of tan(5) observed is indicated, noted tan(5)max. The values ​​of tan(6)max are given on a base of 100, the value 100 being assigned to the control composition (T). The lower the value of tan(5)max, the lower the hysteresis of the rubber composition. Preparation of elastomers; The metallocene [{Me:SiFlu:Nd(u-BH4,)2Li(THF)}]: is prepared according to the procedure described in patent application WO 2007054224. BOMAG butyloctylmagnesium (20% in heptane, at 0.88 mol L!) comes from Chemtura and is stored in a Schlenk tube under an inert atmosphere. Ethylene, grade N35, comes from Air Liquide and is used without prior purification. 1,3-Butadiene and myrcene are purified on alumina guards. The functionalizing agent used is 3-(trimethoxysilyl)propylmethacrylate (TMSiPMA) from Sigma-Aldrich. Commercial methacrylate is used after purification on alumina guards and after bubbling with nitrogen. The methylcyclohexane (MCH) solvent from BioSolve is dried and purified on an alumina column in a solvent fountain from mBraun and used under an inert atmosphere. All reactions are carried out under an inert atmosphere. All polymerization and functionalization reactions are carried out in 90 L stainless steel reactors equipped with a stainless steel stirring blade. Temperature control is ensured by a thermostatically controlled oil bath connected to a double insulated jacket. This reactor has all the necessary inlets and outlets for handling. Synthesis of non-functional ethylene and 1,3-butadiene copolymer: Elastomer El In a 90 L stainless steel reactor, 64 L of MCH and a solution of BOMAG (27 mmol) in MCH (0.01 mol / L) are introduced. The reactor is heated to 80°C and the monomers are added at a controlled flow rate in order to maintain the composition of the monomer mixture in the polymerization medium constant. The ethylene flow rate is set at 40 g / min, butadiene is injected independently and its flow rate is controlled by the ethylene flow rate according to the butadiene / ethylene mass ratio equal to 0.46. When the reactor reaches a pressure of 8 bars, the catalytic system (5.16 mmol of Nd) prepared according to the protocol described below is introduced into the polymerization medium. The polymerization reaction carried out at 80°C is stopped with methanol when nearly 5 to 6 kg of polymer are formed: the polymer is recovered after a stripping step. The polymer is then dried on a screw machine equipped with a single screw at 150°C. Synthesis of non-functional ethylene, 1,3-butadiene and myrcene copolymer - E2 elastomer In a 90 L stainless steel reactor, 64 L of MCH and a solution of BOMAG (23 mmol) in methylcyclohexane (0.01 mol / L) are introduced. The reactor is heated to 80°C and the monomers are added at a controlled rate in order to keep the composition of the monomer mixture in the polymerization medium constant. The ethylene flow rate is set at 40 g / min, myrcene and butadiene are injected independently and their flow rates are controlled by the ethylene flow rate according to the myrcene / ethylene mass ratio equal to 1.62 and according to the butadiene / ethylene mass ratio equal to 0.25. When the reactor reaches a pressure of 8 bars, the catalytic system (6.25 mmol of Nd) preformed at a concentration of 0.007 mol / L prepared according to the previous protocol is introduced into the polymerization medium. The chain termination reaction is carried out by stopping with methanol when 5 to 6 kg of polymer are formed: the polymer is recovered after a stripping step. The polymer is then dried on a screw machine equipped with a single screw at 150°C. The catalyst system is a preformed catalyst system. It is prepared in methylcyclohexane from the metallocene, [Me:Si(Flu);Nd(u-BH,),Li(THF)], the co-catalyst, butyloctylmagnesium (BOMAG), and a preforming monomer, 1,3-butadiene. It is prepared according to a preparation method in accordance with paragraph II.1 of patent application WO 2017093654 A1. In a 500 mL Steinie bottle containing 380 mL of methylcyclohexane previously degassed with nitrogen, 5.7 mL of a solution of butyloctylmagnesium in heptane (0.88 M, 5.0 mmol) and 1.462 g of the complex {(Me 2Si(C;3He)2)Nd(-BH,)Li(THF)}» (number of moles of Nd, nNd = 2.3 mmol), prepared according to patent application WO2007 / 054224 (complex 1) are successively introduced. 