Exterior member and electronic clock

Abstract

To provide an exterior member capable of further expanding surface diversity, an electronic timepiece, and a method of manufacturing the exterior member.SOLUTION: An exterior member (1) disclosed herein has a surface where each of materials with different crystal grain sizes is arranged in any of a plurality of regions (R1, R2).SELECTED DRAWING: Figure 1

Description

[Technical field]

[0001] The present invention relates to an exterior member, an electronic timepiece, and a method for manufacturing the exterior member. [Background technology]

[0002] For portable electronic devices, exterior components must be both functional and stylish, while still being of a size and shape suitable for portability. Conventionally, titanium materials such as titanium and titanium alloys have been used as components that can give off a sense of luxury. However, some titanium materials have low surface hardness, and are prone to aging, such as scratches and loss of luster with use.

[0003] Patent Document 1 discloses a technology for hardening the surface of titanium material without compromising its design, in which oxygen or oxygen and nitrogen are diffused onto the surface of the titanium material to form a solid-solution hardened layer, and the outermost titanium oxide layer is made sufficiently thin to suppress the occurrence of interference fringes and turbidity. [Prior art documents] [Patent documents]

[0004] [Patent Document 1] International Publication No. 2018 / 128160 Summary of the Invention [Problem to be solved by the invention]

[0005] However, conventional techniques have the drawback of producing monotonous surface conditions and lacking diversity.

[0006] An object of the present invention is to provide an exterior member, an electronic timepiece, and a method for manufacturing an exterior member that enable greater diversity in surfaces. [Means for solving the problem]

[0007] In order to achieve the above object, the present invention provides The exterior component has a surface divided into a plurality of regions of constituent materials having different crystal grain sizes. Effect of the Invention

[0008] According to the present invention, there is an effect that the variety of surfaces of exterior members can be further increased. [Brief description of the drawings]

[0009] [Figure 1] FIG. 2 is an overall perspective view of an example of an exterior member of the present embodiment. [Diagram 2] 4 is a flowchart showing a manufacturing procedure of the exterior member. [Diagram 3] FIG. 2 is a cross-sectional perspective view showing a schematic state during manufacturing. [Figure 4] FIG. 2 is a cross-sectional perspective view showing a schematic state during manufacturing. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0010] Hereinafter, an embodiment of the present invention will be described with reference to the drawings. FIG. 1 is an overall perspective view of an example of an exterior member 1 of the present embodiment. The exterior member 1 is attached (bezel) along the periphery of the top surface or along the side surface of an electronic timepiece (electronic wristwatch), and has a generally annular shape.

[0011] The shape of the top surface of the exterior member 1 has projections and recesses according to the design and function. The outer edge of the exterior member 1 has projections and recesses in plan view. At least a portion of the recesses in the outer edge corresponds to the position of a push button switch located on the side of an electronic wristwatch in plan view, for example. In addition, a recess 11 recessed in the height direction is located in a portion of the protruding portion of the outer edge. The recess 11 has a hole H for screw fastening. The top surface of the exterior member 1 (in this embodiment, the top surface means a surface that is visible in plan view from above the display surface of the electronic watch when attached to the electronic watch, and is not limited to a single plane) has at least portions that are inclined from the inside to the outside.

[0012] The exterior member 1 has a plurality of regions on the upper surface that have different appearances, for example, a first region R1 and a second region R2. The first region R1 is a region with a high degree of flatness (small surface roughness). Therefore, light is easily mirror-reflected in the first region R1. The second region R2 has a matte surface with a larger surface roughness than the first region R1. Therefore, light is easily diffusely reflected in the second region R2 than in the first region R1.

[0013] The first region R1 and the second region R2 are clearly separated. Here, the boundary between the first region R1 and the second region R2 has a curved portion, and for example, extends in a substantially circular shape along the circumferential direction while waving in a wave-like manner (wave portion) in a direction perpendicular to the circumferential direction of the exterior member 1. The curved portion here may include a small straight line that is bent and connected within a range that the user can visually recognize as a curve. The boundary may be in multiple rows. The boundary may be partially cut off by protruding from the exterior member 1 depending on the wave amplitude and the width of the exterior member 1. The boundary may also branch or converge midway. That is, the second region R2 may include an isolated region surrounded by the first region R1. The wavy oscillation does not need to be regular and may be determined arbitrarily according to the design. There is no clear difference (step) in the height direction between the first region R1 and the second region R2.