17 mL of 1,3-butadiene (also referred to hereinafter as butadiene) are added to the Steinie bottle at 17°C. The contents of the Steinie bottle are then brought to 80°C for 4 hours with stirring. The resulting catalytic solution is stored in a freezer at -25°C. Synthesis of functional polymers: elastomers E3 and E4: Functional elastomers are prepared under the same synthesis conditions as their non-functional counterparts except that the chain termination reaction is replaced by a functionalization reaction described according to the functionalization procedure described below. Functionalization procedure: When the desired monomer conversion is reached (5 to 6 kg of polymer), the contents of the reactor are degassed, the functionalizing agent, methacrylate, is introduced into the polymerization medium under inert atmosphere by overpressure at a rate of 40 equivalents relative to the number of moles of Nd and Mg introduced into the reactor. The reaction medium is stirred for 15 minutes at 80°C. The reaction medium is deactivated with methanol. The polymer is recovered after a stripping step. The polymer is then dried on a screw machine equipped with a single screw at 150°C. It is then analyzed by SEC (THF), 'H, *C, Si NMR. The characteristics of the prepared elastomers are shown in Table 1. SEC and NMR analyses confirm that the chain end of elastomers E3 and E4 is func- tionalized by a single methacrylate monomer unit carrying the alkoxysilane function. [Tables 1] % cycle (1) |Mn Tg (mol) (g / mol) (éC) % myrcene unit (mol) 1 |Elastomer % ethylene unit (mol) I E E3 77 5 |4 (m5 | qua 180000 -40 186000 -40 174000 -54 (1) 1,2-cyclohexane cyclic unit of formula (I) Preparation of rubber compositions: Rubber compositions whose formulation expressed in pce (parts by weight per hundred parts by weight of elastomer) appears in Table 2, Table 3, and Table 4 were prepared according to the following procedure: the elastomer, the silica, the coupling agent, as well as the various other ingredients with the exception of the vulcanization system are successively introduced into an 85 cm Polylab internal mixer (final filling rate: approximately 70% by volume), whose initial tank temperature is approximately 100°C. Thermomechanical work (non-productive phase) is then carried out in one step, which lasts a total of approximately 5 min, until a maximum "fall" temperature of 160°C is reached. The mixture thus obtained is recovered, cooled and then sulfur and the accelerator are incorporated on a mixer (homo-finisher) at 25°C, mixing everything (productive phase) for approximately ten minutes.The compositions thus obtained are then calendered either in the form of plates (thickness of 2 to 3 mm) or thin sheets of rubber for the measurement of their physical or mechanical properties, after vulcanization at 150°C. Rubber compositions C1, C2 and C3 each contain a functional highly saturated diene elastomer. They are in accordance with the invention. Their control compositions are T1, T2 and T3 respectively. They contain a highly saturated diene elastomer which has not been functionalized, elastomer E1 and elastomer E2 respectively. The results are shown in Table 5. Rubber compositions C1, C2 and C3 exhibit a much lower hysteresis than their respective controls, T1, T2 and T3. This decrease in hysteresis is attributed to the functionalization of the chain end of the highly saturated diene elastomer by a single monomer unit of the methacrylate. This result is obtained without the rheological properties of the rubber composition, in particular the rigidity, being modified, since the modification of the elastomer by the methacrylate is not accompanied by the formation of a polymethacrylate block which would have led to a change in the glass transition temperature of the rubber composition and therefore to a change in the rigidity of the rubber composition. [Tables 2] that I "RE ZnO (9) Sulfur CBS (10) (1) “Zeosil 1165 MP” from Solvay-Rhodia in the form of microbeads (2) N234 (3) Liquid Silanc (TESPT) “Si69” from Evonik company (4) DPG: Diphenylguanidine “Perkacit DPG” from Flexsys (5) Anti-ozone wax “VARAZON 4959” from the company Sasol Wax (6) Santoflex 6PPD from FLEXSYS company (7) Tetramethylquinone (8) Stearic acid “Pristerene 4931” from Unigema (9) Industrial grade Zinc Oxide from Umicore (10) N-cyclohexyl-2-benzothiazol-sulfenamide “Santocure CBS” from Flexsys [Tables 3] (1) “Zeosil 1165 MP” from Solvay-Rhodia in the form of microbeads (2)N234 (3) Liquid silane (TESPT) “Si69” from Evonik company (4) Diphenylguanidine “Perkacit DPG” from Flexsys (5) Trioctyl phosphate (tri-2-ethylhexyl phosphate) “Disflamoll TOF” from Lanxess (Tg = -110°C) (6) Hydrogenated C9 / DCPD copolymer resin “Escorez 5600” (Tg 55°C) (7) Anti-ozone wax “VARAZON 4959” from Sasol Wax (8) “Santoflex 6PPD” from FLEXSYS company (9) Tetramethylquinone (10) Stearic acid “Pristerene 4931” from Unigema (11) Industrial grade Zinc Oxide from Umicore (12) N-cyclohexyl-2-benzothiazol-sulfenamide “Santocure CBS” from Flexsys [Tables 4] [T3 |ea Composition (in [T3 |c3 pce) Elastomer El fo Elastomer E3 100 Silica (1) 38 38 Silane (2) 3.1 31 Antioxidant (3) 2 2 Wax Ozone (4) [1 | 1 Stearic acid (5) |2 qe Zn0 (6) 24 4 s [1 jt CBS (7) pu (1) Zeosil 1165 MP" from Solvay-Rhodia in the form of microbeads (2) Liquid silane (TESPT) “S169” from Evonik company (3) N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine “Santoflex 6PPD” from FLEXSYS {4) Anti-ozone wax “VARAZON 4959” from the company Sasol Wax (5) Stearic acid “Pristerene 4931” from Unigema (6) Industrial grade Zinc Oxide from Umicore (7) N-cyclohexyl-2-benzothiazol-sulfenamide “Santocure CBS” from Flexsys [Tables 5] Composition TI Cl T2 C2 T3 C3 [tan(s)max 23°C [100 |87 |lo0 [ss [100 ds