[0014] The constituent material of the first region R1 is different from the constituent material of the second region R2. For example, the constituent material of the first region R1 is 64 titanium alloy (first constituent material, first metallic material; titanium alloy containing 6% aluminum and 4% vanadium by mass fraction). The constituent material of the second region R2 is, for example, pure titanium (second constituent material, second metallic material). The crystals grow more in the second region R2 than in the first region R1, and the crystal grain size is larger (different from each other), so that the surface roughness of the second region R2 is larger. As a result, the first region R1 and the second region R2 appear differently.

[0015] Next, a method for manufacturing the exterior member 1 of this embodiment will be described. In the exterior member 1, one of the first region R1 and the second region R2, in this case the first region R1 is formed and then the second region R2 is additionally formed. Then, both regions are heated together to cause crystal growth.

[0016] In the crystal growth, the transformation temperature of 64 titanium alloy is higher than that of pure titanium (the transformation temperatures are different). Therefore, when pure titanium and 64 titanium alloy are heat treated at a temperature between these two transformation temperatures, a significant difference occurs in the crystal growth rate between them. That is, the crystals grow significantly in the second region R2 of pure titanium. As a result, the surface roughness is selectively increased in the second region R2.

[0017] FIG. 2 is a flowchart showing a manufacturing procedure for the exterior member 1. 3 and 4 are cross-sectional perspective views that typically show a state during manufacturing. For the sake of explanation, a cross section cut through approximately 1 / 4 of the range of the thickness of one exterior member 1 is shown here.

[0018] In step P1, pure titanium powder (powder particles. Sizes may be appropriately selected for processing. The same applies below) and 64 titanium alloy powder are prepared, and a cylindrical structure S1 including a columnar portion R1a (columnar structure) is formed in a first region R1 when viewed in a plan view by a 3D printer using the 64 titanium alloy powder. As shown in FIG. 3(a), in the formed cylindrical structure S1, the columnar portion R1a extends in the vertical direction. The second region R2 when viewed in a plan view is a hole-like gap V2 (void) remaining between the columnar portions R1a. This cylindrical structure S1 is actually sufficiently longer in the height direction than the exterior member 1, and is later sliced ​​at regular intervals in the height direction and shaped by cutting or the like to obtain multiple exterior members 1. The cylindrical structure S1 may be formed by forming and stacking multiple ring-shaped structures of the same thickness to be sliced.

[0019] In step P2, as shown in FIG. 3(b), the gaps V2 are filled with pure titanium (Ti) powder in the second region R2 in plan view. In step P3, the cylindrical structure S1 filled with the pure titanium powder is pressurized and heated by hot isostatic pressing (HIP). In this process, the pure titanium powder is integrated (bonded) and fixed to the cylindrical structure S1. At this time, the cylindrical structure S1 shrinks as a whole depending on the gaps between the particles of the pure titanium powder, and the cylindrical structure S1 becomes one size smaller. Therefore, the size of the cylindrical structure S1 formed in step P1 is determined to be larger than the final size of the exterior member 1 by the amount of shrinkage, and the amount of the pure titanium powder to be filled is also determined in advance. The device for performing the HIP process may be a known one.

[0020] In step P4, the cylindrical structure S1 in which the 64 titanium alloy and the pure titanium are fixed to each other with a region therebetween is heated at a set temperature. In this heat treatment, the heating temperature is set to a temperature between the transformation temperature of the pure titanium and the transformation temperature of the 64 titanium alloy. As a result, the crystal growth of the pure titanium, whose transformation temperature is lower than the heating temperature, proceeds faster (the crystal growth rate is higher) than that of the 64 titanium alloy, whose transformation temperature is higher than the heating temperature. As a result, as shown in FIG. 3(c), the region R2b of the pure titanium becomes matte and is more likely to diffusely reflect. The crystal growth of the 64 titanium alloy is slow, and the crystal grain size of the pure titanium in a state in which the crystal grain size of the pure titanium reaches an appropriate size is smaller than that of the pure titanium. The difference in the crystal growth rate of both members is changed by appropriately changing and setting the heating temperature within the above range. Therefore, the heating temperature may be adjusted according to the desired light reflection state in the region R1b of the 64 titanium alloy and the desired magnitude of the difference between the region R1b of the 64 titanium alloy and the region R2b of the pure titanium.

[0021] In step P5, the cylindrical structure S1, which has the titanium alloy 64 region R1b and the pure titanium region R2b, is sliced ​​at regular intervals in the height direction to obtain a plurality of ring-shaped members. The intervals between the slices (the height of the ring-shaped members) may be slightly larger than the height of the exterior member 1.

[0022] In step P6, the annular member is cut and polished to obtain the outer shape of the exterior member. As shown in Fig. 4(a), the pattern of the columnar 64 titanium alloy region R1b and the pure titanium region R2b is maintained in a plan view even after cutting, and the first region R1 and the second region R2 appear on the upper surface of the exterior member. In addition, depending on the positional relationship between the region R1b and the region R2b and the outer shape of the exterior member, the pattern may also be exposed on the side of the exterior member (the inner edge side or the outer edge side of the annular shape).

[0023] In step P7, the surface roughened by the treatments in steps P5, P6, etc. is heated to an appropriate temperature to recrystallize each component.

[0024] In step P8, the surface recrystallized in step P7 is chemically (etched) to dissolve the surface of the exterior member. This treatment makes the crystal pattern on the surface of the exterior member stand out.

[0025] In step P9, the surface is covered and protected with a coating (hardened film) by IP (ion plating). The coating is made of various titanium-based materials. As shown in FIG. 4(b), the coating is formed thin enough that the first region R1 and the second region R2 are visible through the coating. A well-known technique such as AIP (arc reaction IP) processing may be used for the IP processing. In this manner, the exterior member 1 is obtained. The exterior member 1 is fixed to the body of the electronic watch by screws passing through the holes H.

[0026] As described above, the exterior member 1 of this embodiment has a surface in which constituent materials with different crystal grain sizes are divided into a plurality of regions (first region R1 and second region R2). By dividing the plurality of constituent materials into portions and exposing them on the surface to produce a pattern, the exterior member 1 can increase the diversity of its surface while maintaining its functionality. This can increase the range of designs for the exterior member 1 and the electronic watch to which the exterior member 1 is attached.

[0027] Furthermore, the boundaries between the regions include curved portions. This allows a wider range of design options for the exterior member 1. In particular, it is possible to obtain an exterior member 1 that incorporates highly artistic designs.

[0028] In addition, the exterior member 1 has an annular shape, and the boundaries of the multiple regions extend along the circumferential direction of the annular shape, and the curved portion may include a wavy portion. By defining the boundaries in this manner, it is easy to incorporate a periodic design, and the exterior member 1 can have a pattern that fits the annular structure.

[0029] In addition, the first region R1 of the multiple regions may be a region formed of a first metal material (64 titanium alloy), and the second region R2 different from the first region R1 may be a region formed of a second metal material (pure titanium) different from the first metal material. In this way, the metal crystals allow the mirror degree of the surface of the exterior member 1 to be appropriately adjusted according to the connection of the crystals, making it easy to give the exterior member 1 a beautiful design.

[0030] The first metal material may be titanium alloy 64, and the second metal material may be pure titanium. By combining two similar materials with different transformation temperatures, it is easy to form the exterior member 1 and to maintain and maintain its function. In addition, with this exterior member 1, it is easy to avoid a flashy design.

[0031] Furthermore, the exterior member 1 may have a coating on a plurality of regions that is thick enough to visually recognize these plurality of regions. Titanium and the like are prone to damage and deterioration over time, so by having the exterior member 1 have a coating, the pattern and function can be stably maintained for a longer period of time.

[0032] Furthermore, the atmosphere of the electronic timepiece can be varied by providing the bezel as the exterior member 1. Furthermore, the luxury feel of the electronic timepiece can be easily achieved with just the exterior member 1.