Claims

Claims

1. A rubber composition which comprises a diene elastomer highly saturated containing units of a 1,3-diene and more than 50% in mole of ethylene units and carrying at one of its chain ends a functional group of formula -CH,-CH(CH;)-COOZ, Z being a hydrocarbon group substituted by an alkoxysilane or silanol function, a crosslinking system and a reinforcing inorganic filler, the highly saturated diene elastomer being an ethylene copolymer and a 1,3-diene or a copolymer of ethylene, a 1,3-diene and a a-monoolefin.

2. A rubber composition according to claim 1 wherein Z denotes an alkyl substituted by an alkoxysilane or silanol function.

3. Rubber composition according to claim 2 in which the alkyl substituted by an alkoxysilane or silanol function is an alkyl which contains 1 to 3 carbon atoms.

4. A rubber composition according to any one of claims 1 to 3 in which Z represents an alkyl substituted by an alkoxy group- dialkylsilyl, by a dialkoxyalkylsilyl group or by a trial- group coxysilyl.

5. A rubber composition according to any one of claims 1 to 4 in which Z represents an alkoxy(C,-C»)dialkyl(C,-C; )silylalkyl(C,-C1), a dialkoxy(C,-C»,)alkyl(C,-C»)silylalkyl(C,-C1) or a trialkoxy(C,-C,)silylalkyl(C,-C3).

6. A rubber composition according to any one of claims 1 to 3 in which Z represents an alkyl substituted by a hy- group droxydialkylsilyl or by a dihydroxyalkylsilyl group.

7. A rubber composition according to any one of claims 1 to 3 or claim 6 in which Z represents a hy- droxydialkyl(C,-C»)silylalkyl(C,-C3).

8. A rubber composition according to any one of claims 1 to 7 in which the highly saturated diene elastomer is a co- polymer of ethylene and a 1,3-diene.

9. A rubber composition according to any one of claims 1 to 8 in which the ethylene units in the diene elastomer highly saturated represent less than 90 mol% of the total monomer units of the highly saturated diene elastomer.

10. A rubber composition according to any one of claims 1 to 9 in which the 1,3-diene is 1,3-butadiene, isoprene, myrcene, B-farnesene or mixtures thereof.

11. | A rubber composition according to any one of claims 1 to 10 in which the 1,3-diene is 1,3-butadiene or a mixture of 1,3-butadiene and myrcene or a mixture of 1,3-butadiene and of B-farnesene.

12. A rubber composition according to any one of claims 1 to 11 in which the highly saturated diene elastomer contains 1,2-cyclohexane units of formula (I). Ch, —G} Ps 7 x CH TH xf 'damna dl} y “

13. A rubber composition according to any one of claims 1 to 12 in which the highly saturated diene elastomer is a co- statistical polymer. [Claim 14} A rubber composition according to any one of claims 1 to 13 wherein the reinforcing inorganic filler is a silica.

15. A tire which has a tread, which tire comprises a rubber composition defined as any one of claims 1 to 14, preferably in its band of rolling.