[0033] The manufacturing method of the exterior member 1 of this embodiment includes the steps of forming a columnar portion R1a having a shape of the first region R1 as viewed from the top side from a first constituent material and extending in the vertical direction, filling a powder of a second constituent material having a transformation temperature different from that of the first constituent material into a portion of the gap V2 of the columnar portion R1a having a shape of the second region as viewed from the top side, bonding the second constituent material by HIP processing to fix it to the columnar portion R1a, and heating at a temperature between the transformation temperature of the first constituent material and the transformation temperature of the second constituent material to grow crystals of the first constituent material and the second constituent material at different crystal growth rates. In this way, crystals of two types of materials are grown under different materials and conditions with different crystal growth rates, and the final crystal grain size is made different, thereby changing the part with a high crystal growth rate into a matte shape. According to this manufacturing method, as long as the columnar portion R1a is obtained, the subsequent processing can be easily performed, and a range of designs can be obtained. In addition, since the pattern is drawn by the difference in the reflection state, the pattern of the exterior member 1 does not become flashy and it is easy to prevent it from asserting too much presence on the display screen of the electronic watch.

[0034] The columnar portion R1a may be formed by a 3D printer. This allows the first region R1 to be formed with high precision even if it is complex, making it possible to obtain a fine and intricate pattern. In particular, it has been difficult to mass-produce the boundaries of multiple regions in a curved shape as designed, much less to expose the boundaries on a non-flat upper surface and use them as a pattern. By using a 3D printer, it is possible to expose a pattern with a curved boundary on the upper surface.

[0035] The manufacturing method of the exterior member 1 may also include a step of forming a coating on the upper surface by ion plating to a thickness that allows the first region R1 and the second region R2 to be visually recognized. This makes it possible to protect the surface of the exterior member 1 and suppress deterioration and damage over time while maintaining the visibility of the design.

[0036] The present invention is not limited to the above-described embodiment, but may be modified in various ways. For example, in the above embodiment, the combination of pure titanium and titanium alloy 64 is taken as an example of two kinds of constituent materials, but the present invention is not limited thereto. Any material that can be processed as described above may be used, and examples of such constituent materials include Cobarion (registered trademark), stainless steel (SUS), zirconium, etc. Cobarion hardly undergoes crystal growth during heat treatment (step P4), and hardly dissolves during etching (step P8). Therefore, the region of Cobarion has a higher specularity than the region of titanium alloy 64, that is, the degree of specular reflection of light is higher. By combining Cobarion with a constituent material that undergoes crystal growth, the contrast between the two regions becomes larger and clearer than the combination of pure titanium and titanium alloy 64.

[0037] In addition, in the above embodiment, the voids of the columnar structure of 64 titanium alloy are filled with pure titanium powder and then HIP treatment is performed, but the reverse is also possible, that is, the voids of the columnar structure of pure titanium may be filled with 64 titanium alloy powder.

[0038] Also, the minute components filled in the gaps have been described as powder, but they may be granular as long as they are within a size range that allows them to be fixed and bonded by HIP processing.

[0039] Furthermore, the boundary between the first region R1 and the second region R2 in the exterior member 1 does not have to be wavy, mainly along the circumferential direction of the annular shape of the exterior member 1. For example, the boundary may have straight lines or bent parts. Furthermore, the exterior member 1 may have a boundary that is mainly a closed shape, such as a circle, an ellipse, or a rectangle.

[0040] In the above embodiment, the upper surface of the exterior member 1 has been described as being a combination of two types of regions, but it may be a combination of three or more types of regions. In this case, for example, if the second and subsequent types of materials do not contact each other, different gaps separated from each other can be filled with powders of different constituent materials. In this way, the exterior member is formed in the same manner as the exterior member 1 having the above two types of regions. As a result, an exterior member 1 having multiple types of second regions having different crystal grain sizes made of multiple second constituent materials is obtained.

[0041] Furthermore, the columnar portion R1a does not have to be formed by a 3D printer.

[0042] The coating may be formed by a method other than IP. If a highly durable material is used, the coating does not necessarily have to be formed. The coating does not have to be completely transparent as long as it is light-transmitting and allows the first region R1 and the second region R2 to be visually recognized. In other words, the coating may be slightly colored on the upper surface.

[0043] Furthermore, there is no restriction on the type of electronic watch to which the exterior member 1 is attached. The electronic watch may be a multi-function terminal such as a smart watch. Alternatively, the electronic watch may not be an electronic watch but may be another portable electronic device. In addition, the specific configurations, structures, and manufacturing methods thereof shown in the above embodiments can be modified as appropriate without departing from the spirit of the present invention.

[0044] Although several embodiments of the present invention have been described, the scope of the present invention is not limited to the above-described embodiments, but includes the scope of the invention described in the claims and its equivalents. The inventions described in the claims originally attached to this application are set forth below. The claim numbers in the appended claims are the same as those in the claims originally attached to this application.

[0045] [Note] <Claim 1> An exterior component having a surface divided into a plurality of regions of constituent materials having different crystal grain sizes. <Claim 2> 2. The exterior member according to claim 1, wherein the boundaries of the plurality of regions include curved portions. <Claim 3> The exterior member has an annular shape, 3. The exterior member according to claim 2, wherein the boundary extends along a circumferential direction of the annular shape, and the curved portion includes a wavy portion. <Claim 4> 2. The exterior member according to claim 1, wherein a first region among the plurality of regions is a region formed from a first metal material, and a second region different from the first region is a region formed from a second metal material different from the first metal material. <Claim 5> 5. The armor member according to claim 4, wherein the first metallic material is titanium alloy 64 and the second metallic material is pure titanium. <Claim 6> 2. The exterior member according to claim 1, further comprising a coating on the plurality of regions that allows the plurality of regions to be visually recognized. <Claim 7> 7. An electronic timepiece comprising a bezel as claimed in claim 1 as an exterior member. <Claim 8> forming a columnar structure extending in a vertical direction from a first constituent material in a first region when viewed from the top surface side; a step of filling a powder or grain of a second constituent material having a transformation temperature different from that of the first constituent material into a second region which is a void portion of the columnar structure when viewed from above; bonding and adhering the second component material to the columnar structures by hot isostatic pressing; a step of heating the first constituent material at a temperature between a transformation temperature of the first constituent material and a transformation temperature of the second constituent material to cause crystal growth of the first constituent material and the second constituent material at different crystal growth rates; A method for manufacturing an exterior member comprising the steps of: <Claim 9> The method for manufacturing an exterior member according to claim 8, wherein the columnar structure is formed by a 3D printer. <Claim 10> 10. The method for producing an exterior member according to claim 9, further comprising the step of forming a coating on the upper surface by ion plating to a thickness that enables the first region and the second region to be visually recognized. [Explanation of symbols]

[0046] 1 Exterior materials 11 Recess H hole R1 First Region R1a Columnar part R1b area R2 Second Region R2b area S1 Cylindrical structure V2 Gap

Claims

Claim 1: An exterior member provided in an electronic timepiece and having a surface in which constituent materials having different crystal grain sizes are divided into a plurality of regions, wherein the boundary between the plurality of regions has a curved portion including a corrugated portion. The exterior member. Claim 2: An exterior member provided in an electronic timepiece and having a surface in which constituent materials having different crystal grain sizes are divided into a plurality of regions, wherein the boundary between the plurality of regions has a straight portion or a bent portion. The exterior member. Claim 3: The exterior member has an annular shape, wherein the boundary between the plurality of regions extends along the circumferential direction of the annular shape. The exterior member according to Claim 1 or 2. Claim 4: Among the plurality of regions, a first region is a region formed of a first metal material, and a second region different from the first region is a region formed of a second metal material different from the first metal material. The exterior member according to Claim 1 or 2. Claim 5: The first metal material is a 64 titanium alloy, and the second metal material is pure titanium. The exterior member according to Claim 4. Claim 6: The exterior member according to Claim 1 or 2, having a film that makes the plurality of regions visible on the plurality of regions. Claim 7: The first metal material is a cobalt alloy, and the second metal material is a metal material in which crystal growth progresses more easily than the cobalt alloy by heat treatment. The exterior member according to Claim 4. Claim 8: An electronic timepiece including a bezel as the exterior member according to Claim 1 or 2.

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